Integrated process for the sustainable and autonomous co2-emission-free production of hydrogen and related system
US-2024200017-A1 · Jun 20, 2024 · US
US10160646B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10160646-B2 |
| Application number | US-201414337242-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 22, 2014 |
| Priority date | Jul 23, 2013 |
| Publication date | Dec 25, 2018 |
| Grant date | Dec 25, 2018 |
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Provided is a waste heat recovery apparatus including a first heat exchanger, a reformer and a reformer feed pre-heater sequentially disposed on or in the waste gas exhaust pipe from the upstream to the downstream thereof, wherein the waste gas temperature at the upstream of the waste gas exhaust pipe is higher than that at the downstream. In an embodiment, the reformer can be a hydrogen-generation reformer, and the generated hydrogen is introduced into the burning equipment for use. In such manner, the waste heat can be effectively utilized, and the carbon deposition issue inside the burning equipment can be fixed. A waste heat recovery method is also provided.
Opening claim text (preview).
The invention claimed is: 1. A waste heat recovery apparatus, comprising: a first heat exchanger, a reformer and a reformer feed pre-heater sequentially and discretely disposed within and from an upstream to a downstream of a same waste gas exhaust pipe, wherein a waste gas temperature at the upstream of the same waste gas exhaust pipe is higher than a waste gas temperature at the downstream, wherein an end of the reformer feed pre-heater is connected to a feeder for a reformer feed, and another end of the reformer feed pre-heater is connected to the reformer, wherein the reformer is installed with a temperature controller to control a temperature inside the reformer, and wherein the reformer comprises a catalyst bed and a heat balance pipe, the heat balance pipe is disposed closer to the upstream of the waste gas exhaust pipe than the catalyst bed of the reformer, and the reformer feed pre-heater is connected to the heat balance pipe feed through a pipe external to the waste gas exhaust pipe. 2. The waste heat recovery apparatus of claim 1 , wherein the waste gas temperature at the upstream of the same waste gas exhaust pipe is about 200° C. to 400° C., and the waste gas temperature at the downstream of the same waste gas exhaust pipe is about 100° C. to less than 200° C. 3. The waste heat recovery apparatus of claim 1 , wherein the temperature inside the reformer is controlled at about 200° C. to 350° C. 4. The waste heat recovery apparatus of claim 1 , wherein the reformer is a fossil fuel reformer for hydrogen generation. 5. The waste heat recovery apparatus of claim 4 , wherein a reformer feed used by the fossil fuel reformer for hydrogen generation comprises a C 1-5 hydrocarbon. 6. The waste heat recovery apparatus of claim 1 , wherein a cooling fluid of the first heat exchanger comprises water, air, a fuel feed or a combination thereof. 7. The waste heat recovery apparatus of claim 1 , further comprising a second heat exchanger disposed at a downstream of the reformer feed pre-heater. 8. The waste heat recovery apparatus of claim 7 , wherein a cooling fluid of the second heat exchanger comprises water, air, a fuel feed or a combination thereof. 9. The waste heat recovery apparatus of claim 7 , further comprising: a burning equipment, connected to the same waste gas exhaust pipe; a water pump, connected to the burning equipment sequentially through a first pipe, the second heat exchanger and a second pipe, and connected to the burning equipment sequentially through the first pipe, a third pipe, the first heat exchanger, a fourth pipe and the second pipe; an air supply, connected to the burning equipment sequentially through a fifth pipe, the second heat exchanger, an air blower and a sixth pipe; a fuel feeder, connected to the burning equipment sequentially through a seventh pipe, the second heat exchanger and an eighth pipe; a magnetic valve, configured to receive a signal from the temperature controller, thereby being turned on or turned off to control a water flow amount through the third pipe; and a ninth pipe, transferring hydrogen produced by the reformer to the eighth pipe. 10. A waste heat recovery apparatus, comprising: a first heat exchanger, a reformer and a reformer feed pre-heater sequentially and discretely arranged within a same waste gas exhaust pipe, wherein the same waste gas exhaust pipe is connected to a burning equipment, and the first heat exchanger and the reformer are disposed in the burning equipment, wherein an end of the reformer feed pre-heater is connected to a feeder for a reformer feed, and another end of the reformer feed pre-heater is connected to the reformer, wherein the reformer is installed with a temperature controller to control a temperature inside the reformer, wherein the waste gas exhaust pipe is at least partly in the burning equipment, and wherein the reformer comprises a catalyst bed and a heat balance pipe, the heat balance pipe is disposed closer to the upstream of the waste gas exhaust pipe than the catalyst bed of the reformer, and the reformer feed pre-heater is connected to the heat balance pipe feed through a pipe external to the waste gas exhaust pipe. 11. The waste heat recovery apparatus of claim 10 , wherein the temperature inside the reformer is controlled at about 400° C. to 800° C. 12. The waste heat recovery apparatus of claim 10 , wherein the reformer is a fossil fuel reformer for hydrogen generation. 13. The waste heat recovery apparatus of claim 12 , wherein a reformer feed used by the fossil fuel reformer for hydrogen generation comprises a C 1-5 hydrocarbon. 14. The waste heat recovery apparatus of claim 10 , wherein a cooling fluid of the first heat exchanger comprises water, air, a fuel feed or a combination thereof. 15. The waste heat recovery apparatus of claim 10 , further comprising a second heat exchanger disposed at a downstream of the reformer feed pre-heater. 16. The waste heat recovery apparatus of claim 15 , wherein a cooling fluid of the second heat exchanger comprises water, air, a fuel feed or a combination thereof. 17. The waste heat recovery apparatus of claim 15 , further comprising: a water pump, connected to the burning equipment sequentially through a first pipe, the second heat exchanger and a second pipe, and connected to the first heat exchanger inside the burning equipment sequentially through the first pipe and a third pipe; an air supply, connected to the burning equipment sequentially through a fourth pipe, the second heat exchanger, an air blower and a fifth pipe; a fuel feeder, connected to the burning equipment sequentially through a sixth pipe, the second heat exchanger and a seventh pipe; a magnetic valve, configured to receive a signal from the temperature controller, thereby being turned on or turned off to control a water flow amount through the third pipe; and a ninth pipe, transferring hydrogen produced by the reformer to the seventh pipe.
Natural gas or methane · CPC title
by combustion of fuel · CPC title
using catalysts · CPC title
Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines · CPC title
Higher hydrocarbons · CPC title
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