Method of hydrophobic treatment of a carbon substrate

Patent metadata

Field	Value
Publication number	US-10170769-B2
Application number	US-201715414217-A
Country	US
Kind code	B2
Filing date	Jan 24, 2017
Priority date	Feb 11, 2016
Publication date	Jan 1, 2019
Grant date	Jan 1, 2019

Abstract

A method of treating a carbon substrate, includes the successive steps of impregnating the carbon substrate with an aqueous solution containing an amorphous fluorinated copolymer of tetrafluoroethylene and of perfluoromethoxy dioxole, drying the carbon substrate at a pressure lower than the atmospheric pressure, and obtaining a carbon substrate impregnated with a fluorinated copolymer. Such a carbon substrate may be used as a gas diffusion layer in a fuel cell.

First claim

The invention claimed is:

1. A method of treating a carbon substrate, comprising the following successive steps of:
impregnating the carbon substrate with an aqueous solution containing an amorphous fluorinated copolymer of tetrafluoroethylene and perfluoromethoxy dioxole; and
drying the impregnated carbon substrate at a pressure lower than the atmospheric pressure to obtain a treated carbon substrate impregnated with the fluorinated copolymer, wherein the method is free of sintering after drying.

2. The carbon substrate treatment method of claim 1 , wherein the carbon substrate is a carbon fiber nonwoven having a thickness in the range from 25 to 300 micrometers.

3. The carbon substrate treatment method of claim 1 , wherein the aqueous solution comprises from 1 to 60 wt. % of fluorinated copolymer.

4. The carbon substrate treatment method of claim 1 , wherein the impregnation of the carbon substrate is performed at a temperature in the range from 15 to 35° C.

5. The carbon substrate treatment method of claim 1 , wherein the drying temperature is in the range from 25 to 95° C.

6. The carbon substrate treatment method claim 1 , wherein the drying time is in the range from 15 minutes to 5 hours.

7. The carbon substrate treatment method of claim 1 , wherein the drying is carried out at a pressure in the range from 0.1 to 500 hPa.

8. The carbon substrate treatment method of claim 1 , wherein, at the end of the drying, the treated carbon substrate comprises from 0.5 to 25 wt. % of fluorinated copolymer.

9. The carbon substrate treatment method of claim 1 , wherein, at the end of the drying, the carbon substrate comprises from 1 to 15 wt. % of fluorinated copolymer.

10. The carbon substrate treatment method of claim 1 , wherein, at the end of the drying, the carbon substrate comprises from 2.5 to 10 wt. % of fluorinated copolymer.

11. The carbon substrate treatment method of claim 1 , wherein the aqueous solution comprises from 5 to 15 wt. % of fluorinated copolymer.

12. The carbon substrate treatment method of claim 1 , wherein the drying is carried out at a pressure in the range from 0.1 to 250 hPa.

13. The carbon substrate treatment method of claim 1 , wherein the drying is carried out at a pressure in the range from 0.1 to 50 hPa.

14. The carbon substrate treatment method of claim 1 , wherein the drying temperature is in the range from 30 to 80° C.

15. The carbon substrate treatment method of claim 1 , wherein the method is performed at a temperature lower than the glass transition temperature of the amorphous fluorinated copolymer.

Assignees

• Commissariat Energie Atomique

Inventors

• Thomas Yohann
• Heitzmann Marie
• Pauchet Joël
• Schroder Maxime

Classifications

• H01M8/0245 Primary

  in the form of layered or coated products · CPC title

• H01M4/96

  Carbon-based electrodes · CPC title

• H01M4/8605

  Porous electrodes · CPC title

• H01M2008/1095

  Fuel cells with polymeric electrolytes · CPC title

• H01M4/8821 Primary

  Wet proofing · CPC title