Aqueous solution of 2-dimethylamino-2-hydroxymethyl-1, 3-propanediol useful for acid gas removal from gaseous mixtures

Patent metadata

Field	Value
Publication number	US-10159930-B2
Application number	US-201515502708-A
Country	US
Kind code	B2
Filing date	Oct 6, 2015
Priority date	Oct 10, 2014
Publication date	Dec 25, 2018
Grant date	Dec 25, 2018

Abstract

The present invention relates to an aqueous alkanolamine solution demonstrating low volatility comprising 2-di-methylamino-2-hydroxymethyl-1, 3-propanediol useful for removing acid gases from gaseous mixtures. Said aqueous alkanolamine solution may further comprise one or more of an acid or acid-forming compound, another amino compound, an activator, a physical solvent, or one or more other compounds used in gal-liquid treatment practices. Further, the present invention relates to a process for removing acid gases from a gaseous mixture, preferably hydrogen sulfide, comprising the step of contacting the gaseous mixture with said aqueous alkanolamine solution. Examples of the gaseous mixtures include natural gas, synthesis gas, tail gas, and refinery gas.

First claim

What is claimed is:

1. A composition, comprising
an aqueous alkanolamine solution and a gas mixture including acid gases, the aqueous alkanolamine solution being for the removal of acid gases from the gas mixture, and said aqueous alkanolamine solution consisting essentially of:
(i) 2-dimethylamino-2-hydroxymethyl-1,3-propanediol,
(ii) an acid having a pKa of 8 or less or an acid-forming material capable of forming in aqueous medium an acid having a pKa of 8 or less,
(iii) an additional amino compound, and
(iv) water.

2. The composition of claim 1 wherein based on the total weight of the aqueous alkanolamine solution:
(i) the 2-dimethylamino-2-hydroxymethyl-1, 3-propanediol is present in an amount of from 0.1 to 75 weight percent,
(ii) the acid or acid-forming material is present in an amount of from 0.1 to 25 weight percent, and
(iii) the additional amino compound is present in an amount of from 0.1 to 75 weight percent.

3. The composition of claim 1 wherein the acid or acid-forming material (ii) is present in an amount of 0.1 to 25 weight percent and is phosphoric acid, sulfuric acid, boric acid, formic acid, or hydrochloric acid.

4. The composition of claim 1 wherein the additional amino compound (iii) is present in an amount of 0.1 to 75 weight percent and is monoethanolamine (MEA); tris(2-hydroxyethyl)amine (TEA); tris(2-hydroxypropyl)amine (triisopropanol); tributanolamine; bis(2-hydroxyethyl)methylamine (MDEA); 2-diethylaminoethanol (DEEA); 2-dimethylaminoethanol (DMEA); 3-dimethylamino-1-propanol; 3-diethylamino-1-propanol; 2-diisopropylaminoethanol (DIEA); N,N-bis(2-hydroxypropyl)methylamine (MDIPA); N,N′-bis(2-hydroxyethyl)piperazine (DiHEP); diethanolamine (DEA); 2-(tert-butylamino)ethanol; 2-(tert-butylaminoethoxy)ethanol; 2-amino-2-methylpropanol (AMP); 2-(2-amino-ethoxy)ethanol; or a 1-hydroxyethyl-4-pyridinlypiperazine compound.

5. The composition of claim 1 , wherein the acid gases include carbon dioxide, hydrogen sulfide, sulfur dioxide, carbon disulfide, hydrogen cyanide, carbonyl sulfide, or mercaptans as impurities.

6. The composition of claim 5 , wherein the gas mixture includes natural gas, refinery gas, hydrocarbon gases from shale pyrolysis, synthesis gas, or liquefied natural gas.

7. A composition, comprising
an aqueous alkanolamine solution and a gas mixture including acid gases, the aqueous alkanolamine solution being for the removal of acid gases from the gas mixture, and said aqueous alkanolamine solution consisting essentially of:
(i) 2-dimethylamino-2-hydroxymethyl-1,3-propanediol,
(ii) an acid having a pKa of 8 or less or an acid-forming material capable of forming in aqueous medium an acid having a pKa of 8 or less, and
(iii) water.

8. The composition of claim 7 wherein the acid or acid-forming material (ii) is present in an amount of 0.1 to 25 weight percent and is phosphoric acid, sulfuric acid, boric acid, formic acid, or hydrochloric acid.

9. The composition of claim 7 , wherein the acid gases include carbon dioxide, hydrogen sulfide, sulfur dioxide, carbon disulfide, hydrogen cyanide, carbonyl sulfide, or mercaptans as impurities.

10. The composition of claim 7 , wherein the gas mixture includes natural gas, refinery gas, hydrocarbon gases from shale pyrolysis, synthesis gas, or liquefied natural gas.

Assignees

• Dow Global Technologies Llc

Inventors

• Laroche Christophe R
• Dowdle John R

Classifications

• C10K1/143

  containing amino groups · CPC title

• C10K1/004

  Sulfur containing contaminants, e.g. hydrogen sulfide · CPC title

• C10K1/003

  of acid contaminants, e.g. acid gas removal · CPC title

• B01D2257/504

  Carbon dioxide · CPC title

• B01D2257/308

  Carbonoxysulfide COS · CPC title