Advanced non-toxic radiation shielding materials from tailored brine sludge and a process for the preparation thereof

Patent metadata

Field	Value
Publication number	US-10165713-B2
Application number	US-201715449088-A
Country	US
Kind code	B2
Filing date	Mar 3, 2017
Priority date	Mar 3, 2016
Publication date	Dec 25, 2018
Grant date	Dec 25, 2018

Abstract

Conventional shielding materials are based on single material either toxic lead or barium based compounds and any matrix made therefrom contains only single phased barium based compounds, thereby posing limited radiation shielding capacity. Since brine sludge, an industrial toxic waste product, generated in chloralkali industry contains multiple compounds; there is a need to provide a process which enables the preparation of multi-phase based radiation shielding materials. In view of the above, the present invention provides advanced non-toxic radiation shielding materials utilizing tailored brine sludge and a process that enables conversion of toxic elements like chromium, zinc, copper and vanadium present in brine sludge into non-toxic shielding phases, thereby enabling to convert a toxic waste material into highly value added advanced radiation shielding materials possessing homogeneous radiation shielding matrix.

First claim

We claim:

1. An advanced non-toxic radiation shielding material comprising:
[a] 200 g to 600 g of brine sludge; and
[b] 20 g to 60 g of sodium hexametaphosphate.

2. A process for an advanced non-toxic radiation shielding material comprising the steps of:
[a] drying 200 g to 600 g of brine sludge in an air oven at a temperature of 100 to 110° C. for a period of 1 to 2 hours;
[b] heating the dried brine sludge as obtained in step [a] in a furnace at a temperature ranging from 800 to 1300° C. for a period of 1 to 2 hours;
[c] mechano-chemical processing of the heat treated brine sludge obtained in step [b] by grinding with 20 to 60 g of sodium hexametaphosphate in a ball mill or planetary mill for a period of 1 to 6 hours to obtain tailored brine sludge powder; and
[d] compacting the tailored brine sludge powder obtained in step [c] in a steel mold using hydraulic pressure in a range of 100 to 300 kg/cm 2 in the form of tiles to obtain the desired advanced non-toxic radiation shielding material.

3. The process of claim 2 , wherein the dimensions of the tiles are 10 cm×10 cm×5-10 mm.

Assignees

• Council Scient Ind Res

Inventors

• Amritphale Sudhir Sitaram
• Anshul Avneesh
• Verma Sarika
• Khan Mohammed Akram
• Das Satyabrata

Classifications

• G21F3/04

  Bricks; Shields made up therefrom · CPC title

• G21F1/00

  Shielding characterised by the composition of the materials · CPC title

• H05K9/0086

  comprising a single discontinuous metallic layer on an electrically insulating supporting structure, e.g. metal grid, perforated metal foil, film, aggregated flakes, sintering · CPC title

• H05K9/0003 Primary

  Shielded walls, floors, ceilings, e.g. wallpaper, wall panel, electro-conductive plaster, concrete, cement, mortar · CPC title