Lithium metal oxide particles coated with a mixture of the elements of the core material and one or more metal oxides

Patent metadata

Field	Value
Publication number	US-10170763-B2
Application number	US-201214125431-A
Country	US
Kind code	B2
Filing date	May 29, 2012
Priority date	Jun 17, 2011
Publication date	Jan 1, 2019
Grant date	Jan 1, 2019

Abstract

A lithium metal oxide powder for use as a cathode material in a rechargeable battery, consisting of a core material and a surface layer, the core having a layered crystal structure consisting of the elements Li, a metal M and oxygen, wherein the Li content is stoichiometrically controlled, wherein the metal M has the formula M=Co1-aM′a, with 0≤a≤0.05, wherein M′ is either one or more metals of the group consisting of Al, Ga and B; and the surface layer consisting of a mixture of the elements of the core material and inorganic N-based oxides, wherein N is either one or more metals of the group consisting of Mg, Ti, Fe, Cu, Ca, Ba, Y, Sn, Sb, Na, Zn, Zr and Si.

First claim

The invention claimed is:

1. A lithium metal oxide powder for use as a cathode material in a rechargeable battery, comprising a core material and a surface layer,
the core material comprising a layered crystal structure comprising the elements Li, a metal M and oxygen, wherein the Li content is stoichiometrically controlled, the metal M has the formula M=Co 1-a M′ a , with 0≤a≤0.05, and M′ is either one or more metals selected from the group consisting of Al, Ga and B; and
the surface layer having a thickness of at least 50 nm and comprising a mixture of the elements of the core material, Li, M, and oxygen, and inorganic N-based oxides, wherein N is one or more metals selected from the group consisting of Mg, Ti, Fe, Cu, Ca, Ba, Y, Sn, Sb, Na, Zn, Zr and Si, and wherein the concentration in N metals decreases with increasing distance from the surface to the core on a gradient, and wherein the concentration of N metals in the core is not zero.

2. The lithium metal oxide powder of claim 1 , wherein 0<a≤0.03.

3. The lithium metal oxide powder of claim 1 , having a mean particle size D50 of at least 5 μm.

4. The lithium metal oxide powder of claim 1 , wherein the thickness of the surface layer is less than 100 nm.

5. The lithium metal oxide powder of claim 1 , wherein the surface layer further comprises less than 2000 ppm of one or more of LiF, Li 3 PO 4 and Li 2 SO 4 .

6. The lithium metal oxide powder of claim 1 , wherein the metal in the core material is diamagnetic.

7. The lithium metal oxide powder of claim 6 , wherein in the core material, the Li occupies a crystallographic site surrounded by trivalent diamagnetic metals.

8. The lithium metal oxide powder of claim 1 , having a pressed density of at least 3.40 g/cm 3 .

9. The lithium metal oxide powder of claim 1 , having a reversible electrode capacity of at least 200 mAh/g, when used as an active component in a cathode which is cycled between 3.0 and 4.6 V vs. Li + /Li at a discharge rate of 0.1 C.

10. The lithium metal oxide powder of claim 9 , having a capacity fade rate per 100 cycles at 1 C below 60%.

11. The lithium metal oxide powder of claim 1 , wherein N comprises Mg and Ti, the Mg content being between 0.1 and 1 mol % and the Ti content being between 0.1 and 0.5 mol %.

12. The lithium metal oxide powder of claim 1 , having a total base content of less than 50 μmol/g.

13. The lithium metal oxide powder of claim 1 , having a carbon content less than 50 ppm.

14. The lithium metal oxide powder of claim 1 , having an electrical conductivity less than 10 −4 S/cm.

15. The lithium metal oxide powder of claim 1 , wherein the surface layer is substantially free from lithium salts.

16. The lithium metal oxide powder of claim 1 , comprising monolithic, potato-shaped and non-agglomerated particles.

17. The lithium metal oxide powder of claim 1 , wherein the powder has a bimodal particle shape distribution where the small particle size fraction has a D50≤5 μm and is between 3 to 20 Vol %, and where the large particle size fraction has a D50≥12 μm.

18. The lithium metal oxide powder of claim 1 , wherein the core material is substantially free from oxygen vacancies and from Li substitution for M in the MO 2 layers of the layered crystal structure.

19. The lithium metal oxide powder of claim 1 , wherein the core material is substantially free from paramagnetic metals.

Assignees

• Blangero Maxime
• Kim Kyubo
• Je Hyun Joo
• Umicore Nv

Inventors

• Blangero Maxime
• Kim Kyubo
• Je Hyun-Joo

Classifications

• C01P2006/11

  Powder tap density · CPC title

• H01M4/366

  as layered products · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• C01P2004/03

  obtained by SEM · CPC title

• C01P2002/72

  by d-values or two theta-values, e.g. as X-ray diagram · CPC title