Methane conversion apparatus and process using a supersonic flow reactor

Patent metadata

Field	Value
Publication number	US-10160697-B2
Application number	US-201715630146-A
Country	US
Kind code	B2
Filing date	Jun 22, 2017
Priority date	Aug 21, 2012
Publication date	Dec 25, 2018
Grant date	Dec 25, 2018

Abstract

Apparatus and methods are provided for converting methane in a feed stream to acetylene. A hydrocarbon stream is introduced into a supersonic reactor and pyrolyzed to convert at least a portion of the methane to acetylene. The reactor effluent stream may be treated to convert acetylene to another hydrocarbon process.

First claim

The invention claimed is:

1. An apparatus for producing acetylene from a feed stream comprising methane comprising:
a supersonic reactor for receiving the methane feed stream and heating the methane feed stream to a pyrolysis temperature;
a reactor shell of the supersonic reactor for defining a reactor chamber;
a combustion zone of the supersonic reactor for combusting a fuel source to provide a high temperature carrier gas passing through the reactor space at supersonic speeds to heat and accelerate the methane feed stream to a pyrolysis temperature;
an outer layer of the reactor shell for providing structural support thereto;
an inner layer of the reactor shell having a thermal conductivity of between about 200 and about 500 W/m-K for conducting heat from the reactor chamber the inner layer comprising at least copper chrome, copper chrome zinc, copper chrome niobium, copper nickel and copper nickel tungsten and mixtures thereof; and
a coating comprising nickel metal, an alloy of nickel, chromium metal, an alloy of chromium, platinum metal, an alloy of platinum, palladium, or an alloy of palladium, or mixtures thereof applied to an inner surface of the inner layer of the reactor shell.

2. The apparatus of claim 1 wherein the coating comprises NiCrAlY, or NiCoCrAlY, or CoNiCrAlY, or Ni—P, or mixtures thereof.

3. The apparatus of claim 1 wherein the coating comprises NiCrAlY.

4. The apparatus of claim 1 wherein the coating is electroplated onto the inner surface of the inner layer.

5. The apparatus of claim 4 wherein the coating is thermally treated at a temperature of from about 482° C. to about 538° C. for about 1 to about 3 hours.

6. The apparatus of claim 4 wherein the coating comprises nickel metal.

7. The apparatus of claim 1 wherein the coating is applied to the inner surface of the inner layer using plasma spray techniques.

8. The apparatus of claim 7 wherein the coating is thermally treated at a temperature of from about 482° C. to about 538° C. for about 1 to about 3 hours.

9. The apparatus of claim 7 wherein the coating comprises NiCrAlY.

10. The apparatus of claim 1 wherein the coating is applied to the inner surface of the inner layer using an electroless plating process.

11. The apparatus of claim 10 wherein the coating is thermally treated at a temperature of from about 482° C. to about 538° C. for about 1 to about 3 hours.

12. The apparatus of claim 10 wherein the coating comprises Ni—P.

13. The apparatus of claim 1 wherein the coating further comprises a material capable of providing a thermal barrier.

14. The apparatus of claim 1 wherein the coating further comprises yttria-stabilized zirconia, lanthanum hexaluminate, rare earth-doped lanthanum hexaluminate, hafnium carbide, tungsten, or mixtures thereof.

15. The apparatus of claim 1 wherein the reactor shell is a composite having the inner and outer layers.

16. The apparatus of claim 1 wherein the inner layer and outer layers comprise separate castings and the castings are brazed together.

17. The apparatus of claim 1 further comprising one or more intermediate layers between the outer layer and the inner layer.

18. The apparatus of claim 1 further comprising one or more layers positioned outside of the outer layer.

19. A process for producing acetylene from a feed stream comprising methane comprising:
introducing the feed stream to a supersonic reactor wherein the supersonic reactor comprises:
a reactor shell of the supersonic reactor for defining a reactor chamber;
a combustion zone of the supersonic reactor for combusting a fuel source to provide a high temperature carrier gas passing through the reactor space at supersonic speeds to heat and accelerate the methane feed stream to a pyrolysis temperature;
an outer layer of the reactor shell for providing structural support thereto;
an inner layer of the reactor shell having a thermal conductivity of between about 200 and about 500 W/m-K for conducting heat from the reactor chamber the inner layer comprising at least copper chrome, copper chrome zinc, copper chrome niobium, copper nickel and copper nickel tungsten and mixtures thereof; and
a coating comprising a coating comprising nickel metal, an alloy of nickel, chromium metal, an alloy of chromium, platinum metal, an alloy of platinum, palladium, or an alloy of palladium, or mixtures thereof applied to an inner surface of the inner layer of the reactor shell;

combusting a fuel source to provide a high temperature carrier gas passing through the reactor at supersonic speeds to heat and accelerate the methane feed stream to a pyrolysis temperature, wherein upon heating and accelerating the methane stream, acetylene is generated; and
preventing formation of acetylides in the reactor by employing the coating that prevents the acetylene from contacting the copper of the inner layer of the reactor.

Assignees

• Uop Llc

Inventors

• Bedard Robert L
• Naunheimer Christopher
• Towler Gavin P
• Leonard Laura E
• Woodcock Gregory O
• Mittendorf Donald L
• Sattar Aziz
• Gatto Christopher D
• Murray Robert S

Classifications

• C10G2300/1025

  Natural gas · CPC title

• B01J19/26

  Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles · CPC title

• B01J19/02

  Apparatus characterised by being constructed of material selected for its chemically-resistant properties · CPC title

• C10G50/00

  Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation · CPC title

• C10G2400/24

  Acetylene and homologues · CPC title