High-purity titanium ingots, manufacturing method therefor, and titanium sputtering target

Patent metadata

Field	Value
Publication number	US-10161032-B2
Application number	US-201314371111-A
Country	US
Kind code	B2
Filing date	Feb 13, 2013
Priority date	Feb 14, 2012
Publication date	Dec 25, 2018
Grant date	Dec 25, 2018

Abstract

Provided is a high-purity titanium ingot having a purity, excluding an additive element and gas components, of 99.99 mass % or more, wherein at least one nonmetallic element selected from S, P, and B is contained in a total amount of 0.1 to 100 mass ppm as the additive component and the variation in the content of the nonmetallic element between the top, middle, and bottom portions of the ingot is within ±200%. Provided is a method of manufacturing a titanium ingot containing a nonmetallic element in an amount of 0.1 to 100 mass ppm, wherein S, P, or B, which is a nonmetallic element, is added to molten titanium as an intermetallic compound or a master alloy to produce a high-purity titanium ingot having a purity, excluding an additive element and gas components, of 99.99 mass % or more. It is an object of the present invention to provide a high-purity titanium having decreased intra- and inter-ingot variations in the content of the nonmetallic element, a uniform structure, and improved strength by containing at least one nonmetallic element selected from S, P, and B.

First claim

The invention claimed is:

1. A method of manufacturing a high purity titanium ingot containing at least one nonmetallic element selected from the group consisting of S, P and B in a total amount of 0.1 to 100 mass ppm, wherein the method comprises the steps of feeding successively and continuously a raw material titanium to an arc melting furnace or an electron beam (EB) melting furnace by using a feeder, melting continuously the raw material titanium fed successively and continuously to produce molten titanium, adding the at least one nonmetallic element to the molten titanium during progress of said melting step to produce a melt containing the at least one nonmetallic element, an amount of the at least one nonmetallic element added during said adding step is decreased during the progress of said melting step, feeding continuously the melt containing the at least one nonmetallic element to a water-cooled copper mold to form a pool of the melt containing the at least one nonmetallic element, and withdrawing downward a solidified part of the pool from a bottom end of the copper mold at a rate of 1 to 10 kg per minute to produce the high purity titanium ingot having a purity of 99.99 mass % or higher excluding the at least one nonmetallic element and gas components, the at least one nonmetallic element being added to the molten titanium in a form of an intermetallic compound or a master alloy, the ingot having a variation in contents of the at least one nonmetallic element in an amount within ±200% with respect to an intended concentration thereof, the contents being measured at top, middle, and bottom portions of the ingot, the middle portion being a portion midway between the top and bottom portions.

2. The method of manufacturing a titanium ingot according to claim 1 , wherein the ingot has a variation in contents of each of the at least one nonmetallic element in an amount within ±200% with respect to the intended concentration thereof for contents measured at edge, half-way, and center portions in a cross-sectional face of the ingot, the half-way portion being located half a distance from the center portion to the edge portion, and the cross-sectional face of the ingot being taken perpendicularly to a longitudinal direction of the ingot and at a half-way between the top and bottom portions of the ingot.

3. The method of manufacturing a titanium ingot according to claim 2 , wherein the variation for contents measured at the edge, half-way, and center portions in the cross-sectional face is within ±100%.

4. The method of manufacturing a titanium ingot according to claim 1 , wherein ingots in different melting lots have a variation in average contents of each of the at least one nonmetallic element in an amount within ±200% with respect to the intended concentration thereof, the average contents being measured for each of the different melting lots.

5. The method of manufacturing a titanium ingot according to claim 4 , wherein the variation in average contents of each of the at least one nonmetallic element is within ±100% with respect to the intended concentration thereof.

6. The method of manufacturing a titanium ingot according to claim 5 , wherein the at least one nonmetallic element added to the molten titanium is added in the form of the master alloy in a shape having a cross-sectional area of 2000 to 18000 mm 2 and a thickness of 1 to 10 mm.

7. The method of manufacturing a titanium ingot according to claim 6 , wherein the addition of the at least one nonmetallic element is performed by adjusting an added amount of the at least one nonmetallic element at a time of starting the melting such that the added amount of the at least one nonmetallic element is at a concentration which is three times the intended concentration of the at least one nonmetallic element in the ingot and by decreasing the added amount during the melting until at an end of the melting the added amount is adjusted such that the added amount of the at least one nonmetallic element is at a concentration which is one third of the intended concentration of the at least one nonmetallic element in the ingot.

8. The method of manufacturing a titanium ingot according to claim 1 , wherein the at least one nonmetallic element added to the molten titanium is added in the form of the master alloy of a shape having a cross-sectional area of 2000 to 18000 mm 2 and a thickness of 1 to 10 mm.

9. The method of manufacturing a titanium ingot according to claim 1 , wherein the addition of the at least one nonmetallic element is performed by adjusting an added amount of the at least one nonmetallic element at a time of starting the melting such that the added amount of the at least one nonmetallic element is at a concentration which is three times the intended concentration of the at least one nonmetallic element in the ingot and by decreasing the added amount during the melting until at an end of the melting the added amount is adjusted such that the added amount of the at least one nonmetallic element is at a concentration which is one third of the intended concentration of the at least one nonmetallic element in the ingot.

10. The method of manufacturing a titanium ingot according to claim 1 , wherein the variation is within ±100%.

11. A method of manufacturing a high purity titanium ingot containing at least one nonmetallic element in a total amount of 0.1 to 100 mass ppm, comprising the steps of:
feeding a raw material titanium to an arc melting furnace or an electron beam (EB) melting furnace with a feeder;
melting successively and continuously the raw material titanium fed to produce molten titanium;
adding at least one nonmetallic element to the molten titanium during progress of said melting step to produce a melt containing the at least one nonmetallic element, an amount of the at least one nonmetallic element added during said adding step being decreased during the progress of said melting step,
feeding continuously the melt containing the at least one nonmetallic element to a water-cooled copper mold to form a pool of the melt containing the at least one nonmetallic element; and
extracting downward a solidified part of the pool from a bottom end of the copper mold to produce the high purity titanium ingot having a purity of 99.99 mass % or higher excluding the at least one nonmetallic element and gas components;
the at least one nonmetallic element being selected from the group consisting of S, P and B and being added to the molten titanium in a form of an intermetallic compound or a master alloy; and
the ingot having a variation in contents of the at least one nonmetallic element at top, middle, and bottom portions of the ingot within ±200%, the middle portion being a portion midway between the top and bottom portions.

Assignees

• Jx Nippon Mining & Metals Corp

Inventors

• Yagi Kazuto
• Hino Eiji
• Shindo Yuichiro

Classifications

• C23C14/3414 Primary

  Metallurgical or chemical aspects of target preparation, e.g. casting, powder metallurgy · CPC title

• C22C1/02

  by melting {(C22C1/1036 takes precedence)} · CPC title

• H01J37/3426

  Material · CPC title

• C22B9/22

  with heating by wave energy or particle radiation {(by acoustic waves C22B9/026)} · CPC title

• C22B34/1295

  Refining, melting, remelting, working up of titanium · CPC title