Delayed-release additives in a degradable matrix

Patent metadata

Field	Value
Publication number	US-10160896-B2
Application number	US-201515563421-A
Country	US
Kind code	B2
Filing date	Apr 27, 2015
Priority date	Apr 27, 2015
Publication date	Dec 25, 2018
Grant date	Dec 25, 2018

Abstract

A wellbore treatment fluid comprising: a base fluid; and an extruded substance comprising: a degradable matrix; and an additive, wherein the degradable matrix provides a time-delayed release of the additive into a wellbore fluid for a desired period of time. A method of treating a portion of a well comprising: introducing the treatment fluid into the well; and causing or allowing at least a portion of the degradable matrix to degrade, wherein degradation of the degradable matrix releases at least some of the additive into the wellbore fluid.

First claim

What is claimed is:

1. A method of treating a portion of a well comprising:
introducing a treatment fluid into the well, wherein the treatment fluid comprises:
(A) a base fluid; and
(B) a substance comprising:
(i) a degradable matrix; wherein the degradable matrix is a plastic or a hydrogel; and
(ii) an additive, wherein the degradable matrix provides a time-delayed release of the additive into a wellbore fluid for a desired period of time;
wherein the substance is extruded; and

causing or allowing at least a portion of the degradable matrix to degrade, wherein a solvent, heated fluid, or other wellbore fluid is introduced into the wall after the step of introducing the treatment fluid to cause at least a portion of the degradable matrix to degrade; wherein degradation of the degradable matrix releases at least some of the additive into the wellbore fluid.

2. The method according to claim 1 , wherein the base fluid comprises water, a hydrocarbon liquid, or combinations thereof.

3. The method according to claim 1 , wherein the plastic is a thermoplastic or a wax.

4. The method according to claim 1 , wherein the degradable matrix is a polymer.

5. The method according to claim 1 , wherein the polymer is selected from the group consisting of polysaccharides, including dextran or cellulose; chitin; chitosan; proteins; aliphatic polyesters; poly(lactides); poly(glycolides); poly(ϵ-caprolactones); poly(hydroxybutyrates); aliphatic polycarbonates; poly(orthoesters); poly(amides); poly(urethanes); poly(hydroxy ester ethers); poly(anhydrides); aliphatic polycarbonates; poly(amino acids); poly(ethylene oxide); polyphosphazenes; and combinations thereof.

6. The method according to claim 1 , wherein the degradable matrix is a eutectic, hypo-eutectic, or hyper-eutectic composition.

7. The method according to claim 1 , wherein the additive is a solid or a liquid.

8. The method according to claim 1 , wherein the additive is selected from the group consisting of corrosion inhibitors, demulsifiers, foaming agents, wetting agents, surfactants, scale inhibitors, chelants, clay stabilizers, biocides, filter cake breakers, gel breakers, fluid loss additives, cement set retarders, cement set accelerators, suspending agents, acids, bases, salts, and combinations thereof in any proportion.

9. The method according to claim 1 , wherein the additive is in a concentration in the range of about 1% to about 85% by weight of the degradable matrix.

10. The method according to claim 1 , wherein more than one type of additive is included in the degradable matrix.

11. The method according to claim 1 , wherein the material making up the degradable matrix is selected such that at least a portion of the degradable matrix degrades at the bottomhole temperature and pressure of the well.

12. The method according to claim 1 , wherein the desired period of time is at least 24 hours.

13. The method according to claim 1 , wherein the desired period of time is in the range of 24 hours to 2 years.

14. The method according to claim 13 , wherein the majority of or all of the additive is released at the end of the period of time.

15. The method according to claim 13 , wherein the degradable matrix is a polymer, and wherein the monomer residues, the end groups and/or functional groups of the polymer, the relative concentration of the monomer residues, and the molecular weight of the polymer are selected to provide a degradation rate such that the additive is released in the desired period of time.

16. The method according to claim 13 , wherein the porosity of the extruded substance is selected to provide a degradation rate such that the additive is released in the desired period of time.

17. The method according to claim 13 , wherein the shape and dimensions of the extruded substance are selected such that the additive is released in the desired period of time.

18. The method according to claim 1 , wherein the step of introducing is performed using a pump.

19. The method according to claim 1 , wherein the substance is neither coated nor encapsulated.

Assignees

• Halliburton Energy Services Inc

Inventors

• Weaver Jimmie D
• Fontenelle Lucas K

Classifications

• C09K8/88

  macromolecular compounds · CPC title

• C09K8/605

  containing biocides · CPC title

• C09K2208/20

  Hydrogen sulfide elimination · CPC title

• C09K8/035 Primary

  Organic additives · CPC title

• C09K8/602

  containing surfactants · CPC title