Fluorescent displays containing an interlayer film of polyvinylacetal which comprises plasticizers

Patent metadata

Field	Value
Publication number	US-10179442-B2
Application number	US-201414760649-A
Country	US
Kind code	B2
Filing date	Jan 10, 2014
Priority date	Jan 11, 2013
Publication date	Jan 15, 2019
Grant date	Jan 15, 2019

Abstract

A fluorescent display suitable for use in a heads up display contains a laminated glass structure containing a plasticized polyvinyl acetal film, at least one fluorophore, and at least one UV absorber, wherein the fluorophore and UV absorber are and remain spatially separated in the laminating film such that UV light projected from a display generating projector remains able to activate the fluorophores, and a UV component of sunlight has lessened ability to activate the fluorophore.

First claim

What is claimed is:

1. A visually observable fluorescent display comprising a glass/glass laminate with a side S facing away from an observer of the fluorescent display and a side B facing the observer of the fluorescent display, comprising at least one interlayer film comprising one or more fluorophores, each fluorophore having an excitation wavelength, one or more UV absorbers different from the fluorophores, and plasticized polyvinyl acetal, wherein the UV absorbers and the fluorophores in the interlayer film are disposed spatially separately from each other in a thickness direction of the interlayer film such that the fluorophores are excited by UV radiation impinging upon the laminate through side B despite the presence of the UV absorbers, wherein the UV absorbers are disposed facing side S of the fluorescent display, the at least one interlayer film comprising:
a) at least one first layer of plasticized polyvinyl acetal, said first layer comprising at least one UV absorber with a low tendency to diffuse, said first layer being disposed towards side S of the fluorescence display, and
b) at least one fluorophore disposed in said first layer, each fluorophore having a low tendency to diffuse, said fluorophore(s) being disposed towards side B of the fluorescent display,
wherein the low tendencies of the fluorophore and UV absorber to diffuse are both such that any diffusion does not prevent excitation of the fluorophore by light impinging upon side B to provide a visible display.

2. The fluorescent display of claim 1 , wherein the interlayer film comprises at least one layer of plasticized polyvinyl acetal further comprising at least one light stabilizer for suppressing radical chain reactions.

3. The visually observable fluorescent display of claim 1 , wherein the UV absorbers having a low tendency to diffuse are polymeric UV absorbers, UV absorbers containing ionic groups, UV absorbing inorganic nanoparticles, organic UV absorbers which are insoluble in the plasticized polyvinyl acetal, UV absorbers chemically bonded to the polyvinyl acetal, UV absorbers having a solubility in the plasticizer of the plasticized polyvinyl acetal of less than 5 g/L at 20° C., or mixtures thereof and wherein the fluorophore having a low tendency to diffuse is a fluorophore selected from the group consisting of fluorescing organic polymers, fluorescing inorganic nanoparticles, and fluorophores having a solubility in the plasticizer of the plasticized polyvinyl acetal film of less than 5 g/L at 20° C., fluorophores containing ionic groups, and mixtures thereof.

4. The visually observable fluorescent display of claim 1 , wherein the side S facing the sunlight exhibits a UV transmission T uv (400) of less than 30% in a composite measurement between 2×2.1 mm clear glass according to ISO 13837, Convention “A” (2008).

5. The visually observable fluorescent display of claim 1 , wherein the side S facing the sunlight exhibits a UV transmission T uv of not more than 50% in a composite measurement between 2×2.1 mm clear glass and with the recording of a UV/VIS transmission spectrum according to ISO 13837 (2008).

6. A visually observable fluorescent display comprising a glass/glass laminate with a side S facing away from an observer of the fluorescent display and a side B facing the observer of the fluorescent display, comprising at least one interlayer film comprising one or more fluorophores each having an excitation wavelength, a UV absorber different from the fluorophores, and plasticized polyvinyl acetal, wherein the UV absorbers and the fluorophores in the interlayer are disposed spatially separately from each other such that the fluorophores are excited by UV radiation despite the presence of the UV absorbers, wherein the UV absorbers are disposed towards side S of the fluorescent display, the at least one interlayer film comprising:
a) at least one first layer of plasticized polyvinyl acetal,
b) at least one fluorophore, disposed at a first side of said first layer of plasticized polyvinyl acetal facing side B of the fluorescent display, each fluorophore having a low tendency to diffuse, and
c) at least one UV absorber having a low tendency to diffuse disposed in a second side of said first layer, said UV absorber being disposed toward side S of the fluorescent display, the low tendencies of the fluorophore and UV absorbers to diffuse being such that any diffusion does not prevent excitation of the fluorophore by light impinging upon side B to provide visible display.

7. The fluorescent display of claim 6 , wherein the interlayer film comprises at least one layer of plasticized polyvinyl acetal further comprising at least one light stabilizer for suppressing radical chain reactions.

8. The visually observable fluorescent display of claim 6 , wherein the UV absorber having a low tendency to diffuse are polymeric UV absorbers, UV absorbers containing ionic groups, UV absorbing inorganic nanoparticles, organic UV absorbers which are insoluble in the plasticized polyvinyl acetal, UV absorbers chemically bonded to the polyvinyl acetal, or UV absorbers having a solubility in the plasticizer of the plasticized polyvinyl acetal of less than 5 g/L at 20° C. or mixtures thereof, and wherein the fluorophore having a low tendency to diffuse is a fluorophore selected from the group consisting of fluorescing organic polymers, fluorescing inorganic nanoparticles, and fluorophores having a solubility in the plasticizer of the plasticized polyvinyl acetal film of less than 5 g/L at 20° C., fluorophores containing ionic groups, and mixtures thereof.

9. The visually observable fluorescent display of claim 6 , wherein the side S facing the sunlight exhibits a UV transmission T uv (400) of less than 30% in a composite measurement between 2×2.1 mm clear glass according to ISO 13837, Convention “A” (2008).

10. The visually observable fluorescent display of claim 1 , wherein the plasticizer content of the interlayer film is from 18 to 36 weight percent based on the total weight of the interlayer film.

11. The visually observable fluorescent display of claim 1 , wherein the fluorophore(s) and/or the UV absorber(s) are applied to respective surfaces of said first layer by coating, printing, transfer, or spraying onto the surface.

12. The visually observable fluorescent display of claim 1 , further comprising at least one further plasticized polyvinyl acetal layer in direct contact with said first layer.

13. The visually observable display of claim 1 , comprising a plurality of plasticized polyvinyl acetal layers, one of said plurality of polyvinyl acetal layers being said first polyvinyl acetal layer, the interlayer film containing no barrier film.

14. The visually observable fluorescent display of claim 6 , wherein the plasticizer content of the interlayer film is from 18 to 36 weight percent based on the total weight of the interlayer film.

15. The visually observable fluorescent display of claim 6 , wherein the fluorophore(s) and/or the UV absorber(s) are applied to respective surfaces of said first layer by coating, printing, transfer, or spraying onto the surface.

16. The visually observable fluorescent display of claim 6 , further comprising at least one further plasticized polyvinyl acetal layer in direct contact with said first layer.

17. The visually observable display of claim 6 , comprising a plurality of plasticized polyvinyl acetal layers, one of said plurality of polyvinyl acetal layers being said first polyvinyl acetal layer, the interlayer film containing no barrier film.

18. The visually observable

Assignees

• Kuraray Europe Gmbh

Inventors

• Keller Uwe
• Lellig Philipp
• Beekhuizen Jan

Classifications

• B32B2605/00

  Vehicles · CPC title

• B32B17/10678

  comprising UV absorbers or stabilizers, e.g. antioxidants · CPC title

• Y10T428/3163

  Next to acetal of polymerized unsaturated alcohol [e.g., formal butyral, etc.] · CPC title

• B32B17/10761

  containing vinyl acetal · CPC title

• B32B17/10036 Primary

  comprising two outer glass sheets · CPC title