Electrochemical reduction device and method for manufacturing hydride of aromatic compound

Patent metadata

Field	Value
Publication number	US-10174431-B2
Application number	US-201615008870-A
Country	US
Kind code	B2
Filing date	Jan 28, 2016
Priority date	Jul 30, 2013
Publication date	Jan 8, 2019
Grant date	Jan 8, 2019

Abstract

An electrochemical reduction device includes an electrode unit, a power control unit, a concentration measurement unit, and a control unit. The electrode unit includes an electrolyte membrane, a reduction electrode, and an oxygen evolving electrode. The control unit controls the power control unit such that a current value I flowing through the reduction electrode and the oxygen evolving electrode satisfies Equation, I≤Imax (C). In Equation, a maximum current value Imax (C) is defined according to a concentration C of an aromatic compound obtained by the concentration measurement unit such that Faraday efficiency is to be a predetermined value or more.

First claim

The invention claimed is:

1. An electrochemical reduction device comprising:
an electrode unit being configured by including an electrolyte membrane having ionic conductivity, a reduction electrode that is provided on one side of the electrolyte membrane and includes an reduction catalyst for hydrogenating a benzene ring of an aromatic compound, and an oxygen evolving electrode that is provided on the other side of the electrolyte membrane;
a power control unit that applies voltage Va to one electrode of the reduction electrode and the oxygen evolving electrode so as to produce an electric difference with respect to other electrode thereof;
a concentration measurement unit that measures a concentration of the aromatic compound supplied to the reduction electrode; and
a control unit that controls the power control unit such that a current value I flowing through the reduction electrode and the oxygen evolving electrode satisfies a relation of I≤Imax (C) with respect to a maximum current value Imax (C) defined according to the concentration C of the aromatic compound obtained by the concentration measurement unit;
wherein the maximum current value Imax (C) is defined such that Faraday efficiency becomes a predetermined value or more.

2. The electrochemical reduction device according to claim 1 , wherein
the maximum current value Imax (C) is set to be low as the concentration C of the aromatic compound is low.

3. The electrochemical reduction device according to claim 1 , wherein
the predetermined value is 80%.

4. A method for manufacturing a hydride of an aromatic compound, the method comprising:
by using the electrochemical reduction device according to claim 1 ,
introducing an aromatic compound to the reduction electrode side of the electrode unit; and
hydrogenating a benzene ring of the aromatic compound introduced to the reduction electrode side by flowing water or a humidified gas to the oxygen evolving electrode side.

5. The method for manufacturing a hydride of an aromatic compound according to claim 4 , wherein
the aromatic compound introduced into the reduction electrode side is introduced in a liquid state for a reaction temperature to the reduction electrode side.

Assignees

• Jx Nippon Oil & Energy Corp
• Jxtg Nippon Oil & Energy Corp

Inventors

• Sato Yasushi
• Miyoshi Kota
• Nakagawa Kojiro
• Kobori Yoshihiro
• Oshima Shinji

Classifications

• C25B15/02

  Process control or regulation · CPC title

• C25B3/04 Primary

  Chemistry & Metallurgy · mapped topic

• C25B9/08

  Chemistry & Metallurgy · mapped topic

• C25B3/09

  Nitrogen containing compounds · CPC title

• C25B3/03

  Acyclic or carbocyclic hydrocarbons · CPC title