Organic light-emitting device having electron transport region including lanthanide and alkali metal halide

Patent metadata

Field	Value
Publication number	US-10181572-B2
Application number	US-201815904286-A
Country	US
Kind code	B2
Filing date	Feb 23, 2018
Priority date	Feb 24, 2015
Publication date	Jan 15, 2019
Grant date	Jan 15, 2019

Abstract

An organic light-emitting device includes a substrate, an anode on the substrate, a hole transport region on the anode, an emission layer on the hole transport region, an electron transport region on the emission layer, and a cathode on the electron transport region, wherein the electron transport region includes an electron injection layer including a first material including at least one of a halide of an alkali metal, and a second material including at least one of a lanthanide metal and a alkaline earth metal, and wherein the cathode contacts the electron injection layer and includes a first metal including at least one of silver, gold, platinum, copper, manganese, titanium, cobalt, nickel, and tungsten, and a second metal including at least one of a lanthanide metal and an alkaline earth metal, wherein an amount of the first metal is equal to or greater than that of the second metal.

First claim

What is claimed is:

1. An organic light-emitting device comprising:
a plurality of anodes which are disposed on a first sub-pixel, a second sub-pixel, and a third sub-pixel, respectively;
a cathode facing the plurality of anodes;
an emission layer between the plurality of anodes and the cathode;
a hole transport region between the plurality of anodes and the emission layer; and
an electron transport region between the emission layer and the cathode,
wherein the emission layer comprises a first emission layer on the first sub-pixel and configured to emit a first color light, a second emission layer on the second sub-pixel and configured to emit a second color light different from the first color light, and a third emission layer on the third sub-pixel and configured to emit a third color light different from the first color light and the second color light,
the electron transport region comprises an electron injection layer comprising: a first material comprising at least one of a halide of an alkali metal (Group 1); and a second material comprising a first lanthanide metal, and
the cathode contacts the electron injection layer and comprises a first metal comprising at least one of silver (Ag), gold (Au), platinum (Pt), copper (Cu), manganese (Mn), titanium (Ti), cobalt (Co), nickel (Ni), and tungsten (W); and a second metal comprising at least one of a second lanthanide metal and an alkaline earth metal, wherein an amount of the first metal is equal to or greater than that of the second metal, and
the first material comprises at least one of lithium chloride (LiCl), sodium chloride (NaCl), potassium chloride (KCl), rubidium chloride (RbCl), cesium chloride (CsCl), potassium bromide (KBr), rubidium bromide (RbBr), cesium bromide (CsBr), potassium iodide (KI), rubidium iodide (RbI), and cesium iodide (CsI).

2. The organic light-emitting device of claim 1 , wherein at least one of the first lanthanide metal and the second lanthanide metal is at least one selected from the group consisting of lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), and lutetium (Lu), and
wherein the alkaline earth metal is at least one selected from the group consisting of beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), and radium (Ra).

3. The organic light-emitting device of claim 1 , wherein a thickness of the electron injection layer is in a range of 1 Å to 50 Å.

4. The organic light-emitting device of claim 1 , wherein the first material and the second material are co-deposited to form the electron injection layer.

5. The organic light-emitting device of claim 4 , wherein a volume ratio of the first material to the second material is in a range of 1:9 to 9:1.

6. The organic light-emitting device of claim 4 , wherein the first material comprises at least one of RbI and RbCl; and the second material comprises at least one of Yb and Mg.

7. The organic light-emitting device of claim 1 , wherein the electron injection layer comprises a first layer comprising the first material, and a second layer comprising the second material.

8. The organic light-emitting device of claim 7 , wherein the first material comprises at least one of RbI and RbCl, and the second material comprises at least one of Yb and Mg.

9. The organic light-emitting device of claim 1 , wherein the electron injection layer comprises a first layer comprising the second material, and a second layer comprising the first material.

10. The organic light-emitting device of claim 9 , wherein the first material comprises at least one of RbI and RbCl, and the second material comprises at least one of Yb and Mg.

11. The organic light-emitting device of claim 7 , wherein each of thicknesses of the first layer and the second layer is in a range of 1 Å to 49 Å, and a sum of the thicknesses is in a range of 1 Å to 50 Å.

12. The organic light-emitting device of claim 1 , wherein a volume ratio of the first metal to the second metal is in a range of 50:50 to 99:1.

13. The organic light-emitting device of claim 1 , wherein the cathode is comprising Ag:Mg or Ag:Yb.

14. The organic light-emitting device of claim 1 , wherein the electron transport region further comprises an electron transport layer between the electron injection layer and the emission layer.

15. The organic light-emitting device of claim 14 , wherein the electron transport layer comprises at least one of Alq 3 , 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP), 4,7-diphenyl-1,10-phenanthroline (Bphen), 3-(4-biphenylyl)-4-phenyl-5-tert-butylphenyl-1,2,4-triazole (TAZ), 4-(naphthalen-1-yl)-3,5-diphenyl-4H-1,2,4-triazole (NTAZ), 2-(4-biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole (tBu-PBD), bis(2-methyl-8-quinolinolato-N1,O8)-(1,1′-biphenyl-4-olato)aluminum (BAlq), beryllium bis(benzoquinolin-10-olate (Bebq 2 ), and 9,10-di(naphthalene-2-yl)anthrascene (ADN).

16. The organic light-emitting device of claim 14 , wherein the electron transport layer further comprises a lithium (Li) complex.

17. The organic light-emitting device of claim 14 , wherein the electron transport region further comprises a hole blocking layer between the electron transport layer and the emission layer.

18. The organic light-emitting device of claim 1 , wherein the hole transport region comprises at least one of a hole injection layer, a hole transport layer, and an electron blocking layer.

19. The organic light-emitting device of claim 1 , wherein at least one of the first sub-pixel, the second sub-pixel, and the third sub-pixel comprise an auxiliary layer.

20. The organic light-emitting device of claim 19 , wherein the auxiliary layer is between the hole transport region and the first emission layer, between the hole transport region and the second emission layer, or between the hole transport region and the third emission layer.

Assignees

• Samsung Display Co Ltd

Inventors

• Kim Eungdo
• Kim Dongchan
• Kim Wonjong
• Seo Dongkyu
• Im Dahea
• Yim Sanghoon
• Han Wonsuk

Classifications

• H01L51/5221

  Electricity · mapped topic

• H01L2251/301

  Electricity · mapped topic

• H01L51/0081

  Electricity · mapped topic

• H01L51/5084

  Electricity · mapped topic

• H01L51/5072 Primary

  Electricity · mapped topic