Methods for constructing parts with improved properties using metallic glass alloys

Patent metadata

Field	Value
Publication number	US-10161025-B2
Application number	US-201514690239-A
Country	US
Kind code	B2
Filing date	Apr 17, 2015
Priority date	Apr 30, 2014
Publication date	Dec 25, 2018
Grant date	Dec 25, 2018

Abstract

Described herein are methods of constructing a part having improved properties using metallic glass alloys, layer by layer. In accordance with certain aspects, a layer of metallic glass-forming powder is deposited to selected positions and then fused to a surface layer (i.e. layer below) by suitable methods such as laser heating or electron beam heating. The deposition and fusing are then repeated as need to construct the part, layer by layer. In certain embodiments, one or more sections or layers of non-metallic glass-forming material can be included as needed to form a composite final part. In certain aspects, the metallic glass-forming powder may be crystalized during depositing and fusing, or may be recrystallized during subsequent processing to provide selectively crystalized sections or layers, e.g., to impart desired functionality. In other aspects, non-metallic glass-forming materials may be deposited and fused at selected positions, e.g., to provide selective shear banding to impart improved ductile properties and plasticity. In yet other aspects, the metallic glass-forming powder or metallic glass material and non-metallic glass-forming material are deposited and fused to form a foam-like, bellow or similar structure, which is able to crumple under high stress to absorb energy under impact.

First claim

The invention claimed is:

1. A method of forming a metallic glass composite part with improved toughness comprising:
depositing a layer of non-metallic glass material to one or more portions of a metallic glass layer formed of a metallic glass-forming alloy comprising at least one of a powder, a wire, or a sheet; and
fusing the layer of non-metallic glass material to the metallic glass layer to form a shear band of non-metallic glass material embedded in the metallic glass layer of the metallic glass composite part.

2. The method of claim 1 where the toughness of the metallic glass composite part is 5% greater than a metallic glass part formed of the metallic glass-forming alloy.

3. The method of claim 1 , wherein the non-metallic glass material is selected from a group consisting of crystalline material, plastic, ceramic, semiconductors, and Kevlar fibers.

4. The method of claim 1 where the metallic glass-forming alloy is a powder.

5. The method of claim 4 where the metallic glass-forming alloy is a homogenous atomized powder.

6. The method of claim 1 where the metallic glass-forming alloy is a wire.

7. The method of claim 1 , further comprising:
depositing a layer formed of the metallic glass-forming alloy over the non-metallic glass material and at least a portion of the metallic glass layer; and
fusing the layer of the metallic glass-forming alloy to the non-metallic glass material and the at least a portion of the metallic glass layer.

8. The method of claim 1 , wherein the non-metallic glass material comprises at least one of a powder, a wire, or a sheet.

9. A method of forming an amorphous metal foam part comprising:
depositing a layer of a metallic glass-forming alloy onto a housing;
heating the layer of metallic glass-forming alloy to a temperature above the glass transition of the alloy and cooling to form an integrally formed amorphous metal foam part onto the housing; and
the amorphous metal foam part having at least 10% void space by volume,
wherein the integrally formed amorphous metal foam part forms internal structures of the housing, wherein the housing comprises a shell, and the amorphous metal foam forms a core that is surrounded by the shell.

10. The method of claim 9 where the metallic glass-forming alloy is heated to above the glass transition temperature in a time of less than 5 seconds.

11. The method of claim 9 wherein the layer of metallic glass-forming alloy is selectively deposited such that the amorphous metal foam part has an ordered lattice structure.

12. The method of claim 11 wherein the ordered lattice structure comprises a honeycomb.

13. The method of claim 9 where the metallic glass-forming alloy is selectively deposited to create crumple zone with an unidirectional collapse.

14. The method of claim 9 where the metallic glass-forming alloy comprises a powder.

15. The method of claim 14 where the powder is a homogenous atomized powder.

16. The method of claim 9 where the metallic glass-forming alloy comprises a wire.

Assignees

• Apple Inc

Inventors

• Poole Joseph C
• Waniuk Theodore A
• Mattlin Jeffrey L
• Nashner Michael S
• Prest Christopher D

Classifications

• C22C1/11

  Making amorphous alloys · CPC title

• B22F12/20

  Cooling means · CPC title

• B22F10/32

  of the atmosphere, e.g. composition or pressure in a building chamber · CPC title

• B22F10/28

  Powder bed fusion, e.g. selective laser melting [SLM] or electron beam melting [EBM] · CPC title

• B22F3/11

  Making porous workpieces or articles · CPC title