Graphene oxide and carbon nanotube ink and methods for producing the same

Patent metadata

Field	Value
Publication number	US-10163583-B2
Application number	US-201315034377-A
Country	US
Kind code	B2
Filing date	Nov 5, 2013
Priority date	Nov 5, 2013
Publication date	Dec 25, 2018
Grant date	Dec 25, 2018

Abstract

An energy device including a paper based substrate having a top surface and a bottom surface, and a graphene oxide and carbon nanotube composite deposited onto at least the top surface. The energy device can be used as an electrode in, for example, a supercapacitor.

First claim

The claimed invention is:

1. An energy device, comprising
a paper based substrate having a top surface and a bottom surface; and
a pure graphene oxide and carbon nanotube composite deposited from a liquid dispersion onto at least the top surface.

2. The energy device of claim 1 , wherein the pure graphene oxide and carbon nanotube composite is substantially free from a surfactant.

3. The energy device of claim 1 , wherein the pure graphene oxide and carbon nanotube composite comprises about 15 weight percent to about 85 weight percent of graphene oxide.

4. The energy device of claim 1 , wherein the pure graphene oxide and carbon nanotube composite comprises about 15 weight percent to about 85 weight percent of carbon nanotubes.

5. The energy device of claim 1 , wherein the carbon nanotubes are single-wall carbon nanotubes.

6. The energy device of claim 1 , wherein the energy device does not include a binder.

7. The energy device of claim 1 , wherein the pure graphene oxide is a single layer graphene oxide flake.

8. The energy device of claim 7 , wherein the single layer graphene oxide flake has a thickness within a range of about 0.35nanometers to about 50nanometers.

9. The energy device of claim 7 , wherein the single layer graphene oxide flake has a length within a range of about 200nanometers to about 500nanometers.

10. A super capacitor, comprising:
a first electrode including:
a first paper based substrate having a top surface and a bottom surface, and
a first pure graphene oxide and carbon nanotube composite deposited from a liquid dispersion onto at least the top surface;
a second electrode, including:
a second paper based substrate having a top surface and a bottom surface, and
a second pure graphene oxide and carbon nanotube composite deposited from a liquid dispersion onto at least the top surface;
an electrolyte; and
a separator positioned between the first electrode and the second electrode.

11. The supercapacitor of claim 10 , wherein the first pure graphene oxide and carbon nanotube composite and the second pure graphene oxide and carbon nanotube composite comprise about 15weight percent to about 85weight percent of graphene oxide.

12. The supercapacitor of claim 10 , wherein the pure graphene oxide and carbon nanotube composite and the second pure graphene oxide and carbon nanotube composite comprise about 15weight percent to about 85weight percent of carbon nanotubes.

13. The supercapacitor of claim 12 , wherein the carbon nanotubes are single-wall carbon nanotubes.

14. The supercapacitor of claim 10 , wherein the first pure graphene oxide and carbon nanotube composite and the second pure graphene oxide and carbon nanotube composite comprise a plurality of graphene oxide flakes, the graphene oxide flake having a thickness within a range of about 0.35nanometers to about 50nanometers and a length within a range of about 200nanometers to about 500nanometers.

15. A method, comprising:
obtaining or providing a pure graphene oxide and carbon nanotube dispersion, the pure graphene oxide and carbon nanotube dispersion substantially free from a surfactant; and
depositing the pure graphene oxide and carbon nanotube dispersion onto a surface of a paper based substrate.

16. The method of claim 15 , wherein the pure graphene oxide and carbon nanotube dispersion comprises carbon nanotubes within a range of about 0.5milligrams per milliliter to about 12milligrams per milliliter.

17. The method of claim 15 , comprising drying the pure graphene oxide and carbon nanotube dispersion deposited onto the surface of the paper based substrate.

18. The method of claim 15 , wherein the pH of the pure graphene oxide and carbon nanotube dispersion is within a range of about 6to about 12.

19. The method of claim 15 , wherein the carbon nanotubes are single-wall carbon nanotubes.

Assignees

• Univ California

Inventors

• Guo Shirui
• Wang Wei
• Ozkan Cengiz S
• Ozkan Mihrimah

Classifications

• H01G11/86

  specially adapted for electrodes (carbonisation or activation of carbon for the manufacture of electrodes H01G11/34) · CPC title

• H01G11/24 Primary

  characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor · CPC title

• H01G11/28

  arranged or disposed on a current collector; Layers or phases between electrodes and current collectors, e.g. adhesives · CPC title

• H01G11/26

  characterised by their structure, e.g. multi-layered, porosity or surface features · CPC title

• B82Y30/00 Primary

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title