Apparatus and electronic devices including transistors comprising two-dimensional materials
US-2024339543-A1 · Oct 10, 2024 · US
US10170651B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10170651-B2 |
| Application number | US-201514607882-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 28, 2015 |
| Priority date | Jan 30, 2014 |
| Publication date | Jan 1, 2019 |
| Grant date | Jan 1, 2019 |
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Various methods are used to provide a desired doping metal concentration in a CIGS-containing ink when the CIGS layer is deposited on a photovoltaic device. When the doping metal is sodium, it may be incorporated by: adding a sodium salt, for example sodium acetate, together with the copper-, indium- and/or gallium-containing reagents at the beginning of the synthesis reaction of Cu(In,Ga)(S,Se) 2 nanoparticles; synthesizing Cu(In,Ga)(S,Se) 2 nanoparticles and adding a sodium salt to the reaction solution followed by mild heating before isolating the nanoparticles to aid sodium diffusion; and/or, using a ligand that is capable of capping the Cu(In,Ga)(S,Se) 2 nanoparticles with one end of its molecular chain and binding to sodium atoms with the other end of its chain.
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We claim: 1. A process for preparing sodium-doped nanocrystals comprising: adding a sodium dialkyldithiocarbamate to a mixture of copper-, indium-, and gallium-containing reagents at the beginning of a synthesis reaction to form sodium-doped Cu(In,Ga)(S,Se) 2 nanoparticles. 2. The process of claim 1 wherein the sodium dialkyldithiocarbamate is sodium diethyldithiocarbamate. 3. The process of claim 1 wherein the sodium dialkyldithiocarbamate is sodium dimethyldithiocarbamate. 4. The process of claim 1 wherein the sodium dialkyldithiocarbamate is sodium methylhexyldithiocarbamate. 5. The process of claim 1 wherein the sodium dialkyldithiocarbamate is sodium ethylhexyldithiocarbamate.
Nanoparticles · CPC title
P-type · CPC title
being chalcogenide semiconductor materials not being oxides, e.g. ternary compounds · CPC title
using solutions · CPC title
CuInSe2 material PV cells · CPC title
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