Dispersant viscosity index improver-containing lubricant compositions and methods of use thereof

Patent metadata

Field	Value
Publication number	US-10174272-B2
Application number	US-201715837379-A
Country	US
Kind code	B2
Filing date	Dec 11, 2017
Priority date	Jul 14, 2016
Publication date	Jan 8, 2019
Grant date	Jan 8, 2019

Abstract

Lubricating oil compositions and methods of their use are provided herein. A lubricating oil composition as described herein includes a major amount of an oil of lubricating viscosity, an amine-functionalized olefin copolymer dispersant viscosity index improver in an amount of from about 1.5 wt. % to 2.0 wt. % based on the weight of the lubricating oil composition, and a dispersant. The amine-functionalized olefin copolymer dispersant viscosity index improver includes a reaction product of an acylated olefin copolymer and a polyamine. The dispersant includes reaction product of components (A) a hydrocarbyl-dicarboxylic acid or anhydride having a number average molecular weight of from about 500 to about 5000 and (B) at least one polyamine, wherein the reaction product is post-treated with (C) an aromatic carboxylic acid, an aromatic polycarboxylic acid, or an aromatic anhydride, wherein all carboxylic acid or anhydride groups are attached directly to an aromatic ring, and/or (D) a non-aromatic dicarboxylic acid or anhydride having a number average molecular weight of less than about 500.

First claim

What is claimed is:

1. A method of lubricating a heavy duty diesel engine, comprising:
supplying to a heavy duty diesel engine a lubricating oil composition comprising:
a major amount of an oil of lubricating viscosity;
an amine-functionalized olefin copolymer dispersant viscosity index improver comprising a reaction product of an acylated olefin copolymer and a polyamine, wherein the amine-functionalized olefin copolymer dispersant viscosity index improver is present in an amount of about 1.8 wt. % based on the weight of the lubricating oil composition; and
a dispersant comprising a reaction product of components (A) a hydrocarbyl-dicarboxylic acid or anhydride having a number average molecular weight of from about 500 to about 5000 and (B) at least one polyamine, wherein the reaction product is post-treated with (C) an aromatic carboxylic acid, an aromatic polycarboxylic acid, or an aromatic anhydride, wherein all carboxylic acid or anhydride groups are attached directly to an aromatic ring, and/or (D) a non-aromatic dicarboxylic acid or anhydride having a number average molecular weight of less than about 500.

2. A method of controlling soot induced viscosity increase in an engine lubricant, comprising:
lubricating a heavy duty diesel engine with a lubricating oil composition comprising:
a major amount of an oil of lubricating viscosity;
an amine-functionalized olefin copolymer dispersant viscosity index improver comprising a reaction product of an acylated olefin copolymer and a polyamine, wherein the amine-functionalized olefin copolymer dispersant viscosity index improver is present in an amount of about 1.8 wt. % based on the weight of the lubricating oil composition; and
a dispersant comprising a reaction product of components (A) a hydrocarbyl-dicarboxylic acid or anhydride having a number average molecular weight of from about 500 to about 5000 and (B) at least one polyamine, wherein the reaction product is post-treated with (C) an aromatic carboxylic acid, an aromatic polycarboxylic acid, or an aromatic anhydride, wherein all carboxylic acid or anhydride groups are attached directly to an aromatic ring, and/or (D) a non-aromatic dicarboxylic acid or anhydride having a number average molecular weight of less than about 500.

3. A method of reducing oil mist separator filter plugging in a heavy duty diesel engine, comprising:
lubricating a heavy duty diesel engine with a lubricating oil composition comprising:
a major amount of an oil of lubricating viscosity;
an amine-functionalized olefin copolymer dispersant viscosity index improver comprising a reaction product of an acylated olefin copolymer and a polyamine, wherein the amine-functionalized olefin copolymer dispersant viscosity index improver is present in an amount of about 1.8 wt. % based on the weight of the lubricating oil composition; and
a dispersant comprising a reaction product of components (A) a hydrocarbyl-dicarboxylic acid or anhydride having a number average molecular weight of from about 500 to about 5000 and (B) at least one polyamine, wherein the reaction product is post-treated with (C) an aromatic carboxylic acid, an aromatic polycarboxylic acid, or an aromatic anhydride, wherein all carboxylic acid or anhydride groups are attached directly to an aromatic ring, and/or (D) a non-aromatic dicarboxylic acid or anhydride having a number average molecular weight of less than about 500.

4. The method of claim 1 , wherein the amine-functionalized olefin copolymer dispersant viscosity index improver comprises an olefin copolymer having grafted thereon from 0.3 to 0.75 carboxylic groups per 1000 number average molecular weight units of olefin copolymer.

5. The method of claim 4 , wherein the olefin copolymer has a number average molecular weight of between about 40,000 and about 150,000.

6. The method of claim 4 , wherein the olefin copolymer is a copolymer of ethylene and one or more C 3 -C 23 alpha-olefins.

7. The method of claim 1 , wherein the dispersant is present in an amount of from about 2 wt. % to about 10 wt. %.

8. The method of claim 1 , wherein the dispersant is present in an amount of from about 5 wt. % to about 5.5 wt %.

9. The method of claim 1 , wherein component (A) comprises a polyalkenyl-substituted succinic acid or anhydride.

10. The method of claim 1 , wherein component (C) comprises 1,8-naphthalic anhydride.

11. The method of claim 1 , wherein component (D) comprises maleic anhydride.

12. The method of claim 1 , wherein from about 0.25 to 1.5 moles of component (C) is reacted per mole of component (B).

13. The method of claim 1 , wherein from about 0.25 to 1.5 moles of component (D) is reacted per mole of component (B).

14. The method of claim 1 , wherein the oil of lubricating viscosity comprises a Group II oil.

15. The method of claim 1 , wherein the oil of lubricating viscosity meets a SAE 10W-30 engine oil specification.

16. The method of claim 1 , wherein the oil of lubricating viscosity meets a a SAE 15W-40 engine oil specification.

17. The method of claim 1 , wherein the dispersant is a reaction product of A and B, post-treated with both C and D.

18. The method of claim 1 , further comprising a metal-containing detergent.

19. The method of claim 1 , further comprising an additional dispersant.

20. The method of claim 19 , wherein the additional dispersant comprises one or more polyalkenyl succinimide dispersants.

21. The method of claim 1 , wherein the lubricating oil composition is a heavy duty engine oil composition.

22. A method of lubricating a heavy duty diesel engine, comprising:
supplying to a heavy duty diesel engine a lubricating oil composition comprising:
(i) a major amount of an oil of lubricating viscosity;
(ii) an amine-functionalized olefin copolymer dispersant viscosity index improver comprising a reaction product of an acylated olefin copolymer and a polyamine, wherein the amine-functionalized olefin copolymer dispersant viscosity index improver is present in an amount of from about 1.6 wt. % to about 1.8 wt. % based on the weight of the lubricating oil composition; and
(iii) a dispersant comprising a reaction product of components (A) a hydrocarbyl-dicarboxylic acid or anhydride having a number average molecular weight of from about 500 to about 5000 and (B) at least one polyamine, wherein the reaction product is post-treated with (C) an aromatic carboxylic acid, an aromatic polycarboxylic acid, or an aromatic anhydride, wherein all carboxylic acid or anhydride groups are attached directly to an aromatic ring, and/or (D) a non-aromatic dicarboxylic acid or anhydride having a number average molecular weight of less than about 500.

23. A method of making a lubricating oil composition for use in a heavy duty diesel engine, comprising combining:
(i) a major amount of an oil of lubricating viscosity;
(ii) an amine-functionalized olefin copolymer dispersant viscosity index improver comprising a reaction product of an acylated olefin copolymer and a polyamine; and
(iii) a dispersant comprising a reaction product of components (A) a hydrocarbyl-dicarboxylic acid or anhydride having a number average molecular weight of from about 500 to about 5000 and (B) at least one polyamine, wherein the reaction product is post-treated with (C) an aromatic carboxylic acid, an aromatic polycarboxylic acid, or an aromatic anhydride, wherein all carboxylic acid or anhydride groups are attached directly to an aromatic ring, and/or (D) a non-aromati

Assignees

• Afton Chemical Corp

Inventors

• Lagona Jason

Classifications

• C10N2040/255

  Gasoline engines · CPC title

• C10N2030/02

  Pour-point; Viscosity index · CPC title

• C10N2020/04

  Molecular weight; Molecular weight distribution · CPC title

• C10M169/044

  the additives being a mixture of non-macromolecular and macromolecular compounds · CPC title

• C10M2217/028

  containing monomers having an unsaturated radical bound to a nitrogen-containing hetero ring · CPC title