Method for enhancing uniformity of crystallized succinic acid and purified succinic acid produced by the same

Patent metadata

Field	Value
Publication number	US-10179758-B2
Application number	US-201715615890-A
Country	US
Kind code	B2
Filing date	Jun 7, 2017
Priority date	Jun 15, 2016
Publication date	Jan 15, 2019
Grant date	Jan 15, 2019

Abstract

A method for crystallizing succinic acid includes agitating a succinic acid reaction solution with a jet-flow agitator that is rotated at low speed and has a low volume power density; compared with the conventional agitators, the jet-flow agitator helps increase the uniformity of succinic acid particles, shorten the time required for crystallizing succinic acid, and raise the yield of the crystallized succinic acid as well as purity of crystallized succinic acid having a purity of 99.8-99.9%.

First claim

What is claimed is:

1. A method for enhancing uniformity of crystallized succinic acid, comprising the steps of:
a) preparing a crystallization tank containing therein a jet-flow agitator composed of a rotating shaft and a plurality of inclined converging-tube blades driven by the rotating shaft into rotation;
b) pouring a solvent into the crystallization tank of the step a), wherein the solvent is one selected from the group consisting of water, methanol and ethanol;
c) adding succinic acid solids to the solvent of the step b) by weight ratio of the solvent to the succinic acid solids ranged from 2.0 to 10.0 to form a reaction solution;
d) activating the jet-flow agitator of the step a) to have the inclined converging-tube blades thereof rotated at 50-500 rpm to cause the reaction solution of the step c) to undergo irregular fluctuations or mixing to disperse the succinic acid solids uniformly in the reaction solution;
e) setting a cooling rate of the crystallization tank to 10-35° C. per hour, and allowing the succinic acid solids of the reaction solution to undergo a crystallization and purification reaction for 1-8 hours at a reaction pressure of 5-100 lbf/in 2 and a reaction temperature of 0-90° C.; and
f) after the crystallization and purification reaction of step e) completed, filtering out and removing the solvent from the reaction solution of the step e) to obtain solid residues, and drying the solid residues to obtain final products of high-purity succinic acids having a purity of 99.8-99.9%.

2. The method of claim 1 , wherein the inclined converging-tube blades of the jet-flow agitator of the step a) are formed as inclined nozzle blades or inclined conical spring blades.

3. The method of claim 2 , wherein in the step b) the ethanol is used as the solvent.

4. The method of claim 2 , wherein in the step c), the weight ratio of the solvent to the succinic acid solids ranges from 2.3 to 7.0.

5. The method of claim 2 , wherein in the step c), the weight ratio of the solvent to the succinic acid solids ranges from 4.0 to 7.0.

6. The method of claim 2 , wherein in the step c), the weight ratio of the solvent to the succinic acid solids was equivalent to 4.

Assignees

• Nanya Plastics Corp

Inventors

• Liao Te-Chao
• Chuang Jung-Jen
• Chen Cheng-Hsun
• Tsai Chia-Ruey
• Chen Chung-Yu

Classifications

• C07C55/10 Primary

  Succinic acid · CPC title

• C07B2200/13

  Crystalline forms, e.g. polymorphs · CPC title

• C07C31/02

  Monohydroxylic acyclic alcohols · CPC title

• C07C51/43 Primary

  by change of the physical state, e.g. crystallisation · CPC title

• B01F7/00541

  Operations & Transport · mapped topic