Method for treating desulfurization slag

Patent metadata

Field	Value
Publication number	US-10174389-B2
Application number	US-201415038514-A
Country	US
Kind code	B2
Filing date	Nov 27, 2014
Priority date	Nov 28, 2013
Publication date	Jan 8, 2019
Grant date	Jan 8, 2019

Abstract

A method for treating desulfurization slag involves conveying desulfurization slag from pig iron desulfurization to a unit where the desulfurization slag is melted at a temperature of at least 1,400° C. In the unit, a thorough mixing is achieved. The treatment takes place in the unit under oxidizing conditions. Sulfur dioxide is generated and collected from the roasting gas and supplied for further utilization.

First claim

The invention claimed is:

1. A method for treating desulfurization slag, comprising:
(a) providing desulfurization slag comprising sulfur, from pig iron desulfurization,
(b) conveying said desulfurization slag to a unit including a burner, said unit assuring a thorough mixing,
(c) melting the desulfurization slag at a temperature of at least 1,400° C., wherein a λ value of the burner is set to 1.3-1.6 during said melting,
(d) setting the burner to a λ value greater than 2.0 to generate a roasting gas including SO 2 ,
(e) collecting the generated SO 2 , and
(f) supplying said generated SO 2 for further utilization.

2. The method of claim 1 , further comprising adding quicklime to the desulfurization slag in the unit.

3. The method of claim 1 , further comprising tapping of a treated desulfurization slag and feeding the treated desulfurization slag into pig iron production.

4. The method of claim 3 , wherein the treated desulfurization slag has a sulfur content of less than 0.1% by mass.

5. The method of claim 3 , wherein the treated desulfurization slag has a sulfur content of less than 0.01% by mass.

6. The method of claim 1 , wherein the unit is a top blown rotary converter.

7. The method of claim 1 , wherein the λ value of the burner during melting is set to 1.4-1.5.

8. The method of claim 7 , further comprising adding quicklime to the desulfurization slag in the unit.

9. The method of claim 7 , further comprising tapping of a treated desulfurization slag and feeding the treated desulfurization slag into pig iron production.

10. The method of claim 7 , wherein a treated desulfurization slag has a sulfur content of less than 0.1% by mass.

11. The method of claim 7 , wherein a treated desulfurization slag has a sulfur content of less than 0.01% by mass.

12. The method according to claim 1 , wherein the unit is a top blown rotary converter.

13. A method for treating desulfurization slag, comprising:
(a) providing desulfurization slag comprising sulfur, from pig iron desulfurization,
(b) conveying said desulfurization slag to a unit including a burner, said unit assuring a thorough mixing,
(c) melting the desulfurization slag at a temperature of at least 1,400° C., wherein a λ value of the burner is set to 1.3-1.6 during said melting,
(d) setting the burner to a λ value greater than 2.0 to generate a roasting gas including SO 2 , CO and dust,
(e) afterburning at a temperature of at least 800° C.,
(f) cooling the roasting gas,
(g) collecting the generated SO 2 ,
(h) removing the dust, and
(i) supplying said generated SO 2 for further utilization.

14. The method of claim 13 , further comprising adding quicklime to the desulfurization slag in the unit.

15. The method of claim 13 , further comprising tapping of a treated desulfurization slag and feeding the treated desulfurization slag into pig iron production.

16. The method of claim 13 , wherein a treated desulfurization slag has a sulfur content of less than 0.1% by mass.

17. The method of claim 13 , wherein a treated desulfurization slag has a sulfur content of less than 0.01% by mass.

18. The method according to claim 13 , wherein the unit is a top blown rotary converter.

19. The method according to claim 13 , further comprising:
(a) determining a volume percent of exhaust gas components CO and SO 2 in an exhaust gas during the melting of the slag and during generating the roasting gas,
(b) when the volume ratio of SO 2 to CO exceeds unity, setting the burner λ value to greater than 2.

20. The method of claim 19 , further comprising adding quicklime to the desulfurization slag in the unit.

Assignees

• Voestalpine Stahl Gmbh

Inventors

• Pilz Karl
• Fritz Bertram
• Antrekowitsch Jürgen
• Schneeberger Gerald

Classifications

• C21C1/02

  Dephosphorising or desulfurising · CPC title

• C21B2100/42

  Sulphur removal · CPC title

• C21B3/06 Primary

  Treatment of liquid slag · CPC title

• C22B7/04

  Working-up slag · CPC title

• C04B5/00

  Treatment of  {metallurgical}  slag  (manufacture of slag wool C03B; in, or for, the production of metals C21B, C22B); Artificial stone from molten  {metallurgical}  slag  {(other cast stone C04B32/005; mechanical aspects B28B1/54)} · CPC title