Non-painting metallic polypropylene resin composition

Patent metadata

Field	Value
Publication number	US-10160855-B2
Application number	US-201715464965-A
Country	US
Kind code	B2
Filing date	Mar 21, 2017
Priority date	May 18, 2016
Publication date	Dec 25, 2018
Grant date	Dec 25, 2018

Abstract

A metallic polypropylene resin composition is provided herein. The metallic polypropylene resin composition provides appearance characteristics that are similar to those provided by painting, but without painting. The metallic polypropylene resin composition of the present invention has excellent physical properties such as scratch resistance, and thus may be applied to molding methods, such as a molded in color (MIC) method. The resin composition is useful as a material for automobile interior and exterior parts, as wells as electric and electronic products, which can be molded by the MIC method.

First claim

What is claimed is:

1. A non-painting metallic polypropylene resin composition comprising:
from about 52 to 97 wt % of a high-crystalline polypropylene resin having an isotactic pentad fraction of from about 96% or more as measured by a C 13 -NMR method;
from about 1 to 30 wt % of an olefin-based rubber;
from about 1 to 15 wt % of an ultra-fine talc having an average particle diameter of from about 0.1 to 1 μm;
from about 0.1 to 3.0 wt % of a scratch-resistant additive of a silica powder; and
from about 0.1 to 3.0 parts by weight of metal particles with respect to 100 parts by weight of the overall resin composition,
wherein the silica powder has a melt flow index (MI) of from about 80 to 130 g/10 min and an average particle diameter of from about 1 to 5 μm.

2. The non-painting metallic polypropylene resin composition of claim 1 , wherein the high-crystalline polypropylene resin is a polypropylene resin of a high-crystalline block copolymer.

3. The non-painting metallic polypropylene resin composition of claim 2 , wherein the high-crystalline block copolymer is one or more selected from a group consisting of a propylene-ethylene block copolymer, a propylene-1-butene block copolymer, and a propylene-1-hexene block copolymer.

4. The non-painting metallic polypropylene resin composition of claim 1 , wherein the high-crystalline polypropylene resin is a polypropylene resin of a block copolymer having a polydispersity index (PI) of from about 5 or more.

5. The non-painting metallic polypropylene resin composition of claim 1 , wherein the olefin-based rubber is an ethylene-butene rubber, an ethylene-octene rubber, or a mixture thereof.

6. The non-painting metallic polypropylene resin composition of claim 1 , wherein the metal particles are coin-shaped alumina particles having an average particle diameter of from about 5 to 50 μm.

7. An injection non-painting molded article molded by the resin composition of claim 1 .

8. The injection non-painting molded article of claim 7 , wherein the molded article is an automobile interior part, an automobile exterior part, an electric product, or an electronic product that is molded by a molded in color (MIC) method.

Assignees

• Hyundai Motor Co Ltd
• Kia Motors Corp
• Hanwha Total Petrochemical Co Ltd

Inventors

• Choi Min Jin
• Choi Young Ho
• Lee Yong Bum
• Jung Ji Hyun
• Han Jae Ho
• Lee Byoung Ho
• Lim Jae Gon
• Han Joung Hwan

Classifications

• B29L2031/3044

  Bumpers · CPC title

• B60R19/03

  characterised by material, e.g. composite (B60R19/18 takes precedence) · CPC title

• B29K2995/0041

  Crystalline · CPC title

• B29C45/0001

  characterised by the choice of material · CPC title

• B29K2505/00

  Use of metals, their alloys or their compounds, as filler · CPC title