Lithium ion batteries using discrete carbon nanotubes, methods for production thereof and products obtained therefrom

Patent metadata

Field	Value
Publication number	US-10153483-B2
Application number	US-201213529797-A
Country	US
Kind code	B2
Filing date	Jun 21, 2012
Priority date	Jun 23, 2011
Publication date	Dec 11, 2018
Grant date	Dec 11, 2018

Abstract

Compositions, and methods of obtaining them, useful for lithium ion batteries comprising discrete oxidized carbon nanotubes having attached to their surface lithium ion active materials in the form of nanometer sized crystals or layers. The composition can further comprise graphene or oxygenated graphene.

First claim

What is claimed is the following:

1. A composition useful for lithium ion batteries comprising: discrete, non-agglomerated, and exfoliated carbon nanotubes having a surface, and mixtures of ion active materials comprising migratable ions said materials comprising crystals or layers of lithium ion active material, wherein a ratio of lithium ion to other total ions in the ion active materials is at least 2:1 to 25:1, and wherein the discrete carbon nanotubes have crystals or layers of lithium ion active material ionically attached to their surface and wherein the discrete carbon nanotubes comprise oxidized species selected from the group consisting of carboxylic, ketone, or hydroxyl functionalities, and wherein the discrete carbon nanotubes have an aspect ratio of 10 to 500 and oxidation levels from 1% to 15% by weight of the carbon nanotube.

2. The composition of claim 1 , wherein the crystals or layers of lithium ion active material comprise a lithium metal salt and an element selected from the group consisting of: iron, manganese, cobalt, copper, nickel, vanadium, titanium, and mixtures thereof.

3. The composition of claim 2 , wherein the lithium metal salt has an olivine crystal structure and wherein the lithium metal salt is LiFePO 4 or LiMnPO 4 .

4. The composition of claim 1 , wherein the crystals or layers of lithium ion active material comprise tin, silicon, copper, antimony, aluminum, germanium, titanium, or mixtures thereof.

5. The composition of claim 1 , further comprising graphene or oxygenated graphene.

6. The composition of claim 5 , wherein the weight ratio of graphene to carbon nanotube is in the range of 0.1:99.9 to 99.9:0.1.

7. A composition useful for lithium ion batteries, comprising discrete, non-agglomerated, and exfoliated carbon nanotubes having a surface, and mixtures of ion active materials comprising migratable ions said materials comprising crystals or layers of lithium ion active material, wherein a ratio of lithium ion to other total ions in the ion active materials is at least 2:1 to 25:1, wherein the discrete carbon nanotubes have crystals or layers of lithium ion active materials ionically attached to their surface, and wherein the carbon nanotubes are in a weight ratio of carbon nanotubes to lithium salts of 0.1% to 10% and wherein the discrete carbon nanotubes comprise oxidized species selected from the group consisting of carboxylic, ketone, or hydroxyl functionalities, and wherein the discrete carbon nanotubes have an aspect ratio of 10 to 500 and oxidation levels from 1% to 15% by weight of the carbon nanotube.

8. A composition useful for lithium ion batteries, comprising oxidized discrete, non-agglomerated, and exfoliated carbon nanotubes having a surface, and mixtures of ion active materials comprising migratable ions said materials comprising crystals or layers of lithium ion active material, wherein a ratio of lithium ion to other total ions in the ion active materials is at least 2:1 to 25:1, wherein the discrete carbon nanotubes have crystals or layers of lithium ion active materials attached to their surface, and wherein the carbon nanotubes are uniformly dispersed without clustering on a dimension scale of less than about 1 micrometer and wherein the discrete carbon nanotubes comprise oxidized species selected from the group consisting of carboxylic, ketone, or hydroxyl functionalities, and wherein the discrete carbon nanotubes have an aspect ratio of 10 to 500 and oxidation levels from 1% to 15% by weight of the carbon nanotube.

9. A composition useful for lithium ion batteries, comprising uniformly dispersible oxidized, non-agglomerated carbon nanotubes having a surface, and mixtures of ion active materials comprising migratable ions said materials comprising crystals or layers of lithium ion active material, wherein a ratio of lithium ion to other total ions in the ion active materials is at least 2:1 to 25:1, and wherein the discrete carbon nanotubes have crystals or layers of lithium ion active materials ionically attached to their surface and wherein the discrete carbon nanotubes comprise oxidized species selected from the group consisting of carboxylic, ketone, or hydroxyl functionalities, and wherein the discrete carbon nanotubes have an aspect ratio of 10 to 500 and oxidation levels from 1% to 15% by weight of the carbon nanotube.

10. The composition of claim 9 , wherein the crystals or layers of lithium ion active materials are chemically attached to the surface of the dispersible oxidized carbon nanotubes.

11. The composition of claim 1 where the ratio of lithium ion to other total ions in the ion active materials is from 3:1 to 25:1.

12. The composition of claim 1 where the ratio of lithium ion to other total ions in the ion active materials is from 10:1 to 25:1.

13. The composition of claim 7 where the ratio of lithium ion to other total ions in the ion active materials is from 3:1 to 25:1.

14. The composition of claim 7 where the ratio of lithium ion to other total ions in the ion active materials is from 10:1 to 25:1.

15. The composition of claim 8 where the ratio of lithium ion to other total ions in the ion active materials is from 3:1 to 25:1.

16. The composition of claim 8 where the ratio of lithium ion to other total ions in the ion active materials is from 10:1 to 25:1.

17. The composition of claim 9 where the ratio of lithium ion to other total ions in the ion active materials is from 3:1 to 25:1.

18. The composition of claim 9 where the ratio of lithium ion to other total ions in the ion active materials is from 10:1 to 25:1.

Assignees

• Bosnyak Clive P
• Swogger Kurt W
• Molecular Rebar Design Llc

Inventors

• Bosnyak Clive P
• Swogger Kurt W

Classifications

• H01M2004/027

  Negative electrodes · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M4/625

  Carbon or graphite · CPC title

• H01M4/133

  Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title