Low-temperature liquid metal batteries for grid-scaled storage

Patent metadata

Field	Value
Publication number	US-10177405-B2
Application number	US-201314045967-A
Country	US
Kind code	B2
Filing date	Oct 4, 2013
Priority date	Oct 5, 2012
Publication date	Jan 8, 2019
Grant date	Jan 8, 2019

Abstract

An electrochemical cell and its method of operation includes an electrolyte having a binary salt system of an alkali hydroxide and a second alkali salt. The anode, cathode, and electrolyte may be in the molten phase. The cell is operational for both storing electrical energy and as a source of electrical energy as part of an uninterruptible power system. The cell is particularly suited to store electrical energy produced by a renewable energy source.

First claim

What is claimed is:

1. An electrochemical storage device comprising:
a positive electrode comprising a first phase including a metal alloy of lead and bismuth or lead and antimony;
an electrolyte comprising a binary salt system of an alkali metal, the binary salt system comprising a hydroxide-iodide eutectic salt of the alkali metal, the electrolyte defining first and second interfaces, the positive electrode being in contact with the electrolyte at the first interface, and the electrolyte enabling transport of a cation of the alkali metal from the positive electrode to the negative electrode or from the negative electrode to the positive electrode; and
a negative electrode, separated from the positive electrode, comprising a third phase including the alkali metal, the negative electrode being in contact with the electrolyte at the second interface,
where the alkali metal is oxidized at the positive electrode and reduced at the negative electrode during charging, and is reduced at the positive electrode and oxidized at the negative electrode during discharging,
the first phase and electrolyte have a melting temperature independently selected from 200° C. to 300° C., and
the third phase has a melting temperature selected such that the third phase is liquid at the selected melting temperatures of the first phase and electrolyte, so that the first phase, the electrolyte, and the third phase are liquid at a selected temperature from 200° C. to 300° C.

2. The device according to claim 1 , wherein the binary salt system comprises a second salt of the alkali metal selected from the group consisting of a halide, a sulfate, a carbonate, and any combination thereof.

3. The device according to claim 1 , wherein the alkali metal is sodium.

4. The device according to claim 1 , wherein the first phase further comprises the alkali metal.

5. An electrochemical storage device comprising:
an electrolyte comprising a hydroxide-iodide eutectic salt of an alkali metal, the electrolyte defining a first interface and enabling transport of a cation of the alkali metal through the electrolyte; and
a positive electrode comprising a first phase including a metal alloy of lead and bismuth or lead and antimony, the positive electrode being in contact with the electrolyte at the first interface,
where the alkali metal is oxidized at the positive electrode and reduced at the negative electrode during charging, and is reduced at the positive electrode and oxidized at the negative electrode during discharging,
the first phase and electrolyte have a melting temperature independently selected from 200° C. to 300° C.

6. The device according to claim 5 , wherein the binary salt system comprises a second salt of the alkali metal selected from the group consisting of a halide, a sulfate, a carbonate, and any combination thereof.

7. The device according to claim 5 , wherein the alkali metal is sodium.

8. A method of exchanging electrical energy with an external circuit, the method comprising:
providing the electrochemical cell of claim 1 ;
connecting the cell to an external circuit; and
operating the external circuit so as to drive transfer of the cation of the alkali metal between the first phase and the third phase.

9. The method according to claim 8 , wherein the positive electrode further comprises the alkali metal, and the external circuit drives the cation of the alkali metal from the positive electrode to the negative electrode.

10. The method according to claim 8 , wherein the alkali metal is sodium.

11. The device according to claim 1 , wherein the binary salt system consists essentially of a hydroxide-iodide eutectic salt of the alkali metal.

12. An electrochemical storage device comprising:
an electrolyte consisting essentially of a hydroxide-iodide eutectic salt of an alkali metal, the electrolyte defining a first interface and enabling transport of a cation of the alkali metal through the electrolyte; and
a positive electrode comprising a first phase including a metal alloy of lead and bismuth or lead and antimony, the positive electrode being in contact with the electrolyte at the first interface,
where the alkali metal is oxidized at the positive electrode and reduced at the negative electrode during charging, and is reduced at the positive electrode and oxidized at the negative electrode during discharging,
the first phase and electrolyte have a melting temperature independently selected from 200° C. to 300° C.

Assignees

• Massachusetts Inst Technology

Inventors

• Spatocco Brian L
• Burke Paul J
• Sadoway Donald R

Classifications

• H01M10/054

  Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium · CPC title

• H01M10/0562 Primary

  Solid materials · CPC title

• H01M10/20

  Semi-lead accumulators, i.e. accumulators in which only one electrode contains lead · CPC title

• H01M10/399

  Cells with molten salts · CPC title

• H01M10/39

  working at high temperature · CPC title