Polymer product and method for selectively metallizing polymer substrate

Patent metadata

Field	Value
Publication number	US-10161044-B2
Application number	US-201715447522-A
Country	US
Kind code	B2
Filing date	Mar 2, 2017
Priority date	Sep 4, 2014
Publication date	Dec 25, 2018
Grant date	Dec 25, 2018

Abstract

A polymer product with a metal layer coated on the surface thereof is provided. The polymer product includes a polymer substrate and a metal layer formed on at least a part of a surface of the polymer substrate. The surface of the polymer substrate covered by the metal layer is formed by a polymer composition comprising a polymer and a doped tin oxide. A doping element of the doped tin oxide comprises niobium. The doped tin oxide has a coordinate L* value of about 70 to about 100, a coordinate a value of about −5 to about 5, and a coordinate b value of about −5 to about 5 in a CIELab color space.

First claim

What is claimed is:

1. A polymer product comprising:
a polymer substrate; and
a metal layer formed on at least a part of a surface of the polymer substrate,
wherein the surface of the polymer substrate covered by the metal layer is formed by a polymer composition comprising a polymer and a doped tin oxide, and
wherein a doping element of the doped tin oxide comprises niobium, and the doped tin oxide has a coordinate L* value of about 70 to about 100, a coordinate a value of about −5 to about 5, and a coordinate b value of about −5 to about 5 in a CIELab color space.

2. The polymer product of claim 1 , wherein the doped tin oxide has a light reflectivity of no more than 60% to a light with a wavelength of about 1064 nm.

3. The polymer product of claim 1 , wherein based on a total weight of the doped tin oxide, content of the tin oxide is about 70 wt % to about 99.9 wt %, and content of the niobium is about 0.1 wt % to about 30 wt % calculated as Nb 2 O 5 .

4. The polymer product of claim 1 , wherein the doped tin oxide has an average particle size of about 10 nm to about 10 μm.

5. The polymer product of claim 1 , wherein the doped tin oxide is prepared by steps of:
providing a powder mixture comprising a tin oxide and at least one compound containing the doping element, and
sintering the powder mixture under an oxidizing atmosphere,
wherein the compound comprises at least one of an oxide of the doping element and a precursor capable of forming the oxide of the doping element under the sintering.

6. The polymer product of claim 1 , wherein in the polymer composition, based on 100 weight parts of the polymer, content of the doped tin oxide is about 1 to about 40 weight parts.

7. The polymer product of claim 1 , wherein in the polymer composition, based on 100 weight parts of the polymer, content of the doped tin oxide is about 1 to about 5 weight parts.

8. A method for selectively metalizing a surface of a polymer substrate, comprising:
removing at least a part of the polymer substrate by irradiating a surface of the polymer substrate with an energy source; and
forming at least one metal layer on the surface of the polymer substrate by chemical plating;
wherein the surface of the polymer substrate is formed by a polymer composition that comprises a polymer and a doped tin oxide, and
wherein a doping element of the doped tin oxide comprises niobium, and the doped tin oxide has a coordinate L* value of about 70 to about 100, a coordinate a value of about −5 to about 5, and a coordinate b value of about −5 to about 5 in a CIELab color space.

9. The method of claim 8 , wherein the doped tin oxide has a light reflectivity of no more than 60% to a light with a wavelength of about 1064 nm.

10. The method of claim 8 , wherein based on the total weight of the doped tin oxide, content of the tin oxide is about 70 wt % to about 99.9 wt %, and content of the niobium is about 0.1 wt % to about 30 wt % calculated as Nb 2 O 5 .

11. The method of claim 8 , wherein the doped tin oxide has an average particle size of about 10 nm to about 10 μm.

12. The method of claim 8 , wherein the doped tin oxide is prepared by steps of:
providing a powder mixture comprising a tin oxide and at least one compound containing the doping element, and
sintering the powder mixture in an oxidizing atmosphere,
wherein the compound comprises at least one of an oxide of the doping element and a precursor capable of forming the oxide of the doping element under the sintering.

13. The method of claim 8 , wherein in the polymer composition, based on 100 weight parts of the polymer, content of the doped tin oxide is about 1 to about 40 weight parts.

14. The method of claim 8 , wherein in the polymer composition, based on 100 weight parts of the polymer, content of the doped tin oxide is about 1 to about 5 weight parts.

15. The method of claim 8 , wherein the energy source is a laser.

16. The method of claim 15 , wherein the laser has a wavelength of about 1064 nm and a power of about 3-40 W.

17. The method of claim 8 , wherein removing the part of the polymer substrate is performed by gasifying the part of the polymer substrate.

18. A polymer product produced by the method according to claim 8 .

Assignees

• Byd Co Ltd

Inventors

• Zhou Wei
• Mao Bifeng

Classifications

• H05K3/185

  by making a catalytic pattern by photo-imaging · CPC title

• C09D11/322

  Pigment inks · CPC title

• C23C18/1653

  Two or more layers with at least one layer obtained by electroless plating and one layer obtained by electroplating · CPC title

• C09D11/03

  characterised by features other than the chemical nature of the binder · CPC title

• B01J23/20

  Vanadium, niobium or tantalum · CPC title