Titanate compound, alkali metal titanate compound and method for producing same, and power storage device using titanate compound and alkali metal titanate compound as active material
US-2016344025-A1 · Nov 24, 2016 · US
US10156277B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10156277-B2 |
| Application number | US-201615578806-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 28, 2016 |
| Priority date | Jun 2, 2015 |
| Publication date | Dec 18, 2018 |
| Grant date | Dec 18, 2018 |
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Provided is an alkali-metal titanate in which the content and adhesivity of the fibrous potassium titanate is significantly reduced. The alkali-metal titanate includes 0.5 mol to 2.2 mol of potassium oxide in terms of potassium atoms, 0.05 mol to 1.4 mol of sodium oxide in terms of sodium atoms, and 0 mol to 1.4 mol of lithium oxide in terms of lithium atoms relative to 1 mol of alkali-metal hexatitanate, in which a total content of potassium oxide in terms of potassium atoms, sodium oxide in terms of sodium atoms, and lithium oxide in terms of lithium atoms relative to 1 mol of alkali-metal hexatitanate is 1.8 mol to 2.3 mol; and the alkali-metal titanate has a single phase conversion ratio of 85% to 100%, a fiber ratio of 0% by volume to 10% by volume, and a moisture content of 0% by mass to 1.0% by mass.
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The invention claimed is: 1. An alkali-metal titanate comprising: 0.5 mol to 2.2 mol of potassium oxide in terms of potassium atoms, 0.05 mol to 1.4 mol of sodium oxide in terms of sodium atoms, and 0 mol to 1.4 mol of lithium oxide in terms of lithium atoms relative to 1 mol of alkali-metal hexatitanate, wherein a total content of potassium oxide in terms of potassium atoms, sodium oxide in terms of sodium atoms, and lithium oxide in terms of lithium atoms relative to 1 mol of alkali-metal hexatitanate is 1.8 mol to 2.3 mol; and the alkali-metal titanate has a single phase ratio of 85% to 100%, a fiber ratio of 0% by volume to 10% by volume, and a moisture content of 0% by mass to 1.0% by mass. 2. The alkali-metal titanate according to claim 1 , wherein the alkali-metal titanate comprises 0.9 mol to 2.2 mol of potassium oxide in terms of potassium atoms, 0.05 mol to 1.1 mol of sodium oxide in terms of sodium atoms, and 0 mol to 0.2 mol of lithium oxide in terms of lithium atoms relative to 1 mol of alkali-metal hexatitanate, and the alkali-metal titanate has a fiber ratio of 0% by volume to 7.0% by volume and a moisture content of 0% by mass to 0.8% by mass. 3. The alkali-metal titanate according to claim 1 , wherein the alkali-metal titanate comprises 1.2 mol to 2.2 mol of potassium oxide in terms of potassium atoms; 0.05 mol to 0.8 mol of sodium oxide in terms of sodium atoms; and 0 mol of lithium oxide in terms of lithium atoms relative to 1 mol of alkali-metal hexatitanate; the total content of potassium oxide in terms of potassium atoms, sodium oxide in terms of sodium atoms, and lithium oxide in terms of lithium atoms relative to 1 mol of alkali-metal hexatitanate is 1.9 mol to 2.2 mol; and the alkali-metal titanate has a fiber ratio of 0% by volume to 5.0% by volume and a moisture content of 0% by mass to 0.6% by mass. 4. A friction material comprising the alkali-metal titanate as claimed in claim 1 . 5. The alkali-metal titanate according to claim 2 , wherein the alkali-metal titanate comprises 1.2 mol to 2.2 mol of potassium oxide in terms of potassium atoms; 0.05 mol to 0.8 mol of sodium oxide in terms of sodium atoms; and 0 mol of lithium oxide in terms of lithium atoms relative to 1 mol of alkali-metal hexatitanate; the total content of potassium oxide in terms of potassium atoms, sodium oxide in terms of sodium atoms, and lithium oxide in terms of lithium atoms relative to 1 mol of alkali-metal hexatitanate is 1.9 mol to 2.2 mol; and the alkali-metal titanate has a fiber ratio of 0% by volume to 5.0% by volume and a moisture content of 0% by mass to 0.6% by mass. 6. A friction material comprising the alkali-metal titanate as claimed in claim 2 . 7. A friction material comprising the alkali-metal titanate as claimed in claim 3 . 8. A friction material comprising the alkali-metal titanate as claimed in claim 5 .
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