Semiconducting component for electrographic device

Patent metadata

Field	Value
Publication number	US-10158082-B2
Application number	US-201414917982-A
Country	US
Kind code	B2
Filing date	Oct 14, 2014
Priority date	Oct 15, 2013
Publication date	Dec 18, 2018
Grant date	Dec 18, 2018

Abstract

A semiconducting component for an electrographic device, comprising a crosslinked body obtained by crosslinking a copolymer containing 9.9 to 39.9% by mole of structural units (a) originating from an epihalohydrin, 60 to 90% by mole of structural units (b) originating from an alkylene oxide, and 0.1 to 10% by mole of structural units (c) originating from a cyclic ether monomer having a (meth)acryloyl or alkoxysilyl group with use of reactivity of the structural units originating from the cyclic ether monomer having a (meth)acryloyl or alkoxysilyl group.

First claim

The invention claimed is:

1. A semiconducting component for an electrographic device, comprising a crosslinked body obtained by crosslinking a copolymer containing 9.9 to 39.9% by mole of structural units (a) originating from an epihalohydrin, 60 to 90% by mole of structural units (b) originating from an alkylene oxide, and 0.1 to 10% by mole of structural units (c) originating from a cyclic ether monomer having a (meth)acryloyl or alkoxysilyl group with use of reactivity of the structural units originating from the cyclic ether monomer having a (meth)acryloyl or alkoxysilyl group, and wherein, taking the total proportion of the copolymer to be 100% by weight, the copolymer is crosslinked with less than 0.1% by weight of crosslinking agent.

2. The semiconducting component for an electrographic device according to claim 1 , wherein the structural units (c) originating from the cyclic ether monomer having a (meth)acryloyl or alkoxysilyl group are each a structural unit originating from at least one selected from the group consisting of glycidyl acrylate, glycidyl methacrylate, 3-glycidoxypropyltrimethoxysilane, and 3-glycidoxypropylmethyldimethoxysilane.

3. The semiconducting component for an electrographic device according to claim 1 , wherein the structural units (a) originating from the epihalohydrin are each a structural unit originating from at least one selected from the group consisting of epichlorohydrin and epibromohydrin.

4. The semiconducting component for an electrographic device according to claim 1 , wherein the structural units (b) originating from the alkylene oxide are each a structural unit originating from at least one selected from the group consisting of ethylene oxide, propylene oxide and butylene oxide.

5. The semiconducting component for an electrographic device according to claim 1 , wherein the crosslinked body has a hardness of 10 to 80 in a hardness test according to type A in JIS K 6253-3:2012.

6. The semiconducting component for an electrographic device according to claim 1 , which is a semiconducting roll in which the crosslinked body is stacked on a substrate, the crosslinked body being a crosslinked body obtained by crosslinking the copolymer containing 9.9 to 39.9 by mole of the structural units (a) originating from the epihalohydrin, 60 to 90% by mole of the structural units (b) originating from the alkylene oxide, and 0.1 to 10% by mole of the structural units (c) originating from the cyclic ether monomer having a (meth)acryloyl or alkoxysilyl group with the use of the reactivity of the structural units originating from the cyclic ether monomer having a (meth)acryloyl or alkoxysilyl group.

7. An electrographic device comprising the semiconducting component for an electrographic device according to claim 1 .

8. The semiconducting component for an electrographic device according to claim 1 , wherein the crosslinked body does not comprise crosslinking agent.

9. The semiconducting component for an electrographic device according to claim 1 , wherein the copolymer contains 9.9% to 34.5% by mole of the structural units (a).

10. The semiconducting component for an electrographic device according to claim 1 , wherein the copolymer contains 9.9% to 29.5% by mole of the structural units (a).

11. The semiconducting component for an electrographic device according to claim 1 , wherein the copolymer contains 60% to 80% by mole of the structural units (b).

12. The semiconducting component for an electrographic device according to claim 1 , wherein the copolymer contains 65% to 80% by mole of the structural units (b).

13. The semiconducting component for an electrographic device according to claim 1 , wherein the copolymer contains 1% to 8% by mole of the structural units (c).

14. The semiconducting component for an electrographic device according to claim 1 , wherein the structural units (a) originate from epichlorohydrin.

15. The semiconducting component for an electrographic device according to claim 1 , wherein the structural units (b) originate from ethylene oxide.

16. The semiconducting component for an electrographic device according to claim 1 , wherein the structural units (c) originate from at least one of glycidyl methacrylate and 3-glycidoxypropyltrimethoxysilane.

17. The semiconducting component for an electrographic device according to claim 1 ,
wherein the structural units (a) originate from epichlorohydrin,
wherein the structural units (b) originate from ethylene oxide,
wherein the structural units (c) originate from at least one of glycidyl methacrylate and 3-glycidoxypropyltrimethoxysilane.

18. A semiconducting component for an electrographic device, comprising a crosslinked body obtained by crosslinking a copolymer containing 9.9 to 39.9% by mole of structural units (a) originating from an epihalohydrin, 60 to 90% by mole of structural units (b) originating from an alkylene oxide, and 0.1 to 10% by mole of structural units (c) originating from a cyclic ether monomer having a (meth)acryloyl or alkoxysilyl group with use of reactivity of the structural units originating from the cyclic ether monomer having a (meth)acryloyl or alkoxysilyl group, and wherein the copolymer is crosslinked without crosslinking agent.

Assignees

• Osaka Soda Co Ltd

Inventors

• Uno Kazuki
• Ohnuki Kohji
• Udo Shinichi
• Yasuda Yoritaka

Classifications

• G03G15/0233

  Structure, details of the charging member, e.g. chemical composition, surface properties · CPC title

• G03G15/0818

  characterised by the structure of the donor member, e.g. surface properties · CPC title

• G03G15/00 Primary

  Apparatus for electrographic processes using a charge pattern (G03G16/00, G03G17/00 take precedence) · CPC title

• G03G15/1685 Primary

  Structure, details of the transfer member, e.g. chemical composition · CPC title

• C08G59/02

  Polycondensates containing more than one epoxy group per molecule · CPC title