Phosphine-imino-quinoline and related ligands for use in ethylene oligomerization processes
US-2024360052-A1 · Oct 31, 2024 · US
US10179326B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10179326-B2 |
| Application number | US-201514955609-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 1, 2015 |
| Priority date | Jan 23, 2012 |
| Publication date | Jan 15, 2019 |
| Grant date | Jan 15, 2019 |
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Embodiments of the present disclosure also provide for a supported fused Fe catalyst, a method of making the supported fused Fe catalyst, methods of hydrocarbon decomposition, and the like.
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We claim at least the following: 1. A method of selectively producing hydrogen or ethane from methane, comprising: selecting a first temperature to produce a first selected product, wherein the first temperature is selected to favor either a predominately (a) hydrogen and solid carbon product or (b) ethane and hydrogen product; contacting a feed gas containing methane, with a single catalyst at the first temperature to produce the first selected product, wherein the single catalyst is a supported fused FeAl 2 O 4 catalyst; selecting a second temperature to produce a second selected product, wherein the second selected product is different from the first selected product; and contacting a feed gas containing methane, with the single catalyst at the second temperature to produce the second selected product. 2. The method of claim 1 , wherein Fe is about 5 to 65 wt. % of the single catalyst. 3. The method of claim 1 , wherein the support includes one or more of silicon oxide, aluminum oxide, titanium oxide, zirconium oxide, magnesium oxide, cerium oxide, zinc oxide, molybdenum oxide, iron oxide, nickel oxide, cobalt oxide, and graphite. 4. The method of claim 1 , wherein the fused catalyst includes red mud generated from industrial production of aluminum.
Composition of support materials · CPC title
containing a catalytic decomposition step · CPC title
Ruthenium, rhodium, osmium or iridium · CPC title
Iron · CPC title
Platinum catalysts · CPC title
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