Chemically foamed polysulfide sealant for aerospace fuel tank use

Patent metadata

Field	Value
Publication number	US-10160893-B2
Application number	US-201615195141-A
Country	US
Kind code	B2
Filing date	Jun 28, 2016
Priority date	Jun 28, 2016
Publication date	Dec 25, 2018
Grant date	Dec 25, 2018

Abstract

The present application is directed to polysulfide sealant formulations, application of such sealants, and methods for reducing the density of polysulfide sealant formulations.

First claim

What is claimed is:

1. A sealant formulation comprising:
a polysulfide in an amount ranging from about 75 to about 90 weight %;
an acid salt in an amount ranging from about 3 to about 10 weight %; and
a bicarbonate in an amount ranging from about 2.5 to about 10 weight %.

2. The sealant formulation of claim 1 , wherein the acid salt comprises at least one of:
sodium aluminum sulfate; monocalcium phosphate; delta-gluconolactone; sodium acid pyrophosphate; sodium aluminum phosphate; sodium aluminum pyrophosphate; or potassium bitartrate.

3. The sealant formulation of claim 1 , wherein the bicarbonate comprises at least one of:
sodium bicarbonate; potassium bicarbonate; or ammonium bicarbonate.

4. The sealant formulation of claim 1 , wherein the polysulfide comprises at least one of:
a polymer comprising one or more disulfide linkages and the polysulfide ranges in molecular weight from about 1100 to about 8000, said polymer comprising a crosslinking density of from about 0.2 to about 5 mol %.

5. The sealant formulation of claim 1 , wherein the polysulfide comprises at least one of:
polysulfide polymers made from monomers comprising: 1,3-dichloropropane; 1,3-dibromopropane; 1,2-dichloropropane; 1,4-dichlorobutane; 1,4-dibromobutane; trans-1,4-dibromo-2-butene; 1,3-dichlorobutane; 1,2-dichlorobutane; 1,2-dibromobutane; 2,3-dichlorobutane; 2,3-dibromobutane; 1,5-dichloropentane; 1,5-dibromopentane; 1,4-dichloropentane; 1,4-dibromopentane; 1,3-dichloropentane; 1,2-dichloropentane; 2,3-dichloropentane; 2,4-dichloropentane; 1,6-dichlorohexane; 1,6-dibromohexane; 1,2-dichlorohexane; 1,2-dichlorocyclohexane; 1,2-dichlorocyclohexane cis and trans isomers; 1,3-dichlorocyclohexane; 1,3-dichlorocyclohexane cis and trans isomers; 1,4-dichlorocyclohexane; 1,4-dichlorocyclohexane cis and trans isomers; 1,2-bis(chloromethyl)cyclohexane; 1,2-bis(chloromethyl)cyclohexane cis and trans isomers; 1, I-bis(chloromethyl)cyclo-hexane; 1, I-bis(chloromethyl)cyclohexane cis and trans isomers; 1,4-bis(chloromethyl)cyclohexane; 1,4-bis(chloromethyl)cyclohexane cis and trans isomers; 1,2-bis(chloromethyl)benzene; 1,2,3-trichloropropane; 1,2,3-tribromopropane; ethane,1,1′-thiobis[2-[(2-chloroethyl)thio]-; ethane,1,1′-oxybis[2-chloro]-; sodium sulfide; sodium polysulfide; elemental sulfur or combinations thereof.

6. The sealant formulation of claim 1 comprising:
a polysulfide;
sodium aluminum sulfate or monocalcium phosphate;
and sodium bicarbonate.

7. A cured sealant made from the sealant formulation of claim 1 , wherein the cured sealant has a density ranging from about 0.6 g/cm 3 to about 1.0 g/cm 3 .

8. The sealant formulation of claim 1 , further comprising:
an aqueous media in an amount ranging from about 1 to about 5 weight %.

9. A component comprising a cured sealant made from the sealant formulation of claim 8 .

10. A vehicle comprising the component of claim 9 .

11. A method of manufacturing a polysulfide-containing sealant formulation comprising:
a polysulfide in an amount ranging from about 75 to about 90 weight %; an acid salt in an amount ranging from about 3 to about 10 weight %; and a bicarbonate in an amount ranging from about 2.5 to about 10 weight %, to form a first mixture.

12. The method of claim 11 , wherein, the step of combining a polysulfide with an acid salt and a bicarbonate to form a first mixture, the acid salt comprising at least one of:
sodium aluminum sulfate; monocalcium phosphate; delta-gluconolactone; sodium acid pyrophosphate; sodium aluminum phosphate; sodium aluminum pyrophosphate; or potassium bitartrate.

13. The method of claim 11 , wherein, the step of combining a polysulfide with an acid salt and a bicarbonate to form a first mixture, the bicarbonate comprising at least one of:
sodium bicarbonate; potassium bicarbonate; or ammonium bicarbonate.

14. The method of claim 11 , wherein, the step of combining a polysulfide with an acid salt and a bicarbonate to form a first mixture, the polysulfide comprising at least one of:
polysulfide polymers made from monomers comprising at least one of: 1,3-dichloropropane;
1,3-dibromopropane; 1,2-dichloropropane; 1,4-dichlorobutane; 1,4-dibromobutane; trans-1,4-dibromo-2-butene; 1,3-dichlorobutane; 1,2-dichlorobutane; 1,2-dibromobutane; 2,3-dichlorobutane; 2,3-dibromobutane; 1,5-dichloropentane; 1,5-dibromopentane; 1,4-dichloropentane; 1,4-dibromopentane; 1,3-dichloropentane; 1,2-dichloropentane; 2,3-dichloropentane; 2,4-dichloropentane; 1,6-dichlorohexane; 1,6-dibromohexane; 1,2-dichlorohexane; 1,2-dichlorocyclohexane; 1,2-dichlorocyclohexane cis and trans isomers; 1,3-dichlorocyclohexane; 1,3-dichlorocyclohexane cis and trans isomers; 1,4-dichlorocyclohexane; 1,4-dichlorocyclohexane cis and trans isomers; 1,2-bis(chloromethyl)cyclohexane; 1,2-bis(chloromethyl)cyclohexane cis and trans isomers; 1,1-bis(chloromethyl)cyclo-hexane; 1,1-bis(chloromethyl)cyclohexane cis and trans isomers; 1,4-bis(chloromethyl)cyclohexane; 1,4-bis(chloromethyl)cyclo-hexane cis and trans isomers; 1,2-bis(chloromethyl)benzene; 1,2,3-trichloropropane; 1,2,3-tribromopropane; ethane,1,1′-thiobis[2-[(2-chloroethyl)thio]-; ethane,1,1′-oxybis[2-chloro]-; sodium sulfide; sodium polysulfide; elemental sulfur or combinations thereof.

15. The method of claim 11 , wherein, in the step of combining a polysulfide with an acid salt and a bicarbonate to form a first mixture, the polysulfide is present in an amount ranging from about 75 to about 90 weight %, the acid salt is present in an amount ranging from about 3 to about 10 weight %, the bicarbonate is present in an amount ranging from about 2.5 to about 10 weight %.

16. The method of claim 11 , further comprising the step of:
adding an aqueous media to the first mixture to form a second mixture in an amount of from about 1 to about 5 weight %.

17. The method of claim 11 , after the step of combining a polysulfide with an acid salt and a bicarbonate to form a first mixture, further comprising the step of:
mixing the first mixture in a centrifugal mixer at predetermined and varying RPMs for predetermined durations.

18. The method of claim 17 , after the step of adding an aqueous media to the first mixture to form a second mixture, further comprising the step of:
mixing the second mixture in a centrifugal mixer at predetermined and varying RPMs for predetermined durations.

19. The method of claim 18 , further comprising the step of:
curing the second mixture.

20. The method of claim 19 , wherein, in the step of curing the second mixture, the curing is conducted at a temperature ranging from about 120° F. to about 145° F. for a duration of about 12 hours.

21. The method of claim 19 , wherein, in the step of curing the second mixture, the curing is conducted at a temperature ranging from about 70° F. to about 100° F.

22. The sealant formulation of claim 1 , wherein the sealant formulation cures to form sealant having a density ranging from about 0.6 g/cm 3 to about 1.0 g/cm 3 .

Assignees

• Boeing Co

Inventors

• Stevens Barton E
• Booth Brandon D
• Zweig Andrew M

Classifications

• C08K2003/262

  Alkali metal carbonates · CPC title

• C08L81/04

  Polysulfides · CPC title

• C09J181/04

  Polysulfides · CPC title

• C08G75/14

  Polysulfides · CPC title

• C08J2381/04

  Polysulfides · CPC title