Radical crosslinking of polyether carbonate polyols that have electron-poor and electron-rich double bonds

Patent metadata

Field	Value
Publication number	US-10179835-B2
Application number	US-201414914308-A
Country	US
Kind code	B2
Filing date	Sep 2, 2014
Priority date	Sep 5, 2013
Publication date	Jan 15, 2019
Grant date	Jan 15, 2019

Abstract

The present invention relates to a method for producing polyether carbonate polyols, the polyether carbonate polyols having electron-poor and electron-rich double bonds, said method preferably comprising the steps of (a) providing a suspending agent and/or an H-functional starter compound and a DMC catalyst, 03) adding at least one epoxide and (y) adding carbon dioxide, an epoxide that does not contain an unsaturated group, and at least two unsaturated compounds, the unsaturated compounds in method step (y) being selected from the group comprising unsaturated epoxides and unsaturated cyclic anhydrides, and one of the unsaturated compounds having an electron-rich double bond and one of the unsaturated compounds having an electron-poor double bond. The invention also relates to the crosslinking of polyether carbonate polyols, the polyether carbonate polyols having electronpoor and electron-rich double bonds, and to the crosslinked polyether carbonates obtainable therefrom.

First claim

The invention claimed is:

1. A process for preparing polyethercarbonate polyols, the polyethercarbonate polyols comprising double bonds, comprising the steps of:
(α) initially introducing a catalyst and
(αα) a suspension medium which contains no H-functional groups and/or
(αβ) an H-functional starter compound

(γ) metering in carbon dioxide, an epoxide which contains no unsaturated group, and at least two unsaturated compounds,
wherein
the unsaturated compounds metered in step (γ) are selected from unsaturated epoxides and/or unsaturated cyclic anhydrides, and
(γ1) one of the unsaturated compounds comprises a double bond comprising at least one substituent selected from the group of -0X 1 , —OCOX 1 , —X 1 , —CH 2 OX 1 and/or —CH═CHX 1 , where X 1 in each case is substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted aryl or a substituted or unsubstituted methylene chain;
(γ2) and another of the unsaturated compounds comprises a double bond comprising at least one substituent selected from the group of —F, —Cl, —Br, —I, —COH, COX 2 , —COOX 2 , —C≡N and/or —NO 2 or is an unsaturated, substituted or unsubstituted cyclic anhydride of an organic dicarboxylic acid, where X 2 in each case is substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted aryl or a substituted or unsubstituted methylene chain, wherein the molar ratio of the double bonds with substituents as per (γ1) to double bonds with substituents as per (γ2), including structural units in a polymer that originated from cyclic anhydrides, is less than or equal to 3:1 and greater than or equal to 1:3;
and where additionally, if no H-functional starter compound is introduced in step (α), step (γ) comprises the metering in of an H-functional starter compound.

2. The process as claimed in claim 1 , further comprising the following step (β) between step (α) and step (γ):
(β) metering in of at least one epoxide.

3. The process as claimed in claim 1 , wherein the catalyst is a double metal cyanide catalyst.

4. The process as claimed in claim 1 , wherein the unsaturated compound as per (γ2) is an unsaturated cyclic anhydride having a double bond adjacent to a carbonyl group.

5. The process as claimed in claim 1 , wherein the unsaturated compound as per (γ2) is an unsaturated epoxide selected from the group of glycidyl esters of α,β-unsaturated acids.

6. The process as claimed in claim 1 , wherein the temperature in step (γ) is greater than or equal to 60° C. and less than or equal to 150° C.

7. The process as claimed in claim 1 , wherein the unsaturated compound as per (γ1) is selected from the group consisting of allyl glycidyl ether, vinylcyclohexene oxide, cyclooctadiene monoepoxide, cyclododecatriene monoepoxide, butadiene monoepoxide, isoprene monoepoxide, limonene oxide, 1,4-divinylbenzene monoepoxide, 1,3-divinylbenzene monoepoxide, glycidyl esters of unsaturated fatty acids and/or partially epoxidized fats, and oils.

8. The process as claimed in claim 1 , wherein the molar ratio is less than or equal to 2:1 and greater than or equal to 1:2.

9. The process as claimed in claim 1 , wherein the molar ratio is less than or equal to 1.3:1 and greater than or equal to 1:1.3.

Assignees

• Covestro Deutschland Ag

Inventors

• Müller Thomas E
• Gürtler Christoph
• Subhani Muhammad A
• Köhler Burkhard
• Leitner Walter

Classifications

• C08G64/34 Primary

  and cyclic ethers · CPC title

• C08G65/2663

  Metal cyanide catalysts, i.e. DMC's · CPC title

• C09J169/00

  Adhesives based on polycarbonates; Adhesives based on derivatives of polycarbonates · CPC title

• C08G64/42

  Chemical after-treatment · CPC title

• C08L69/00

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title