Low-E Panels Utilizing High-Entropy Alloys and Combinatorial Methods and Systems for Developing the Same
US-2015362473-A1 · Dec 17, 2015 · US
US10161021B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10161021-B2 |
| Application number | US-201715493026-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 20, 2017 |
| Priority date | Apr 20, 2016 |
| Publication date | Dec 25, 2018 |
| Grant date | Dec 25, 2018 |
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The present disclosure relates to new materials comprising Al, Co, and Ni. The new materials may realize a single phase field of a face-centered cubic (fcc) solid solution structure immediately below the solidus temperature of the material. The new materials may include at least one precipitate phase and have a solvus temperature of at least 1000° C. The new materials may include 6.7-11.4 wt. % Al, 5.0-48.0 wt. % Co, and 43.9-88.3 wt. % Ni. In one embodiment, the precipitate is selected from the group consisting of the L12 phase, the B2 phase, and combinations thereof. The new alloys may realize improved high temperature properties.
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The invention claimed is: 1. A method comprising: (a) using a feedstock in an additive manufacturing apparatus, wherein the feedstock comprises: 6.7-11.4 wt. % Al; 5.0-48.0 wt. % Co; and 43.9-88.3 wt. % Ni; (b) producing a metal product in the additive manufacturing apparatus using the feedstock. 2. The method of claim 1 , wherein the feedstock comprises a powder feedstock, wherein the method comprises: (a) dispersing a metal powder of the powder feedstock in a bed and/or spraying a metal powder of the powder feedstock towards or on a substrate; (b) selectively heating a portion of the metal powder above its liquidus temperature, thereby forming a molten pool; (c) cooling the molten pool, thereby forming a portion of the metal product, wherein the cooling comprises cooling at a cooling rate of at least 100° C. per second; and (d) repeating steps (a)-(c) until the metal product is completed, wherein the metal product comprises a metal matrix, wherein the Al, Co, and Ni make-up the matrix. 3. The method of claim 1 , wherein the feedstock comprises a wire feedstock, wherein the method comprises: (a) using a radiation source to heat the wire feedstock above its liquidus point, thereby creating a molten pool, wherein the molten pool comprises Al, Co, and Ni; (b) cooling the molten pool at a cooling rate of at least 1000° C. per second; and (c) repeating steps (a)-(b) until the metal product is completed, wherein the metal product comprises a metal matrix, wherein the Al, Co, and Ti make-up the matrix. 4. The method of claim 1 , comprising: cooling at a rate sufficient to form at least one precipitate phase. 5. The method of claim 4 , wherein the at least one precipitate phase comprises at least one of L1 0 and Al 2 Zr. 6. The method of claim 5 , wherein the metal product comprises at least 0.5 vol. % of the precipitate phase. 7. The method of claim 1 , comprising: working the metal product. 8. The method of claim 7 , wherein the metal product is a final additively manufactured body and wherein the working is working of the final additively manufactured body. 9. The method of claim 7 , wherein the producing step comprises: first producing a portion of the metal product using the feedstock; second producing another portion of the metal product using the feedstock; wherein the working occurs at least after the first or second producing steps. 10. The method of claim 9 , wherein the working occurs between the first producing step and the second producing step. 11. The method of claim 9 , wherein the working comprises hot isostatic pressing. 12. The method of claim 9 , wherein the working comprises one or more of rolling, forging, and extrusion. 13. The method of claim 1 , wherein the feedstock comprises at least 32.7 wt. % Co. 14. The method of claim 1 , wherein the feedstock comprises at least 38.2 wt. % Co. 15. The method of claim 1 , wherein the feedstock comprises not greater than 43.6 wt. % Co.
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