Method for manufacturing biodegradable packaging material, biodegradable packaging material and a package or a container made thereof

Patent metadata

Field	Value
Publication number	US-10167594-B2
Application number	US-201314438139-A
Country	US
Kind code	B2
Filing date	Oct 28, 2013
Priority date	Oct 26, 2012
Publication date	Jan 1, 2019
Grant date	Jan 1, 2019

Abstract

A biodegradable packaging material, a method of manufacturing the same, as well as products made of the material wherein the manufacture comprises extrusion onto a fibrous substrate one or mote polymer coating layers including at least one layer of a polymer blend consisting of (i) 20-95 wt-% of polylactide having a high melt index of more than 35 g/10 min (210° C.; 2.16 kg), (ii) 5-80 wt-% of polybutylene succinate (PBS) or a biodegradable derivate thereof, and (iii) 0-5 wt-% of one or more polymeric additives. The components of the blend are melted and blended in connection with the extrusion step. The goal is to improve extrudability, increase machine speed in extrusion and maintaining good adhesiveness to the substrate and wood heat-sealability of the coating. The products include disposable drinking cups and board trays, as well as sealed carton packages for solids and liquids.

First claim

The invention claimed is:

1. A method of manufacturing a biodegradable packaging material, the method comprising:
extruding one or more polymer coating layers onto a fibrous substrate, the one or more polymer coating layers including at least one layer of a non-aromatic polymer blend, the at least one layer of non-aromatic polymer blend consisting of (i) 20-95 wt-% of polylactide (PLA) having a high melt index of more than 35 g/10 min (210° C.; 2.16 kg), (ii) 5-80 wt-% of polybutylene succinate (PBS) or a biodegradable derivate thereof, and (iii) greater than 0 wt-% and up to 5 wt-% of ethylene butyl acrylate glycidyl methacrylate terpolymer, wherein the PLA and the PBS or the biodegradable derivate thereof are fed into the extruder as granules, and the components of the polymer blend are melted and blended in connection with the extrusion step.

2. The method of claim 1 , wherein said polymer blend consists of (i) 30-60 wt-% of said high melt index polylactide, (ii) 40-70 wt-% of said polybutylene succinate or said biodegradable derivate thereof, and (iii) greater than 0 wt-% up to 5 wt-% of said ethylene butyl acrylate glycidyl methacrylate terpolymer.

3. The method of claim 1 , wherein said high melt index polylactide has a melt index of 50-100 g/10 min (210° C.; 2.16 kg).

4. The method of claim 1 , wherein said polymer blend is extruded as an outermost heat-sealable layer of a multilayer coating.

5. The method of claim 1 , wherein said polymer blend is extruded as an innermost adhesive layer of a multilayer coating.

6. The method of claim 4 , wherein said multilayer coating comprises an innermost layer of said polymer, an outermost layer of said polymer blend, and a middle intermediate layer between said innermost and outermost layers, said middle intermediate layer containing polylactide having a low melt index of 5-35 g/10 min (210° C.; 2.16 kg).

7. The method of claim 6 , wherein the same polymer blend is extruded as the innermost and the outermost layer of the multilayer coating.

8. The method of claim 1 , wherein a monolayer coating is extruded into direct contact with the fibrous substrate.

9. The method of claim 1 , wherein the machine speed in extrusion is at least 100 m/min.

10. The method of claim 1 , wherein said high melt index polylactide has a melt index of 70-85 g/10 min (210° C.; 2.16 kg).

11. The method of claim 5 , wherein said multilayer coating comprises an innermost layer of said polymer blend, an outermost layer of said polymer blend, and an intermediate middle layer between said innermost and outermost layers, said intermediate middle layer containing polylactide having a low melt index of 5-35 g/10 min (210° C.; 2.16 kg).

12. The method of claim 9 , wherein the machine speed in extrusion is at least 250 m/min.

13. The method of claim 1 , further comprising forming said one or more polymer coating layers extruded onto said fibrous substrate into a consumable product chosen from a drinking cup, a sealed liquid package, a sealed carton package, and a tray package for ready-made food.

14. The method of claim 13 , wherein said one or more polymer coating layers are located on an inner liquid-contact side of said drinking cup, an inner liquid-contact side of said sealed liquid package, an outside of said sealed carton package, or a food contact side of said tray package for ready-made food.

Assignees

• Stora Enso Oyj

Inventors

• Nevalainen Kimmo
• Ribu Ville

Classifications

• D21H5/0005 Primary

  Processes or apparatus specially adapted for applying liquids or other fluent materials to finished paper or board, e.g. impregnating, coating (applying liquids to surfaces in general B05; treating textile materials by liquids, gases or vapours D06B; impregnated or coated fibreboard D21J1/08; apparatus for making patterned paper D21H5/06; printing machines B41F) · CPC title

• B32B2307/7163

  Biodegradable · CPC title

• B32B27/36

  comprising polyesters · CPC title

• B32B2317/12

  Paper, e.g. cardboard · CPC title

• B32B2439/66

  Cans, tins · CPC title