Processes and systems for converting hydrocarbons to cyclopentadiene

Patent metadata

Field	Value
Publication number	US-10155702-B2
Application number	US-201615288430-A
Country	US
Kind code	B2
Filing date	Oct 7, 2016
Priority date	Nov 4, 2015
Publication date	Dec 18, 2018
Grant date	Dec 18, 2018

Abstract

This invention relates to a process for converting acyclic C 5 hydrocarbons to cyclopentadiene in a reactor system, wherein the process comprises a reaction interval comprising: cyclically providing to the reactor system a feedstock comprising acyclic C 5 hydrocarbons; contacting the feedstock and with a particulate material comprising a catalyst material in a first reaction zone under reaction conditions to convert at least a portion of the acyclic C 5 hydrocarbons to a first effluent comprising cyclopentadiene; and a reheating interval comprising: cyclically halting the feedstock to the first reaction zone; and providing a reheating gas to the first reaction zone to reheat the particulate material.

First claim

What is claimed is:

1. A process for converting acyclic C 5 hydrocarbons to cyclic C 5 s including cyclopentadiene in a reactor system, wherein the process comprises:
a reaction interval comprising:
cyclically providing to the reactor system a feedstock comprising acyclic C 5 hydrocarbons;
contacting the feedstock with a particulate material comprising a catalyst material in a first reaction zone under reaction conditions to convert at least a portion of the acyclic C 5 hydrocarbons to a first effluent comprising cyclopentadiene; and
a reheating interval comprising:
cyclically halting the feedstock to the first reaction zone; and
providing a reheating gas to the first reaction zone to reheat the particulate material.

2. The process of claim 1 , wherein an inverse temperature profile or an isothermal temperature profile is maintained in the first reaction zone.

3. The process of claim 1 , wherein the first reaction zone is a fixed bed reactor or a fluidized bed reactor.

4. The process of claim 1 , wherein the first reaction zone is a horizontal fixed bed reactor or a vertical fixed bed reactor.

5. The process of claim 1 , wherein the feedstock flows co-current or counter-current to a direction of a flow of the reheating gas.

6. The process of claim 1 , wherein the feedstock is provided at a temperature of less than or equal to about 525° C.

7. The process of claim 1 , wherein the first effluent exiting the at least first reaction zone has a temperature of at least about 575° C.

8. The process of claim 1 , wherein the reaction interval is performed until the temperature in the first reaction zone falls below about 550° C.

9. The process of claim 1 , wherein the reheating gas comprises hydrogen and the reheating gas contacts the particulate material to remove at least a portion of incrementally deposited coke material on the catalyst material thereby forming a rejuvenated catalyst material and volatile hydrocarbon.

10. The process of claim 1 , wherein the reheating gas enters the at least first reaction zone at a temperature of at least about 600° C. and a pressure of about 100 psia.

11. The process of claim 9 , wherein at least about 10.0 wt % of the incrementally deposited coke material is removed from the catalyst material.

12. The process of claim 1 , wherein the reaction interval and/or the reheating interval has a duration of about 1 min to about 90 min.

13. The process of claim 1 further comprising a regeneration interval comprising:
cyclically halting the feedstock to the first reaction zone;
supplying a regeneration gas to the first reaction zone; and
contacting the particulate material with the regeneration gas under regenerating conditions to remove at least a portion of coke material deposited on the catalyst material thereby forming a regenerated catalyst material.

14. The process of claim 13 , wherein the regeneration interval occurs at an interval of every about 1 day to about 50 days.

15. The process of claim 1 , wherein the first reaction zone comprises at least one heating device.

16. The process of claim 1 , wherein the reaction conditions comprise a temperature of about 400° C. to about 700° C. and an outlet pressure of about 3 psia to about 30 psia.

17. The process of claim 1 , wherein the particulate material further comprises an inert material.

18. The process of claim 1 , wherein the catalyst material has an average diameter of about 1.0 mm to about 20.0 mm and the inert material has an average diameter of about 3.0 mm to about 20.0 mm.

19. The process of claim 17 , wherein the particulate material comprises at least about 25.0 wt % inert material.

20. The process of claim 1 , wherein the catalyst material comprises platinum on ZSM-5; platinum on zeolite L, and/or platinum on silica.

21. The process of claim 1 , wherein the particulate material provides at least a portion (such as about 50%) of heat required for converting at least a portion of the acyclic C 5 hydrocarbons to the first effluent comprising cyclopentadiene.

22. The process of claim 1 , further comprising a second reaction zone, and a third reaction zone operated in parallel with the first reaction zone;
wherein during the reaction interval in the first reaction zone:
a reheating interval is performed in the second reaction zone, wherein a second feedstock comprising acyclic C 5 hydrocarbons fed to the second reaction zone is cyclically halted; a second reheating gas is supplied to the second reaction zone and contacts a particulate material comprising a catalyst material to reheat the particulate material, and/or remove at least a portion of incrementally deposited coke material on the catalyst material thereby forming a reheated and/or rejuvenated catalyst material and a volatile hydrocarbon; and
a regeneration interval is performed in the third reaction zone, wherein a third feedstock comprising acyclic C 5 hydrocarbons fed to the third reaction zone is cyclically halted; a regeneration gas is supplied to the third reaction zone and contacts a particulate material comprising a catalyst material under regenerating conditions to remove at least a portion of coke material deposited on the catalyst material thereby forming a regenerated catalyst material.

23. The process of claim 1 , wherein the reheating gas is substantially free of reactive oxygen-containing compounds.

24. The process of claim 1 , wherein the catalyst composition is formed into a structured catalyst shape.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Iaccino Larry L
• Lemoine Romain O V

Classifications

• C07C5/373 Primary

  with simultaneous isomerisation · CPC title

• Y02P20/584

  Recycling of catalysts · CPC title

• B01J29/90

  Regeneration or reactivation · CPC title

• C07C2101/10

  Chemistry & Metallurgy · mapped topic

• C07C2601/10

  the ring being unsaturated · CPC title