Methane conversion apparatus and process using a supersonic flow reactor

Patent metadata

Field	Value
Publication number	US-10166524-B2
Application number	US-201715491280-A
Country	US
Kind code	B2
Filing date	Apr 19, 2017
Priority date	Aug 21, 2012
Publication date	Jan 1, 2019
Grant date	Jan 1, 2019

Abstract

Apparatus and methods are provided for converting methane in a feed stream to acetylene. A hydrocarbon stream is introduced into a supersonic reactor and pyrolyzed to convert at least a portion of the methane to acetylene. The reactor effluent stream may be treated to convert acetylene to another hydrocarbon process.

First claim

The invention claimed is:

1. An apparatus for producing acetylene from a feed stream comprising methane comprising:
a supersonic reactor for receiving the methane feed stream and heating the methane feed stream to a pyrolysis temperature;
a reactor shell of the supersonic reactor for defining a reactor chamber wherein the reaction chamber operates at a temperature from about 1200° C. to about 4000° C.;
a combustion zone of the supersonic reactor for combusting a fuel source to provide a high temperature carrier gas passing through the reactor space at supersonic speeds to heat and accelerate the methane feed stream to a pyrolysis temperature;
the reactor shell comprising an inner shell and an outer shell with one or more channels between the inner shell and the outer shell where the inner shell is constructed of a material having a thermal conductivity of between about 300 and about 450 W/m-K for conducting heat from the reactor chamber and having a melting temperature of between about 500° C. and about 2000° C.; the material being at least copper chrome, or copper chrome zinc, or copper chrome niobium, or copper zirconium or copper silver zirconium; or mixtures thereof; and
one or more sensors positioned within the channel and electronically connected to one or more of a display, a monitoring system and a control system.

2. The apparatus of claim 1 wherein the one or more sensors include pressure sensors, temperature sensors, chemical sensors, hydrogen sensors, hydrocarbon sensors, or methane sensors.

3. The apparatus of claim 1 wherein the channel houses one or more support structures to support the inner shell relative to the outer shell.

4. The apparatus of claim 1 wherein the channels are defined by a surface of the reactor shell.

5. The apparatus of claim 1 wherein the channels are within a wall of the reactor shell.

6. The apparatus of claim 1 wherein the channels axially along the reactor shell, circumferentially about the reactor shell, radially through the reactor shell, or helically about the annular reactor shell.

7. The apparatus of claim 1 wherein the reactor portion comprises a material selected from the group consisting of aluminum, or zirconium, or niobium, or silver, or alloys thereof.

8. The apparatus of claim 1 wherein the reactor portion has a melting temperature of between about 800° C. and about 1300° C.

9. The apparatus of claim 1 further comprising an active cooling system for maintaining the reactor portion at a temperature below the melting temperature thereof.

10. An apparatus for producing acetylene from a feed stream comprising methane comprising:
a supersonic reactor for receiving the methane feed stream and heating the methane feed stream to a pyrolysis temperature;
a reactor shell of the supersonic reactor for defining a reactor chamber wherein the reaction chamber operates at a temperature from about 1200° C. to about 4000° C.;
a combustion zone of the supersonic reactor for combusting a fuel source to provide a high temperature carrier gas passing through the reactor space at supersonic speeds to heat and accelerate the methane feed stream to a pyrolysis temperature;
the reactor shell comprising an inner shell and an outer shell with one or more channels between the inner shell and the outer shell where the inner shell is constructed of a material having a thermal conductivity of between about 300 and about 450 W/m-K for conducting heat from the reactor chamber and having a melting temperature of between about 500° C. and about 2000° C.; the material being at least copper chrome, or copper chrome zinc, or copper chrome niobium, or copper zirconium or copper silver zirconium; or mixtures thereof; and
an isolation valve at an inlet of the supersonic reactor and a control system capable of detecting a change in pressure and in connection with the isolation valve.

11. An apparatus for producing acetylene from a feed stream comprising methane comprising:
a supersonic reactor for receiving the methane feed stream and heating the methane feed stream to a pyrolysis temperature;
a reactor shell of the supersonic reactor for defining a reactor chamber wherein the reaction chamber operates at a temperature from about 1200° C. to about 4000° C.;
a combustion zone of the supersonic reactor for combusting a fuel source to provide a high temperature carrier gas passing through the reactor space at supersonic speeds to heat and accelerate the methane feed stream to a pyrolysis temperature;
the reactor shell comprising an inner shell and an outer shell with one or more channels between the inner shell and the outer shell where the inner shell is constructed of a material having a thermal conductivity of between about 300 and about 450 W/m-K for conducting heat from the reactor chamber and having a melting temperature of between about 500° C. and about 2000° C.; the material being at least copper chrome, or copper chrome zinc, or copper chrome niobium, or copper zirconium or copper silver zirconium; or mixtures thereof; and
a pressure relief device in the reactor shell.

12. The apparatus of claim 11 wherein the pressure relief device is a relief valve or a rupture disc.

13. An apparatus for producing acetylene from a feed stream comprising methane comprising:
a supersonic reactor for receiving the methane feed stream and heating the methane feed stream to a pyrolysis temperature;
a reactor shell of the supersonic reactor for defining a reactor chamber wherein the reaction chamber operates at a temperature from about 1200° C. to about 4000° C.;
a combustion zone of the supersonic reactor for combusting a fuel source to provide a high temperature carrier gas passing through the reactor space at supersonic speeds to heat and accelerate the methane feed stream to a pyrolysis temperature;
the reactor shell comprising an inner shell and an outer shell with one or more channels between the inner shell and the outer shell where the inner shell is constructed of a material having a thermal conductivity of between about 300 and about 450 W/m-K for conducting heat from the reactor chamber and having a melting temperature of between about 500° C. and about 2000° C.; the material being at least copper chrome, or copper chrome zinc, or copper chrome niobium, or copper zirconium or copper silver zirconium; or mixtures thereof; and
wherein the supersonic reactor is oriented vertically.

14. The apparatus of claim 13 wherein the vertical orientation is 90° from the horizontal.

Assignees

• Uop Llc

Inventors

• Bedard Robert L
• Naunheimer Christopher
• Towler Gavin P
• Leonard Laura E
• Dudebout Rodolphe
• Woodcock Gregory O
• Mittendorf Donald L

Classifications

• B01J6/008 Primary

  Pyrolysis reactions (of hydrocarbons C10G9/00) · CPC title

• C10G2400/24

  Acetylene and homologues · CPC title

• C10G2300/1025

  Natural gas · CPC title

• C10G50/00

  Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation · CPC title

• B01J19/26

  Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles · CPC title