Production of isocyanate functional organosilanes

Patent metadata

Field	Value
Publication number	US-10155779-B2
Application number	US-201515526518-A
Country	US
Kind code	B2
Filing date	Oct 29, 2015
Priority date	Nov 21, 2014
Publication date	Dec 18, 2018
Grant date	Dec 18, 2018

Abstract

Isocyanate-functional silanes are prepared in high yield by pyrolysis of an O-carbamate prepared by reaction of a dialkylcarbonate with an aminoalkyl-functional silane in the presence of a basic catalyst, where the catalyst is neutralized by an acid which has a pK a of all protolysis stages of not more than 4. The neutralized or partially neutralized catalyst need not be removed prior to pyrolysis. The isocyanato-functional silanes exhibit higher storage stability as compared to those prepared from O-carbamates where catalyst neutralization is effected by weak acids.

First claim

The invention claimed is:

1. A process for preparing isocyanatoorganosilanes of the formula (4)
OCN—R 2 —SiR 3 (3-x) (OR 4 ) x   (4),

comprising reacting at least one aminoorganosilane of the formula (6),
NH 2 —R 2 —SiR 3 (3-x) (OR 4 ) x   (6),

with at least one dialkyl carbonate of the formula (7),

to form carbamatoorganosilanes of the formula (5),

in the presence of a basic metal alkoxide catalyst, and
pyrolyzing the carbamatoorganosilanes of the formula (5)
completely or partially neutralizing the basic metal alkoxide catalyst with an acid, all of whose protolysis stages have pK a values of not more than 4.0, before pyrolysis to form the isocyanatoorganosilanes,
where
R 1 , R 3 , R 4 and R 5 are identical or different and are each a monovalent, unsubstituted or substituted hydrocarbon radical,
R 2 is a divalent, unsubstituted or substituted hydrocarbon radical and
x is 1, 2 or 3.

2. The process of claim 1 , wherein at least one acid is selected from the group consisting of halogen-containing acids and acids containing halogen and oxygen, sulfur-containing acids, nitrous acid and nitric acid.

3. The process of claim 1 , wherein the acid is selected from among halogen-hydrogen acids having a direct halogen-oxygen bond.

4. The process of claim 2 , wherein the acid is selected from among halogen-hydrogen acids having a direct halogen-oxygen bond.

5. The process of claim 1 , wherein at least one acid is sulfuric acid or toluenesulfonic acid.

6. The process of claim 1 , wherein the acid is added in the complete or partial neutralization in such an amount that from 0.9 to 5 mol of acidic hydrogens are present per 1 mol of alkoxide ions m the catalyst.

7. The process of claim 2 , wherein the acid is added in the complete or partial neutralization in such an amount that from 0.9 to 5 mol of acidic hydrogens are present per 1 mol of alkoxide ions in the catalyst.

8. The process of claim 3 , wherein the acid is added in the complete or partial neutralization in such an amount that from 0.9 to 5 mol of acidic hydrogens are present pet 1 mol of alkoxide ions in the catalyst.

9. The process of claim 1 , wherein R 1 is an alkyl radical having 1 or 4 carbon atoms.

10. The process of claim 1 , wherein R 5 is an alkyl radical having 1 or 4 carbon atoms.

11. The process of claim 1 , wherein all radicals R 4 , R 1 and R 5 are identical.

12. The process of claim 1 , wherein the neutralization product of the catalyst and the acid is solid at 20° C. and is not separated off from the dialkyl carbonate of formula (7).

13. The process of claim 1 , wherein the basic metal alkoxide catalyst comprises an alkoxide of an alkali metal or of an alkaline earth metal.

Assignees

• Wacker Chemie Ag

Inventors

• Stanjek Volker
• Zander Lars

Classifications

• C07F7/1892 Primary

  by reactions not provided for in C07F7/1876 - C07F7/1888 · CPC title

• C07F7/1804

  Compounds having Si-O-C linkages (Si-O-acyl linkages C07F7/1896) · CPC title

• B01J31/0212

  Alkoxylates · CPC title