Organosilica materials and uses thereof
US-2016168333-A1 · Jun 16, 2016 · US
US10179839B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10179839-B2 |
| Application number | US-201715802680-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 3, 2017 |
| Priority date | Nov 18, 2016 |
| Publication date | Jan 15, 2019 |
| Grant date | Jan 15, 2019 |
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Provided herein are compositions and methods for use of an organosilica material comprising a copolymer of at least one monomer of Formula [R 1 R 2 SiCH 2 ] 3 (I), wherein, R 1 represents a C 1 -C 4 alkoxy group; and R 2 is a C 1 -C 4 alkoxy group or a C 1 -C 4 alkyl group; and at least one other monomer of Formula [(Z 1 O) x Z 2 3-x Si—Z 3 —SZ 4 ] (II), wherein, Z 1 represents a hydrolysable functional group; Z 2 represents a C 1 -C 10 alkyl or aryl group; Z 3 represents a C 2 -C 11 cyclic or linear hydrocarbon; Z 4 is either H or O 3 H; and x represents any one of integers 1, 2, and 3. The composition may be used as a support material to covalently attach transition metal cations, as a sorbent for olefin/paraffin separations, as a catalyst support for hydrogenation reactions, as a precursor for highly dispersed metal nanoparticles, or as a polar sorbent for crude feeds.
Opening claim text (preview).
The invention claimed is: 1. An organosilica material comprising a copolymer of at least one monomer of Formula [R 1 R 2 SiCH 2 ] 3 (I), wherein: R 1 represents a C 1 -C 4 alkoxy group; and R 2 is a C 1 -C 4 alkoxy group or a C 1 -C 4 alkyl group; and at least one other monomer of Formula [(Z 1 O) x Z 2 3-x Si—Z 3 —SZ 4 ] (II), wherein: Z 1 represents a hydrolysable functional group; Z 2 represents a C 1 -C 10 alkyl or aryl group; Z 3 represents a C 2 -C 11…
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