Heat-resistant silane crosslinked resin molded body and method of producing the same, heat-resistant silane crosslinkable resin composition and method of producing the same, silane master batch, and heat-resistant product using heat-resistant silane crosslinked resin molded body

Patent metadata

Field	Value
Publication number	US-10155854-B2
Application number	US-201615081301-A
Country	US
Kind code	B2
Filing date	Mar 25, 2016
Priority date	Sep 27, 2013
Publication date	Dec 18, 2018
Grant date	Dec 18, 2018

Abstract

A method comprising at least (a) a step of preparing a silane master batch by melt-kneading, to 100 parts by mass of a base resin (R B ) containing a non-aromatic organic oil and ethylene rubber, an organic peroxide of from 0.01 to 0.6 parts by mass, an inorganic filler of from 10 to 400 parts by mass, and a silane coupling agent of from 1 to 15.0 parts by mass, at a temperature equal to or higher than the decomposition temperature of the organic peroxide; a heat-resistant silane crosslinked resin molded body and a heat-resistant silane crosslinkable resin composition prepared by the method, and a silane master batch and a heat-resistant product.

First claim

The invention claimed is:

1. A method of producing a heat-resistant silane crosslinked resin molded body, comprising:
(a) a step of preparing a silane master batch by melt-kneading, to 100 parts by mass of a base resin (R B ) containing a non-aromatic organic oil and an ethylene rubber containing a terpolymer of ethylene, α-olefin and diene, from 0.01 to 0.6 parts by mass of an organic peroxide, from 10 to 400 parts by mass of an inorganic filler, and from 1 to 15.0 parts by mass of a silane coupling agent, at a temperature equal to or higher than the decomposition temperature of the organic peroxide,
(b) a step of obtaining a mixture by mixing the silane master batch and a silanol condensation catalyst,
(c) a step of obtaining a molded body by molding the mixture, and
(d) a step of obtaining a heat-resistant silane crosslinked resin molded body by contacting the molded body with water,
wherein a content of said ethylene rubber in the base resin (R B ) is from 15 to 55 mass %.

2. The method of producing a heat-resistant silane crosslinked resin molded body according to claim 1 , wherein the base resin (R B ) further comprises a styrene-based elastomer.

3. The method of producing a heat-resistant silane crosslinked resin molded body according to claim 1 , wherein the silane coupling agent is vinyltrimethoxysilane or vinyltriethoxysilane.

4. The method of producing a heat-resistant silane crosslinked resin molded body according to claim 1 , wherein the inorganic filler is at least one selected from the group consisting of silica, aluminum hydroxide, magnesium hydroxide, calcium carbonate, and antimony trioxide.

5. The method of producing a heat-resistant silane crosslinked resin molded body according to claim 1 , wherein the melt-kneading at the step (a) is performed in an enclosed mixer.

6. The method of producing a heat-resistant silane crosslinked resin molded body according to claim 1 , wherein substantially no silanol condensation catalyst is mixed in the step (a).

7. A method of producing a heat-resistant silane crosslinkable resin composition, comprising:
(a) a step of preparing a silane master batch by melt-kneading, to 100 parts by mass of a base resin (R B ) containing a non-aromatic organic oil and an ethylene rubber containing a terpolymer of ethylene, α-olefin and diene, from 0.01 to 0.6 parts by mass of an organic peroxide, from 10 to 400 parts by mass of an inorganic filler, and from 1 to 15.0 parts by mass of a silane coupling agent, at a temperature equal to or higher than the decomposition temperature of the organic peroxide, and
(b) a step of obtaining a mixture by mixing the silane master batch and a silanol condensation catalyst,
wherein a content of said ethylene rubber in the base resin (R B ) is from 15 to 55 mass %.

8. A heat-resistant silane crosslinkable resin composition produced by the method according to claim 7 .

9. A heat-resistant silane crosslinked resin molded body produced by the method according to claim 1 .

10. The heat-resistant silane crosslinked resin molded body according to claim 9 , wherein the heat-resistant silane crosslinked resin molded body contains a resin crosslinked with the inorganic filler through a silanol bond in the silane coupling agent.

11. A heat-resistant product having the heat-resistant silane crosslinked resin molded body according to claim 9 .

12. The heat-resistant product according to claim 11 , wherein the heat-resistant silane crosslinked resin molded body is provided as a coating for an electric wire or an optical fiber cable.

13. A silane master batch, for use in a production of a heat-resistant silane crosslinkable resin composition formed by melt-mixing, to 100 parts by mass of a base resin (R B ) containing a non-aromatic organic oil and an ethylene rubber containing a terpolymer of ethylene, α-olefin and diene, from 0.01 to 0.6 parts by mass of an organic peroxide, from 10 to 400 parts by mass of an inorganic filler, from 1 to 15.0 parts by mass of a silane coupling agent, and a silanol condensation catalyst,
wherein all or part of the base resin (R B ), the organic peroxide, the inorganic filler, and the silane coupling agent are melt-mixed at a temperature equal to or higher than the decomposition temperature of the organic peroxide, and
wherein a content of said ethylene rubber in the base resin (R B ) is from 15 to 55 mass %.

Assignees

• Furukawa Electric Co Ltd

Inventors

• Nishiguchi Masaki
• Matsumura Arifumi

Classifications

• C08J3/22

  using masterbatch techniques · CPC title

• H01B3/441

  from alkenes · CPC title

• C08L2201/08

  Stabilised against heat, light or radiation or oxydation · CPC title

• C08L23/06

  Polyethylene · CPC title

• C08J2423/16

  Ethene-propene or ethene-propene-diene copolymers · CPC title