Coated articles and methods of making the same

Patent metadata

Field	Value
Publication number	US-10160005-B2
Application number	US-201615152311-A
Country	US
Kind code	B2
Filing date	May 11, 2016
Priority date	May 28, 2015
Publication date	Dec 25, 2018
Grant date	Dec 25, 2018

Abstract

During an example coating method, a metallic substrate is provided. A foundation coat precursor is applied on the metallic substrate. The foundation coat precursor includes a matrix and a plurality of capsules present in the matrix. Each capsule includes a shell and a healing agent surrounded by the shell. A basecoat precursor is applied, and a clearcoat precursor is applied. The metallic substrate, the foundation coat precursor, the basecoat precursor, and the clearcoat precursor are heated i) after each respective application or ii) simultaneously, in order to cure the foundation coat, basecoat, and clearcoat precursors and respectively form a foundation coat, a basecoat, and a clearcoat. The foundation coat is ultraviolet (UV) stable and bonds the metallic substrate to the basecoat and the clearcoat.

First claim

What is claimed is:

1. A coating method, comprising:
applying a foundation coat precursor on a metallic substrate, the foundation coat precursor including:
a sol matrix comprising titania or silica nanoparticles suspended in a liquid comprising water, ethanol, or butyl acetate; and
a plurality of capsules present in the sol matrix, each capsule including a shell capable of covalently bonding to the sol matrix and a healing agent surrounded by the shell, wherein the healing agent is an alcohol-based sol-gel material comprising titania or silica nanoparticles and is compatible with the sol matrix;

applying a basecoat precursor on the foundation coat precursor;
applying a clearcoat precursor on the basecoat precursor; and
heating the metallic substrate, the foundation coat precursor, the basecoat precursor, and the clearcoat precursor i) after each respective application or ii) simultaneously, in order to cure the foundation coat, basecoat, and clearcoat precursors and respectively form a foundation coat, a basecoat, and a clearcoat;
wherein the foundation coat is ultraviolet (UV) stable and bonds the metallic substrate to the basecoat and the clearcoat.

2. The method as defined in claim 1 wherein the metallic substrate is not subjected to an electro-deposition (ELPO) operation.

3. The method as defined in claim 1 wherein:
the applying of the foundation coat precursor includes dipping the metallic substrate in a tank containing the foundation coat precursor;
the applying of the basecoat includes spraying the basecoat over the foundation coat precursor after the foundation coat precursor has been applied on the metallic substrate; and
the applying of the clearcoat precursor includes spraying the clearcoat precursor over the basecoat precursor after the basecoat precursor has been applied over the foundation coat precursor.

4. The method as defined in claim 1 wherein the heating of the metallic substrate includes positioning the metallic substrate in an oven after applying the foundation coat precursor, the basecoat precursor, and the clearcoat precursor, and heating the metallic substrate using the oven at a temperature between about 220 degrees Fahrenheit and about 320 degrees Fahrenheit for a time between 15 minutes and 50 minutes.

5. A coated article, comprising:
a metallic substrate;
a foundation coat bonded to the metallic substrate, the foundation coat including:
cross-linked silica nanoparticles; and
a plurality of capsules disposed among the cross-linked silica particles, each capsule including a shell capable of covalently bonding to the cross-linked silica nanoparticles and a healing agent surrounded by the shell, wherein the healing agent is an alcohol-based sol-gel material comprising silica nanoparticles, and wherein the shell and the healing agent are chemically compatible with the cross-linked silica nanoparticles;

a basecoat disposed over the foundation coat, wherein the foundation coat is disposed between the metallic substrate and the basecoat; and
a clearcoat disposed over the basecoat, wherein the basecoat is disposed between the clearcoat and the foundation coat.

6. The coated article as defined in claim 5 wherein the coated article does not include an electro-deposition coat.

7. The coated article as defined in claim 5 wherein the plurality of capsules is a plurality of first capsules and the coated article further comprises a plurality of second capsules, wherein the first capsules include a resin as a first healing agent, and where the second capsules include a curing agent of the resin as a second healing agent.

8. The coated article as defined in claim 5 wherein the shell is selected from the group consisting of titania, silicon dioxide, quartz crystal, and silica glass.

9. The coated article as defined in claim 5 wherein the metallic substrate is formed of steel, aluminum, or magnesium.

10. A method for enhancing corrosion resistance of a metallic substrate, the method comprising:
incorporating a plurality of capsules in a sol matrix of a foundation coat precursor, each capsule including a shell capable of covalently bonding to the sol matrix and a healing agent surrounded by the shell, wherein the healing agent is an alcohol-based sol-gel material comprising silica nanoparticles suspended in a liquid that is compatible with the sol matrix, and wherein the sol matrix comprises silica nanoparticles suspended in a liquid comprising water, ethanol, or butyl acetate;
dipping the metallic substrate in a tank containing the foundation coat precursor in order to apply the foundation coat precursor over the metallic substrate;
applying a basecoat precursor over the foundation coat precursor;
applying a clearcoat precursor over the basecoat precursor; and
heating the metallic substrate, the foundation coat precursor, the basecoat precursor, and the clearcoat precursor i) after each respective application or ii) simultaneously, in order to cure the foundation coat precursor, the basecoat precursor, and the clearcoat precursor and to respectively form a foundation coat, a basecoat, and a clearcoat;
wherein the healing agent, when released from the shell, polymerizes with the sol matrix, resealing the foundation coat.

11. The method as defined in claim 10 wherein the incorporating of the plurality of capsules in the sol matrix includes adding the capsules to the sol matrix in an amount ranging from about 1 wt % to about 40 wt % of a total wt % of the sol matrix.

12. The method as defined in claim 1 wherein the sol matrix has a nanoparticle concentration of 25 wt % and the plurality of capsules has a nanoparticle concentration of 40 wt %.

13. The method as defined in claim 1 wherein the shell is selected from the group consisting of titania, silicon dioxide, quartz crystal, and silica glass.

14. The method as defined in claim 1 wherein the clearcoat precursor is selected from the group consisting of a hydroxyl acrylic, a polyester carbamate acrylic, a polyester, an epoxy, a blocked isocyanate system, and combinations thereof; and
wherein the metallic substrate is formed of at least one of steel, aluminum, or magnesium.

15. The coated article as defined in claim 7 wherein the resin of the first capsules is a vinyl-terminated polydimethylsiloxane (PDMS) resin and the curing agent of the second capsules is a polyisocyanate resin.

16. The method as defined in claim 1 wherein a silica nanoparticle source material is one of a silicon alkoxide or a sodium silicate, wherein the silicon alkoxide is selected from the group consisting of tetramethoxysilane and tetraethoxysilane and the sodium silicate is selected from the group consisting of sodium metasilicate, sodium polysilicate, and sodium orthosilicate.

17. The coated article as defined in claim 5 wherein the basecoat includes a pigment and one or more compounds selected from the group consisting of acrylics, vinyls, polyurethanes, polycarbonates, polyesters, alkyds, polyepoxy, polysiloxanes, resins, and combinations thereof.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Fan Hua-Tzu
• Arinez Jorge F
• Plazas Torres Alejandro Hernan

Classifications

• C23C18/1212

  Zeolites, glasses · CPC title

• B05D1/00 Primary

  Processes for applying liquids or other fluent materials (B05D5/00, B05D7/00 take precedence) · CPC title

• C23C18/127

  Preformed particles · CPC title

• C23C28/00

  Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D · CPC title

• C23C18/122

  Inorganic polymers, e.g. silanes, polysilazanes, polysiloxanes · CPC title