Mesoporous ternary composite material and corresponding method of preparation

Patent metadata

Field	Value
Publication number	US-10179327-B2
Application number	US-201615176417-A
Country	US
Kind code	B2
Filing date	Jun 8, 2016
Priority date	Mar 27, 2014
Publication date	Jan 15, 2019
Grant date	Jan 15, 2019

Abstract

Mesoporous ternary composite materials and a corresponding preparation method are described herein. The method includes the following steps: (1) adding hydrochloric acid and acetic acid into an ethanol solution to prepare a dissolving system; (2) adding a surfactant into the dissolving system and fully stirring for dissolution; (3) adding copper nitrate, manganese nitrate solution and tetrabutyl titanate into the mixed liquid obtained from step (2) and evenly stirring; (4) transferring the mixture obtained from step (3) into petri dishes and obtaining transparent films after drying; and (5) calcinating the transparent films to obtain mesoporous ternary composite materials. The materials prepared are ordered mesoporous materials with high specific surface areas and high dispersion degree of every component.

First claim

What is claimed:

1. A method for preparing mesoporous ternary composite materials, comprising the following steps:
(a) adding hydrochloric acid and acetic acid into an ethanol solution to prepare a dissolving system;
(b) adding a surfactant into the dissolving system and fully stirring for dissolution;
(c) adding copper nitrate, manganese nitrate solution and tetrabutyl titanate into the mixed liquid obtained from step (b) and evenly stirring;
(d) transferring the mixture obtained from step (c) into petri dishes and obtaining transparent films after drying; and
(e) calcinating the transparent films to obtain mesoporous ternary composite materials.

2. The method according to claim 1 , wherein in the step (a) the concentrations of the hydrochloric acid and the acetic acid in the dissolving system are 30 to 50 g/L and 60 to 100 g/L, respectively.

3. The method according to claim 1 , wherein in the step (b), the surfactant comprises a polyoxyethylene-polyoxypropylene-polyoxyethylene triblock copolymer, and the mass ratio of surfactant to ethanol is 1:10 to 1:20.

4. The method according to claim 3 , wherein in the step (c), the copper nitrate, the manganese nitrate solution and the tetrabutyl titanate are added at element mole ratio of Cu:Mn:Ti =(1-5):(1-5):(40-48) and then vigorously stirring at the temperature of 40° C. for 1 to 3 h with the rotating speed at 300 to 500 r/min; wherein, the mass ratio of the tetrabutyl titanate to surfactant is 1:1 to 3:1.

5. The method according to claim 1 , wherein in the step (d), the mixture is placed under conditions at a temperature of 40° C. and a relative humidity of 40 to 60%, and stands for 12 to 24 h for volatilization.

6. The method according to claim 1 , wherein in the step (e), calcinating is conducted at 350 to 350° C. for 5 h.

7. The method of claim 1 , wherein the surfactant comprises a polyoxyethylene-polyoxypropylene-polyoxyethylene triblock copolymer having the molecular formula (ethylene oxide) 106 (propylene oxide) 70 (ethylene oxide) 106 .

Assignees

• Univ Tongji

Inventors

• Fan Jianwei
• Min Hongyang
• Jiang Xu
• Li Dandan
• Chen Wangyuan
• Chen Minjun

Classifications

• B01J35/1047

  Operations & Transport · mapped topic

• B01J2523/00

  Constitutive chemical elements of heterogeneous catalysts · CPC title

• B01J35/026

  Operations & Transport · mapped topic

• B01J2523/47

  Titanium · CPC title

• B01J35/023

  Operations & Transport · mapped topic