Supercritical fluid device

Patent metadata

Field	Value
Publication number	US-10180412-B2
Application number	US-201515557769-A
Country	US
Kind code	B2
Filing date	Mar 19, 2015
Priority date	Mar 19, 2015
Publication date	Jan 15, 2019
Grant date	Jan 15, 2019

Abstract

Provided is a supercritical fluid device equipped with a back pressure regulator for creating a pressurized state in which a mobile phase in a separation/extraction unit of an analysis flow passage is kept in a supercritical fluid state. One end of a pipe is connected to an outlet side of the back pressure regulator, and the other end of the pipe is open to the atmosphere. A heating unit is provided on the pipe, and the heating unit includes a plurality of electrically independent heaters arranged on mutually different portions of the pile along the pipe. A power supply controller is connected to the heaters, and the power supply controller is configured to supply heating power to one or more heaters selected among the plurality of heaters, but to not supply heating power to the other heaters.

First claim

The invention claimed is:

1. A supercritical fluid device comprises:
a supercritical fluid analysis unit, the supercritical fluid analysis unit including an analysis flow passage equipped with a separation/extraction unit configured to separate or extract a sample component, a fluid feeder equipped with a pump and configured to supply a mobile phase which becomes a supercritical fluid to the analysis flow passage arranged on an upstream side of the separation/extraction unit, and a back pressure regulator arranged on a downstream side of the separation/extraction unit with respect to a flow of the mobile phase and configured to create a pressurized state in which the mobile phase in the separation/extraction unit is kept in a supercritical fluid state;
a pipe having one end connected to an outlet side of the back pressure regulator and the other end opened to atmosphere;
a heating unit equipped with a plurality of electrically independent heaters arranged on mutually different portions of the pipe along the pipe; and
a power supply controller connected to the heaters and configured to supply heating power source to one or a plurality of heaters selected from among the plurality of heaters but to not supply heating power to the other heaters,
wherein the power supply controller comprises:
a positional information holder that holds positional information indicating a freezing portion of the pipe for a plurality of parameters of the supercritical fluid analysis unit including an inner diameter of the pipe and a flow rate of liquefied carbon dioxide in the mobile phase,
input circuitry configured to input a parameter during an operation of the supercritical fluid device, and
a control circuit configured to selectively supply power to a heater for preventing freezing of the pipe among the heaters based on the parameter input from the input circuitry and positional information held in the positional information holder.

2. The supercritical fluid device as recited in claim 1 ,
wherein the power supply controller is equipped with a switch and a control circuit for controlling power supply to each heater.

3. The supercritical fluid device as recited in claim 2 ,
wherein the switch and the control circuit are configured to set a current value.

4. The supercritical fluid device as recited in claim 1 ,
wherein the heaters are arranged substantially over an entire length of the pipe.

5. The supercritical fluid device as recited in claim 1 ,
wherein the heater is a film heater wound around the pipe.

Assignees

• Shimadzu Corp

Inventors

• Goto Hiroomi
• KAJIYAMA Risa
• Mori Takahiro

Classifications

• G01N30/30 Primary

  of temperature · CPC title

• G01N2030/3053

  using resistive heating · CPC title

• G01N2030/3007

  same temperature for whole column · CPC title

• G01N2030/3038

  temperature control of column exit, e.g. of restrictors · CPC title

• B01D15/40

  using supercritical fluid as mobile phase or eluent · CPC title