Nucleation with a block composite nucleator

Patent metadata

Field	Value
Publication number	US-10155861-B2
Application number	US-201515505475-A
Country	US
Kind code	B2
Filing date	Aug 20, 2015
Priority date	Aug 21, 2014
Publication date	Dec 18, 2018
Grant date	Dec 18, 2018

Abstract

A composition includes (A) 30-95 wt % of a random or homogeneous propylene-based interpolymer having: (i) a comonomer content of at least one of C 2 and C 4-10 α-olefins of 7 wt % to 49 wt % based on the total weight of the propylene-based interpolymer, (ii) a density of 0.90 g/cc or less, and (iii) an MFR of 1 g/10 min or greater (230° C./2.16 kg); and (B) 5-70 wt % of a block composite nucleator comprising: (1) a first polymer that includes polypropylene; (2) a second polymer that includes an alpha-olefin based polymer, the alpha-olefin being selected from at least one of a C 2 and C 4-10 α-olefins, and (3) a block copolymer having a first segment and a second segment, the first segment of the block copolymer having the same composition as the first polymer in the block composite nucleator and the second segment of the block copolymer having the same composition as the second polymer of the block composite nucleator.

First claim

What is claimed is:

1. A composition, comprising:
(A) 30-95 wt % of a random or homogeneous propylene-based interpolymer having: (i) a comonomer content of at least one of C 2 and C 4-10 α-olefins of 7 wt % to 49 wt % based on the total weight of the propylene-based interpolymer, (ii) a density of 0.90 g/cc or less, and (iii) an MFR of 1 g/10 min or greater (230° C./2.16 kg); and
(B) 5-70 wt % of a block composite nucleator comprising:
(1) a first polymer that includes polypropylene;
(2) a second polymer that includes an alpha-olefin based polymer, the alpha-olefin being ethylene; and
(3) a block copolymer having a first segment and a second segment, the first segment of the block copolymer having the same composition as the first polymer in the block composite nucleator and the second segment of the block copolymer having the same composition as the second polymer of the block composite nucleator, wherein the second segment of the block copolymer includes at least 80 wt % of the mer units derived from ethylene.

2. The composition as claimed in claim 1 , wherein the first segment of the block copolymer includes at least 80 wt % of mer units derived from propylene.

3. The composition as claimed in claim 1 , wherein the block composite nucleator is a nucleating agent and the composition excludes any other nucleating agents.

4. The composition as claimed in claim 1 , further comprising a tackifier and at least one selected from the group of a wax and an oil.

5. The composition as claimed in claim 1 , wherein a microstructure index of the block composite nucleator is greater than 1 and less than 20.

6. A composition, comprising:
(A) 30-95 wt % of a random or homogeneous propylene-based interpolymer having: (i) a comonomer content of at least one of C 2 and C 4-10 α-olefins of 7 wt % to 49 wt % based on the total weight of the propylene-based interpolymer, (ii) a density of 0.90 g/cc or less, and (iii) an MFR of 1 g/10 min or greater (230° C./2.16 kg); and
(B) 5-70 wt % of a block composite nucleator comprising:
(1) a first polymer that includes polypropylene;
(2) a second polymer that includes an alpha-olefin based polymer, the alpha-olefin being ethylene; and
(3) a block copolymer having a first segment and a second segment, the first segment of the block copolymer having the same composition as the first polymer in the block composite nucleator and the second segment of the block copolymer having the same composition as the second polymer of the block composite nucleator, wherein the block copolymer includes 30-50 wt % of the second segment and 50-70 wt % of the first segment, with the first segment comprising 5-20 wt % of mer units derived from ethylene and the second segment comprising 85-95 wt % of mer units derived from ethylene.

7. A process for nucleating a homogeneous propylene/α-olefin copolymer, comprising:
contacting under nucleating conditions the following:
(A) 30-95 wt % of a random or homogeneous propylene-based interpolymer having: (i) a comonomer content of at least one of C 2 and C 4-1 α-olefins of 7 wt % to 49 wt % based on the total weight of the propylene-based interpolymer, (ii) a density of 0.90 g/cc or less, and (iii) an MFR of 1 g/10 min or greater (230° C./2.16 kg); and
(B)5-70 wt % of a block composite nucleator comprising:
(1) a first polymer that includes polypropylene;
(2) a second polymer that includes an alpha-olefin based polymer, the alpha-olefin being ethylene; and
(3) a block copolymer having a first segment and a second segment, the first segment of the block copolymer having the same composition as the first polymer in the block composite nucleator and the second segment of the block copolymer having the same composition as the second polymer of the block composite nucleator, wherein the second segment of the block copolymer includes at least 80 wt % of the mer units derived from ethylene.

Assignees

• Dow Global Technologies Llc

Inventors

• Jin Yi
• Walton Kim L
• Hughes Morgan M
• Karjala Thomas W
• Chopin Iii Lamy J
• Lee Dean
• Cong Rongjuan

Classifications

• C08L23/16 Primary

  Ethylene-propylene or ethylene-propylene-diene copolymers · CPC title

• C08L53/00

  Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers · CPC title

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C09J123/20

  having four to nine carbon atoms · CPC title

• C08L23/142 Primary

  at least partially crystalline copolymers of propene with other olefins · CPC title