Ultrahard nanotwinned diamond bulk material and method for preparing the same

Patent metadata

Field	Value
Publication number	US-10160654-B2
Application number	US-201414540836-A
Country	US
Kind code	B2
Filing date	Nov 13, 2014
Priority date	Nov 13, 2014
Publication date	Dec 25, 2018
Grant date	Dec 25, 2018

Abstract

The present invention relates to ultrahard nanotwinned diamond bulk materials and synthetic method thereof. In particular, the present invention discloses a diamond bulk material containing high density of nanocrystalline twins and synthetic method thereof, in which a nanotwinned diamond bulk is synthesized from particles of nanospherical onion-like carbon without diamond core (preferably with a size of 5-70 nm) as raw materials by using high temperature and high pressure synthesis. As compared with the prior art, the nanotwinned diamond bulk obtained according to the present invention has a much higher hardness than that of single crystal diamond and that of ultrahard polycrystalline diamond. The nanotwinned diamond bulk has wide prospects in various applications, including geological drilling, machining fields such as high speed cutting and precision and ultra-precision machining, abrasives, drawing dies, and special optics as well as other fields.

First claim

The invention claimed is:

1. A method for preparing a an ultrahard nanotwinned diamond bulk material, which has a grain size of 2-100 nm, Vickers hardness of 155-350 GPa and Knoop hardness of 140-240 GPa, and which has an internal nanocrystalline cubic structure possessing high density of twins inside its grains, comprising:
(1) pressing onion carbon without diamond core in a mold into a preform;
(2) loading the preform into a mold for high pressure synthesis, and treating the preform under about 4-35 GPa at about 1,200-2,300° C. for a sufficient time; and
(3) decompressing and cooling.

2. The method according to claim 1 , wherein the pressure employed in (2) is about 4-25 GPa.

3. The method according to claim 1 , wherein (2) is performed for about 1-600 minutes.

4. The method according to claim 1 , wherein the particle size of the particles of onion carbon without diamond core is 5-70 nm and the purity thereof is not less than 90%.

5. The method according to claim 1 , wherein the prepared diamond bulk material has a volume of 1-2000 mm 3 .

6. The method according to claim 1 , wherein the prepared diamond bulk material is an ultrahard nanotwinned diamond bulk material.

7. The method according to claim 6 , wherein the ultrahard nanotwinned diamond bulk material is a nanotwinned multi-crystal material comprising high density of twins inside its grains and having a twin thickness of 1-15 nm.

8. An ultrahard nanotwinned diamond bulk material, which has a grain size of 2-100 nm, Vickers hardness of 155-350 GPa and Knoop hardness of 140-240 GPa, and which has an internal nanocrystalline cubic structure possessing high density of twins inside its grains.

9. The ultrahard nanotwinned diamond bulk material according to claim 8 , wherein the volume of the diamond bulk material is 1-2000 mm 3 .

10. The ultrahard nanotwinned diamond bulk material according to claim 8 , wherein the fracture toughness (K 1C ) of the ultrahard nanotwinned diamond bulk material is 10-30 MPa·m 1/2 .

11. The ultrahard nanotwinned diamond bulk material according to claim 8 , wherein the Vickers hardness of the diamond bulk material is 160-340 GPa and the Knoop hardness of the diamond bulk material is 140-230 GPa.

Assignees

• Univ Yanshan

Inventors

• Tian Yongjun
• Huang Quan
• Yu Dongli
• Xu Bo
• He Julong
• Liu Zhongyuan
• Hu Wentao
• Zhao Zhisheng

Classifications

• C01B32/26

  Preparation (by using ultra-high pressure B01J3/06; by crystal growth C30B29/04) · CPC title

• C01B32/25 Primary

  Diamond · CPC title