Aqueous composition with improved elongation at break

Patent metadata

Field	Value
Publication number	US-10167408-B2
Application number	US-201515306279-A
Country	US
Kind code	B2
Filing date	Apr 23, 2015
Priority date	Apr 25, 2014
Publication date	Jan 1, 2019
Grant date	Jan 1, 2019

Abstract

An aqueous polymer composition which when in the form of a film shows excellent elongation at break comprising (i) 5 to 30 wt. % of polyurethane where the acid value of the polyurethane is between 3 to 40 mg KOH/g; (ii) 70 to 95 wt. % of vinyl polymer comprising 20 to 90 wt. % of vinyl polymer with Tg<20° C.; 10 to 80 wt. % of vinyl polymer with Tg≥20° C.; where at least one of the vinyl polymers contains acid functional groups with acid value in the range of from 15 and 240 mg KOH/g.

First claim

The invention claimed is:

1. An aqueous polymer composition comprising
(i) 5 to 30 wt. % of polyurethane obtained by the reaction of:
(a)
(1) 9 to 31 wt. % of at least one polyisocyanate;
(2) 0 to 8 wt. % of at least one isocyanate-reactive compound with a weight average molecular weight in the range of from 50 to 500 g/mol, containing ionic or potentially ionic water-dispersing groups;
(3) 0 to 91 wt. % of at least one isocyanate-reactive compound with a weight average molecular weight in the range of from 501 to 5000 g/mol containing ionic or potentially ionic water-dispersing groups;
(4) 0 to 91 wt. % of at least one isocyanate-reactive compound with a weight average molecular weight in the range of from 501 to 5000 g/mol not comprised by (3);
where (3) and (4) add up to 57 to 91 wt. %;
(5) 0 to 10 wt. % of at least one isocyanate-reactive compound with a weight average molecular weight in the range of from 50 to 500 g/mol not comprised by (2);
where (1), (2), (3), (4) and (5) add up to 100%; and

(b) at least one chain-extending compound;
where the acid value of the resulting polyurethane (i) is between 3 to 40 mg KOH/g;

(ii) 70 to 95 wt. % of vinyl polymer comprising
(c) 20 to 90 wt. % of vinyl polymer with Tg<20° C.;
(d) 10 to 80 wt. % of vinyl polymer with Tg≥20° C.;
wherein (c) and (d) add up to 100%;
where at least one of (c) and (d) contains acid functional groups with an acid value in the range of from 15 to 240 mg KOH/g; and
wherein (i) and (ii) add up to 100%.

2. An aqueous polymer composition according to claim 1 wherein the weight percentage of (i) and (ii) together is more than 60 wt. % of the total composition.

3. An aqueous polymer composition according to claim 1 wherein at least one of (c) and (d) contains acid functional groups so that the acid value of the resulting vinyl polymer is in the range of from 15 to 100 mg KOH/g.

4. An aqueous polymer composition according to claim 1 wherein at least one of (c) and (d) contains acid functional groups so that the acid value of the resulting vinyl polymer is in the range of from 101 to 240 mg KOH/g.

5. An aqueous polymer composition according to claim 1 wherein the Tg of vinyl polymer (d) is at least 30° C. higher than the Tg of vinyl polymer (c).

6. An aqueous polymer composition according to claim 1 wherein the weight ratio of vinyl polymer (c) to vinyl polymer (d) is within the range of from 35/65 to 90/10.

7. An aqueous polymer composition according to claim 1 wherein at least 50 wt. % of the total amount of polyisocyanate (1) used comprises aliphatic polyisocyanate.

8. An aqueous polymer composition according to claim 1 wherein at least 30 wt. % of the total amount of polyisocyanate (1) used is selected from HDI, pentamethylene diisocyanate and or mixtures thereof.

9. An aqueous polymer composition according to claim 1 wherein the acid value of the polyurethane is in the range of from 6 to 35 mg KOH/g.

10. An aqueous polymer composition according to claim 1 containing less than 10 wt. % solvent.

11. A clear lacquer comprising the aqueous polymer composition according to claim 1 wherein said lacquer comprises:
I) 2 to 15 wt. % of the polyurethane (i);
II) 25 to 50 wt. % of the vinyl polymer (ii);
III) 35 to 74 wt. % of water;
IV) 0 to 4 wt. % of transparent inorganic additives
where I), II), III) and IV) all add up to 100%.

12. A clear lacquer as defined in claim 11 which when in the form of a film has an elongation at break of at least 140% at 10 wt. % of polyurethane at room temperature.

13. A clear lacquer as defined in claim 11 which when in the form of a film has an elongation at break of at least 160% at 10 wt. % of polyurethane at room temperature.

14. A pigmented lacquer comprising the aqueous ploymer composition according to claim 1 as wherein said lacquer comprises:
I) 1 to 10 wt. % of the polyurethane (i);
II) 10 to 40 wt. % of the vinyl polymer (ii);
III) 30 to 79 wt. % of water;
IV) 10 to 30 wt. % of pigment;
where I), II), III) and IV) all add up to 100%.

15. A pigmented lacquer as defined in claim 14 with a pigment volume concentration range of 10 to 30 vol. % which when in the form of a film has an elongation at break of at least 60% at 10 wt. % of polyurethane at room temperature.

16. A method of coating a substrate comprising applying to the substrate the lacquer according to claim 11 .

17. A substrate having a coating comprising a lacquer according to claim 11 .

Assignees

• Dsm Ip Assets Bv

Inventors

• Satgurunathan Rajasingham
• Scheerder Jurgen
• Overbeek Gerardus Cornelis
• Swaans Roel Johannes Marinus
• Tennebroek Ronald
• Nabuurs Tijs
• Kastelijn Maud
• Malda Hinrike

Classifications

• C08L33/10

  Homopolymers or copolymers of methacrylic acid esters · CPC title

• C08L2201/52

  Aqueous emulsion or latex, e.g. containing polymers of a glass transition temperature (Tg) below 20°C · CPC title

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• C09D133/12 Primary

  Homopolymers or copolymers of methyl methacrylate · CPC title

• C09D133/10 Primary

  Homopolymers or copolymers of methacrylic acid esters · CPC title