Blowing agent compositions of hydrochlorofluoroolefins
US-9206297-B2 · Dec 8, 2015 · US
US10155856B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10155856-B2 |
| Application number | US-201715408838-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 18, 2017 |
| Priority date | Jan 22, 2016 |
| Publication date | Dec 18, 2018 |
| Grant date | Dec 18, 2018 |
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The present invention provides a process comprising reacting polyisocyanate with active hydrogen-containing compound in the presence of Z-1,1,1,4,4,4-hexafluoro-2-butene at a temperature of at least 135° F. (57.2° C.) or a temperature of 135° F. (57.2° C.) to 150° F. (65.6° C.) to obtain as a result thereof, foamed reaction product, wherein the thermal conductivity of the foamed reaction product exhibits no appreciable change at any of the foaming temperatures within this range.
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What is claimed is: 1. Process comprising reacting polyisocyanate with active hydrogen-containing compound in the presence of Z-1,1,1,4,4,4-hexafluoro-2-butene at a temperature of at least 135° F(57.2° C.) to obtain as a result thereof, foamed reaction product. 2. The process of claim 1 wherein said temperature is 135° F(57.2° C.) to 150° F(65.6° C.). 3. The process of claim 1 wherein said temperature is 140° F(60.0° C.) to 150° F(65.6° C.). 4. The process of claim 1 wherein said active hydrogen-containing compound is polyol. 5. The process of claim 1 wherein said reaction product is polyurethane polyisocyanurate, or a mixture of these polymers. 6. The process of claim 1 wherein said active hydrogen-containing compound and said Z-1,1,1,4,4,4-hexafluoro-2-butene are combined into a composition prior to said reacting with said polyisocyanate. 7. The process of claim 6 wherein said composition also comprises at least one of catalyst, surfactant, flame retardant. 8. The process of claim 7 wherein said composition contains each of said catalyst, surfactant, and flame retardant.
Polyisocyanates or polyisothiocyanates · CPC title
premixing or pre-blending a part of the components of a foamable composition, e.g. premixing the polyol with the blowing agent, surfactant and catalyst and only adding the isocyanate at the time of foaming · CPC title
Rigid foams · CPC title
Manufacture of cellular products · CPC title
Aerosol, e.g. polyurethane foam spray · CPC title
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