Polyolefin-based antistatic fiber, being a single component or a conjugate type fiber, and nonwoven fabric including the same

Patent metadata

Field	Value
Publication number	US-10174446-B2
Application number	US-201213985044-A
Country	US
Kind code	B2
Filing date	Feb 10, 2012
Priority date	Feb 14, 2011
Publication date	Jan 8, 2019
Grant date	Jan 8, 2019

Abstract

A polyolefin-based antistatic fiber, wherein a polyethylene resin com¬position containing polyethylene resin (A) obtained using a metal-locene catalyst and high molecular antistatic agent (B) forms a fiber surface, and the total amount (at 90° C. for 30 minutes) of volatile organic compounds having up to 20 carbon atoms is 10 ug/g or less. The polyolefin-based antistatic fiber may be in the form of a sheath-core type conjugate fiber in which the polyolefin resin composition forms the sheath. A nonwoven fabric formed from the polyolefin-based antistatic fiber, preferably having a defined surface resistance value, as well as a composite nonwoven fabric and formed body obtained using the nonwoven fabric are further disclosed.

First claim

The invention claimed is:

1. A polyolefin-based antistatic fiber, wherein a fiber surface thereof is formed by a polyethylene resin composition that contains: polyethylene resin (A) obtained using a metallocene catalyst, high molecular antistatic agent (B), and 5 to 20 parts by weight of at least one kind of low density polyethylene resin (C) selected from low density polyethylene resin (c1) obtained using a metallocene catalyst and having a melt index, measured at 190° C. under 2.16 kg load, of 10 to 100 g/10 minutes and a density of 0.87 to 0.92 g/cm 3 , and linear low density polyethylene resin (c2) obtained using the metallocene catalyst and having a melt index, measured at 190° C. under 2.16 kg load, of 10 to 100 g/10 minutes and a density of 0.91 to 0.94 g/cm 3 based on 100 parts by weight of polyethylene resin (A), and the total amount, at 90° C. for 30 minute, of volatile organic compounds having up to 20 carbon atoms is 10 μg/g or less, wherein the high molecular antistatic agent (B) is a block copolymer comprising polyethers having a hydrophilic group and is mixed in a ratio of 5 to 30 parts by weight based on 100 parts by weight of the polyethylene resin (A), the polyolefin-based antistatic fiber is a sheath-core type conjugate fiber in which the polyethylene resin composition forms a sheath component completely covering the fiber surface, a core component contains high density polyethylene resin (D) obtained using a metallocene catalyst or Ziegler-Natta catalyst and having a melt index, measured at 190° C. under 2.16 kg load, of 10 to 100 g/10 minutes and a density of 0.94 to 0.97 g/cm 3 , and, based on 100 parts by weight of the high density polyethylene resin (D), 5 to 20 parts by weight of linear low density polyethylene resin (e2) obtained using the metallocene catalyst or Ziegler-Natta catalyst and having a melt index, measured at 190° C. under 2.16 kg load, of 10 to 100 g/10 minutes and a density of 0.91 to 0.94 g/cm 3 , a weight ratio of the core component to the sheath component is 50/50, and a weight percentage of (e2) in a combination of (A), (B), (C), (D) and (e2) ranges from 2.38% to 8.3%.

2. The polyolefin-based antistatic fiber according to claim 1 , wherein the polyethylene resin (A) is a high density polyethylene having a density of 0.94 to 0.97 g/cm 3 .

3. The polyolefin-based antistatic fiber according to claim 1 , wherein a melt index, measured at 190° C. under 2.16 kg load, of the polyethylene resin (A) is 10 to 100 g/10 minutes.

4. The polyolefin-based antistatic fiber according to claim 1 , wherein a melting point of the core component is higher than a melting point of the sheath component by 10° C. or more in the melting point measured at a heating rate of 10° C./minute by means of a differential scanning calorimeter (DSC).

5. The polyolefin-based antistatic fiber according to claim 1 , wherein the fiber is a continuous fiber.

6. The polyolefin-based antistatic fiber according to claim 5 , wherein the fiber is manufactured by any one of a manufacturing method, selected from a spunbond method or a meltblown method.

7. A nonwoven fabric obtained using the fiber according to claim 1 .

8. The nonwoven fabric according to claim 7 , wherein a surface resistance value of the nonwoven fabric is in the range of 10 3 to 10 13 Ω.

9. A composite nonwoven fabric, wherein second layer is laminated on the nonwoven fabric according to claim 7 .

10. A formed body obtained using the nonwoven fabric according to claim 7 .

11. A composite nonwoven fabric, wherein second layer is laminated on the nonwoven fabric according to claim 8 .

12. A formed body obtained using the nonwoven fabric according to claim 8 .

13. A formed body obtained using the composite nonwoven fabric according to claim 9 .

14. The polyolefin-based antistatic fiber according to claim 1 , wherein the linear low density polyethylene resin (e2) comprises a copolymer with an α-olefin of 3 to 12 carbon atoms based essentially on ethylene.

Assignees

• Maehara Hiroyuki
• Yoshida Shuhei
• Jnc Corp
• Jnc Fibers Corp

Inventors

• Maehara Hiroyuki
• Yoshida Shuhei

Classifications

• Y10T442/696

  Including strand or fiber material which is stated to have specific attributes [e.g., heat or fire resistance, chemical or solvent resistance, high absorption for aqueous compositions, water solubility, heat shrinkability, etc.] · CPC title

• D01F8/06 Primary

  with at least one polyolefin as constituent · CPC title

• D01F1/09 Primary

  for making electroconductive or anti-static filaments · CPC title

• D04H3/007 Primary

  Addition polymers · CPC title

• Y10T428/2929

  Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type] · CPC title