Polyolefin compositions and articles manufactured therefrom

Patent metadata

Field	Value
Publication number	US-10160848-B2
Application number	US-201615778974-A
Country	US
Kind code	B2
Filing date	Nov 8, 2016
Priority date	Nov 24, 2015
Publication date	Dec 25, 2018
Grant date	Dec 25, 2018

Abstract

A polyolefin composition made from or containing:
A) from 55 to 75 wt % of a polyethylene having a density of 0.920 to 0.940 g/cm 3 and a fraction soluble in xylene (XS A ) of less than 10%, based upon the weight of the polyethylene; B) from 25 to 45 wt. % of a copolymer of ethylene with one or more comonomers selected from α-olefins having formula HC 2 ═CHR I , where R I is an alkyl radical, linear or branched, having from 1 to 8 carbon atoms, made from or containing from 50 to 70 wt. %, based upon the weight of the copolymer of ethylene, of ethylene and having a fraction soluble in xylene (XS B ) of at least about 50 wt. %, based upon the weight of the copolymer of ethylene;

the polyolefin composition having a flexural modulus of less than 260 MPa as measured according to ISO 178. The polyolefin composition is useful for producing geomembranes.

First claim

What is claimed is:

1. A polyolefin composition comprising:
A) from about 55 to about 75 wt. %, based upon the total weight of the polyolefin composition, of a polyethylene having a density of about 0.920 to about 0.940 g/cm 3 and a fraction soluble in xylene (XS A ) of less than about 10 wt. %, based upon the weight of the polyethylene, the polyethylene comprising ethylene and one or more comonomers selected from α-olefins having formula CH 2 ═CHR, wherein R is an alkyl radical, linear or branched, having from 1 to 10 carbon atoms; and
B) from about 25 to about 45 wt. %, based upon the total weight of the polyolefin composition, of a copolymer of ethylene with one or more comonomers selected from α-olefins having formula HC 2 ═CHR I , where R I is an alkyl radical, linear or branched, having from 1 to 8 carbon atoms, comprising from about 50 to about 70 wt. %, based upon the weight of the copolymer of ethylene, of ethylene and having a fraction soluble in xylene (XS B ) of at least about 50 wt. %, based upon the weight of the copolymer of ethylene;
the polyolefin composition having a flexural modulus of less than about 260 MPa as measured according to ISO 178.

2. The polyolefin composition according to claim 1 , wherein the amount of the α-olefin comonomer in polyethylene component A) is from about 4 to about 15 wt. %, based upon the weight of polyethylene component A).

3. The polyolefin composition according to claim 1 , wherein the α-olefin comonomer in polyethylene component A) is propylene, butene-1, or a mixture of propylene and butene-1.

4. The polyolefin composition according to claim 3 , wherein the polyethylene component A) comprises from about 2 to about 5 wt. %, based upon the weight of polyethylene component A), of propylene and from about 4 to about 7 wt. %, based upon the weight of polyethylene component A), of butene-1.

5. The polyolefin composition according to claim 1 , wherein the polyethylene component A) has a solubility in xylene (XS A ) at 25° C. of less than about 8 wt. %, based upon the weight of polyethylene component A).

6. The polyolefin composition according to claim 1 , wherein the ethylene copolymer of component B) comprises from about 35 to about 45 wt. % of propylene, based upon the weight of ethylene copolymer of component B).

7. The polyolefin composition according to claim 1 , wherein the ethylene copolymer of component B) has a fraction soluble in xylene (XS B ) of from about 70 to about 95 wt. %, based upon the weight of ethylene copolymer of component B).

8. The polyolefin composition according to claim 1 , having an ethylene content, determined on the total amount of A)+B), of about 70% to about 95% by weight.

9. The polyolefin composition according to claim 1 , comprising from about 60 to about 70 wt. %, based upon the total weight of the polyolefin composition, of Component A) and from about 30 to about 40 wt. %, based upon the total weight of the polyolefin composition, of Component B).

10. A polymerization process for producing a polyolefin composition having components A) and B), comprising:
at least two sequential stages, wherein
(i) components A) and B) are produced in separate subsequent stages,
(ii) the polymerization being carried out in each stage, except the first stage, in the presence of the polymer formed and the catalyst used in the preceding stage, and
(iii) the polyolefin composition having (a) from about 55 to about 75 wt. %, based upon the total weight of the polyolefin composition, of component A) (being a polyethylene having a density of about 0.920 to about 0.940 g/cm 3 and a fraction soluble in xylene (XS A ) of less than about 10 wt. %, based upon the weight of the polyethylene, the polyethylene made from and containing ethylene and one or more comonomers selected from α-olefins having formula CH 2 ═CHR, wherein R is an alkyl radical, linear or branched, having from 1 to 10 carbon atoms), (b) from about 25 to about 45 wt. %, based upon the total weight of the polyolefin composition, of component B) (being a copolymer of ethylene with one or more comonomers selected from α-olefins having formula HC 2 ═CHR I , where R I is an alkyl radical, linear or branched, having from 1 to 8 carbon atoms, comprising from about 50 to about 70 wt. %, based upon the weight of the copolymer of ethylene, of ethylene and having a fraction soluble in xylene (XS B ) of at least about 50 wt. %, based upon the weight of the copolymer of ethylene), and (c) a flexural modulus of less than about 260 MPa as measured according to ISO 178.

11. A composite polyolefin composition comprising:
(i) up to about 50% by weight, based upon the total weight of the composite polyolefin, of a first polyolefin composition comprising
A) from about 55 to about 75 wt. %, based upon the total weight of the first polyolefin composition, of a polyethylene having a density of about 0.920 to about 0.940 g/cm 3 and a fraction soluble in xylene (XS A ) of less than about 10 wt. %, based upon the weight of the polyethylene, the polyethylene made from and containing ethylene and one or more comonomers selected from α-olefins having formula CH 2 ═CHR, wherein R is an alkyl radical, linear or branched, having from 1 to 10 carbon atoms, and
B) from about 25 to about 45 wt. %, based upon the total weight of the first polyolefin composition, of a copolymer of ethylene with one or more comonomers selected from α-olefins having formula HC 2 ═CHR I , where R I is an alkyl radical, linear or branched, having from 1 to 8 carbon atoms, comprising from about 50 to about 70 wt. %, based upon the weight of the copolymer of ethylene, of ethylene and having a fraction soluble in xylene (XS B ) of at least about 50 wt. %, based upon the weight of the copolymer of ethylene, and
having a flexural modulus of less than about 260 MPa as measured according to ISO 178; and

(ii) at least about 50% by weight, based upon the total weight of the composite polyolefin, of an additional polyolefin.

12. The composite polyolefin composition according to claim 11 , wherein the additional polyolefin is selected from propylene homoploymers and propylene copolymers.

13. A shaped article comprising
A) from about 55 to about 75 wt. %, based upon the total weight of the first polyolefin composition, of a polyethylene having a density of about 0.920 to about 0.940 g/cm 3 and a fraction soluble in xylene (XS A ) of less than about 10 wt. %, based upon the weight of the polyethylene, the polyethylene made from and containing ethylene and one or more comonomers selected from α-olefins having formula CH 2 ═CHR, wherein R is an alkyl radical, linear or branched, having from 1 to 10 carbon atoms, and
B) from about 25 to about 45 wt. %, based upon the total weight of the first polyolefin composition, of a copolymer of ethylene with one or more comonomers selected from α-olefins having formula HC 2 ═CHR I , where R I is an alkyl radical, linear or branched, having from 1 to 8 carbon atoms, comprising from about 50 to about 70 wt. %, based upon the weight of the copolymer of ethylene, of ethylene and having a fraction soluble in xylene (XS B ) of at least about 50 wt. %, based upon the weight of the copolymer of ethylene, and
having a flexural modulus of less than about 260 MPa as measured according to ISO 178.

14. The shaped article according to claim 13 , selected from the group consisting of sheets, roofing membranes and geomembranes.

Assignees

• Basell Polyolefine Gmbh

Inventors

• Cavalieri Claudio
• Grazzi Michele

Classifications

• C08J2423/08

  Copolymers of ethene (C08J2423/16 takes precedence) · CPC title

• B29C48/32

  with annular openings, e.g. for forming tubular articles · CPC title

• C08L2314/02

  Ziegler natta catalyst · CPC title

• B29C48/10

  flexible, e.g. blown foils · CPC title

• C08J2323/08

  Copolymers of ethene (C08J2323/16 takes precedence) · CPC title