Process for the production of white oils from waste oils

Patent metadata

Field	Value
Publication number	US-10174264-B2
Application number	US-201414564879-A
Country	US
Kind code	B2
Filing date	Dec 9, 2014
Priority date	Nov 6, 2013
Publication date	Jan 8, 2019
Grant date	Jan 8, 2019

Abstract

The present invention describes a process for the production of technical white oils or edible or medicinal oils from waste oils originating from industrial use or engine use, said process using a deep hydrotreatment.

First claim

The invention claimed is:

1. A process for the production of a white oil, comprising;
(I) obtaining a waste oil from industrial use or from use in engines;
(II) subjecting the waste oil to a dehydration stage to eliminate water, light hydrocarbons, and light additives in the waste oil to produce a dehydrated oil;
(III) subjecting the dehydrated oil to a vacuum distillation stage to obtain a 420-480° C. range distilled cut;
(IV) subjecting said 420-480° C. range distilled cut to a demetallization stage in the presence of a demetallization catalyst comprising a Group VIB metal and at least two Group VIIIB metals to produce a demetallized product, wherein the demetallization stage is carried out at (i) a temperature between 200° C. and 400° C., (ii) a pressure between 0.5 MPa and 30 MPa, and (iii) an LHSV between 0.1 and 10 h −1 , and wherein the demetallization catalyst has a Group VIIIB metal content between 1 wt % and 10 wt % and a Group VIB metal content between 2 wt % and 15 wt %;
(V) subjecting said demetallized product to a first deep hydrotreatment stage in the presence of (i) a supported nickel- and molybdenum-based catalyst, or (ii) a nickel- and tungsten-based catalyst to produce a deep hydrotreated product, wherein the deep hydrotreatment stage takes place under the following conditions:
(1) a temperature of between 250° C. and 450° C.,
(2) a pressure between 17 MPa and 21 MPa,
(3) an LHSV between 0.1 and 10 h −1 , and
(4) a flow rate of hydrogen between 100 and 3,000 normal liters/liter of feedstock;

(VI) subjecting said deep hydrotreated product to a second hydrotreatment stage in the presence of a catalyst comprising a noble metal deposited on a support, wherein the noble metal is selected from the group consisting of Pt, Pd, Ru, Rh, and combinations thereof, wherein the second hydrotreatment stage comprises hydrogenating aromatic hydrocarbons contained in the deep hydrotreated product to produce said white oil under the following operating conditions:
(1) a pressure between 5 MPa and 25 MPa,
(2) a LHSV between 0.1 and 10 h −1 , and
(3) a temperature between 150° C. and 450° C.;

(VII) recovering said white oil from the second hydrotreatment stage, wherein said white oil has a Saybolt Color value of >20, as determined by the ASTM D156 method.

2. The process according to claim 1 , in which the dehydration stage comprises preheating the waste oil, either in an exchanger or in an oven at a temperature of 50° C. to 200° C.

3. The process according to claim 1 , in which the temperature during said vacuum distillation stage is maintained below 250° C.

4. The process according to claim 1 , in which the demetallization catalyst comprises at least one oxide or sulphide of a Group VIIIB metal and/or at least one oxide or sulphide of a Group VIB metal.

5. The process according to claim 1 , in which the demetallization catalyst has a Group VIIIB metal content of between 1 wt % and 5 wt % and a Group VIB metal content of 5 wt % to 10 wt %.

6. The process according to claim 1 , in which the catalyst employed in the first deep hydrotreatment stage is a supported nickel- and molybdenum catalyst, wherein the support is alumina.

7. The process according to claim 1 , in which the demetallization stage and the first deep hydrotreatment stage are carried out under the same temperature, pressure, and LHSV conditions.

8. The process according to claim 1 , in which the noble metal of the catalyst employed in the second hydrotreatment stage is selected from the group consisting of Pt, Pd, and combinations thereof.

9. The process according to claim 8 , wherein the support of the catalyst employed in the second hydrotreatment stage is selected from the group consisting of silica, alumina, silica-alumina, zirconium, titanium oxide, and mixtures thereof.

10. The process according to claim 4 , wherein the Group VIIIB metal in the at least one oxide or sulphide of a Group VIIIB metal is nickel or cobalt, and the Group VIB metal in the at least one oxide or sulphide of a Group VIB metal is chromium, molybdenum, or tungsten.

11. The process according to claim 8 , wherein the catalyst employed in the second hydrotreatment stage includes Pt and the support employed in the second hydrotreatment stage is selected from the group consisting of silica, alumina, and silica-alumina.

12. The process according to claim 1 , wherein the vacuum distillation stage is conducted in a thin-film evaporator.

13. A process for the production of a technical white oil, comprising:
(I) obtaining a waste oil from industrial use or from use in engines;
(II) subjecting the waste oil to a dehydration stage to eliminate water, light hydrocarbons, and light additives in the waste oil to produce a dehydrated oil;
(III) subjecting the dehydrated oil to a vacuum distillation stage to obtain a 420-480° C. range distilled cut;
(IV) subjecting said 420-480° C. range distilled cut to a demetallization stage to produce a demetallized product;
(V) subjecting said demetallized product to a hydrotreatment stage in the presence of (i) a supported nickel- and molybdenum-based catalyst, or (ii) a nickel- and tungsten-based catalyst to produce said technical white oil, wherein the hydrotreatment stage takes place under the following conditions:
(1) a temperature between 250° C. and 450° C.,
(2) a pressure between 17 MPa and 21 MPa,
(3) an LHSV between 0.1 and 10 h −1 , and
(4) a flow rate of hydrogen between 100 and 3,000 normal liters/liter of feedstock; and

(VI) recovering said technical white oil from the hydrotreatment stage,
wherein said technical white oil has a Saybolt Colour Color value of >20, as determined by the ASTM D156 method.

Assignees

• Axens

Inventors

• Morel Frederic
• Bonnardot Jerome
• Guibard Isabelle

Classifications

• C10G2300/1007

  Used oils · CPC title

• C10G67/14 Primary

  including at least two different refining steps in the absence of hydrogen · CPC title

• C10G2400/14

  White oil, eating oil · CPC title

• C10G65/08

  at least one step being a hydrogenation of the aromatic hydrocarbons · CPC title

• C10G65/04

  including only refining steps · CPC title