Processes and systems for converting hydrocarbons to cyclopentadiene

Patent metadata

Field	Value
Publication number	US-10155703-B2
Application number	US-201615288439-A
Country	US
Kind code	B2
Filing date	Oct 7, 2016
Priority date	Nov 4, 2015
Publication date	Dec 18, 2018
Grant date	Dec 18, 2018

Abstract

This invention relates to a process for converting acyclic C 5 hydrocarbons to cyclic C 5 compounds including cyclopentadiene in a reactor system, wherein the process comprises: providing to the reactor system a feedstock comprising acyclic C 5 hydrocarbons; providing to the reactor system a particulate material comprising a catalyst material; contacting the feedstock and the particulate material in at least one reaction zone under reaction conditions to convert at least a portion of the acyclic C 5 hydrocarbons to a first effluent comprising cyclopentadiene; wherein the feedstock flows co-current to a direction of a flow of the particulate material.

First claim

What is claimed is:

1. A process for converting acyclic C 5 hydrocarbons to cyclic C 5 compounds including cyclopentadiene in a reactor system, wherein the process comprises:
providing to the reactor system a feedstock comprising acyclic C 5 hydrocarbons;
providing to the reactor system a particulate material comprising a catalyst material;
contacting the feedstock and the particulate material in at least one reaction zone under reaction conditions to convert at least a portion of the acyclic C 5 hydrocarbons to a first effluent comprising cyclopentadiene; and
wherein the feedstock flows co-current to a direction of a flow of the particulate material.

2. The process of claim 1 , wherein an isothermal temperature profile is maintained in the at least one reaction zone.

3. The process of claim 1 , wherein the at least one reaction zone is a circulating fluidized bed reactor.

4. The process of claim 1 , wherein the feedstock is provided at a temperature of less than or equal to about 500° C.

5. The process of claim 1 , wherein the first effluent exiting the at least one reaction zone has a temperature of at least about 550° C.

6. The process of claim 1 further comprising: transferring at least a portion of the particulate material from the at least one reaction zone to a reheating zone, wherein the reheating zone comprises one or more heating devices.

7. The process of claim 6 further comprising:
contacting the particulate material with hydrogen to remove at least a portion of incrementally deposited coke material on the catalyst material thereby forming rejuvenated catalyst material and a volatile hydrocarbon; and
returning the rejuvenated catalyst material to the at least one reaction zone.

8. The process of claim 7 , wherein the reheating zone is operated at a temperature of about 550° C. to about 800° C.

9. The process of claim 7 , wherein at least 10 wt % of the incrementally deposited coke material is removed from the catalyst material.

10. The process of claim 7 , wherein the reheating zone comprises a plurality of fluid bed tubes within a furnace and/or a fluidized bed having one or more heating devices.

11. The process of claim 6 further comprising:
transferring at least a portion of the particulate material from the at least one reaction zone to a regeneration zone; wherein the particulate material is contacted with a regeneration gas under regenerating conditions to oxidatively remove at least a portion of coke material deposited on the catalyst material thereby forming a regenerated catalyst material; and
recycling at least a portion of the regenerated catalyst material to the at least one reaction zone or the reheating zone.

12. The process of claim 1 further comprising feeding hydrogen to the at least one reaction zone.

13. The process of claim 1 , wherein the at least one reaction zone comprises at least one heating device.

14. The process of claim 1 , wherein the reaction conditions comprise a temperature of about 450° C. to about 800° C. and a pressure of about 3 psia to about 80 psia.

15. The process of claim 1 , wherein at least about 30 wt % of the acyclic C 5 hydrocarbons is converted to cyclopentadiene.

16. The process of claim 1 , wherein the particulate material further comprises an inert material.

17. The process of claim 16 , wherein the catalyst material has an average diameter of about 50 μm to about 1,000 μm and the inert material has an average diameter of about 50 μm to about 1,000 μm.

18. The process of claim 16 , wherein the particulate material comprises less than or equal to about 30 wt % inert material.

19. The process of claim 1 , wherein the particulate material comprises at least about 30 wt % catalyst material.

20. The process of claim 1 , wherein the catalyst material comprises platinum on ZSM-5, platinum on zeolite L, and/or platinum on silica.

21. The process of claim 1 , wherein the particulate material provides at least about 50% of required heat for converting at least a portion of the acyclic C 5 hydrocarbons to the first effluent comprising cyclopentadiene.

22. The process of claim 1 , wherein the at least one reaction zone comprises at least a first reaction zone and a second reaction zone operated in parallel.

23. The process of claim 22 , wherein the first reaction and second reaction zones are a circulating fluidized bed reactor.

24. The process of claim 6 further comprising providing fresh particulate material (i) directly to the at least one reaction zone and/or (ii) to the reheating zone before entering the at least one reaction zone.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Iaccino Larry L
• Lemoine Romain O V

Classifications

• C07C5/373 Primary

  with simultaneous isomerisation · CPC title

• C07C13/15

  with a cyclopentadiene ring · CPC title

• B01J29/44

  Noble metals · CPC title

• C07C2529/44

  Noble metals · CPC title

• B01J29/63

  Iron group metals or copper · CPC title