Piezoresistive cement nanocomposites

Patent metadata

Field	Value
Publication number	US-10167714-B2
Application number	US-201415036975-A
Country	US
Kind code	B2
Filing date	Nov 21, 2014
Priority date	Nov 22, 2013
Publication date	Jan 1, 2019
Grant date	Jan 1, 2019

Abstract

Methods may include pumping a cement composition containing one or more conductive fillers into an annular region of a wellbore created between a casing and a surface of the wellbore, allowing the cement composition to cure, emplacing a tool for measuring at least one electromagnetic property into the wellbore, and measuring at least one of the cemented casing and the formation. In another aspect, methods may include preparing a cement composition containing one or more conductive fillers, allowing the cement composition to set, and measuring at least one electromagnetic property of the set cement. In yet another aspect, cement compositions may contain a cement, one or more conductive fillers, and a surfactant, wherein the resistivity of the cement composition is less than 10 Ω*m.

First claim

What is claimed is:

1. A method comprising:
pumping a cement composition comprising one or more conductive fillers into an annular region of a wellbore created between a casing and a surface of the wellbore wherein the one or more conductive fillers is functionalized carbon nanotubes;
allowing the cement composition to cure;
emplacing a tool for measuring at least one electromagnetic property into the wellbore; and
measuring at least one of the cemented casing and the formation.

2. The method of claim 1 , wherein the one or more conductive fillers is a mixture of the functionalized carbon nanotubes and carbon fibers.

3. The method of claim 1 , wherein the functionalized carbon nanotubes contain one or more carboxylate functional groups.

4. The method of claim 1 , wherein the cement composition further comprises a surfactant.

5. The method of claim 1 , wherein the cement composition comprises a high temperature setting cement.

6. The method of claim 1 , wherein the one or more conductive fillers is present at a concentration that ranges from 0.001% by weight of cement to 10% by weight of cement.

7. The method of claim 1 , wherein measuring at least one of the cemented casing and the formation comprises measuring the resistivity of the formation through the emplaced cement composition and casing and into the surrounding formation.

8. The method of claim 1 , wherein the set cement composition functions as a piezoresitive sensor, and wherein measuring at least one of the cemented casing and the formation comprises measuring mechanical stress of the cemented casing.

9. A method comprising:
preparing a cement composition comprising one or more conductive fillers;
allowing the cement composition to set;
measuring at least one electromagnetic property of the set cement; and wherein measuring at least one of the resistivity or conductivity of the set cement comprises measuring a mechanical stress on the cement.

10. The method of claim 9 , wherein the cement composition further comprises a surfactant.

11. The method of claim 9 , wherein the cement composition comprises one or more cement additives selected from a group consisting of magnesium oxide and calcium oxide.

12. A cement composition comprising:
a cement;
one or more conductive fillers wherein the one or more conductive fillers comprises one or more functionalized conductive fillers; and
a surfactant, wherein the resistivity of the cement composition is less than 10 Ω*m.

13. The composition of claim 12 , wherein the one or more conductive fillers is one or more selected from a group consisting of: single wall nanotubes, multi-walled nanotubes, graphene, conductive carbon, and carbon fibers.

14. The composition of claim 12 , wherein the surfactant is one or more selected from a group consisting of: sodium dodecyl sulfate, sodium dodecyl benzene sulfonate, polynaphthalene sulfonate, and polyethylene oxide/polyphenylene oxide copolymer.

15. The composition of claim 12 , wherein the composition further comprises one or more cement additives selected from a group consisting of magnesium oxide and calcium oxide.

16. The composition of claim 12 , wherein the one or more conductive fillers is a mixture of the one or more functionalized carbon nanotubes and carbon fibers.

17. The composition of claim 12 , wherein the resistivity of the cement composition is less than 1 Ω*m.

Assignees

• Schlumberger Technology Corp

Inventors

• Musso Simone
• Allouche Mickael
• Pavese Matteo

Classifications

• C09K8/467

  containing additives for specific purposes · CPC title

• C04B28/02 Primary

  containing hydraulic cements other than calcium sulfates · CPC title

• C04B14/026 Primary

  of particular shape, e.g. nanotubes · CPC title

• E21B47/005 Primary

  Monitoring or checking of cementation quality or level · CPC title

• C09K2208/08

  Fiber-containing well treatment fluids · CPC title