Cost efficient kraft cooking method using polysulfide cooking liquor

Patent metadata

Field	Value
Publication number	US-10151063-B2
Application number	US-201415506359-A
Country	US
Kind code	B2
Filing date	Aug 26, 2014
Priority date	Aug 26, 2014
Publication date	Dec 11, 2018
Grant date	Dec 11, 2018

Abstract

The invention is related to a method for the preparation of kraft pulp with increased pulping yield from lignin-containing cellulosic material using polysulfide cooking liquor. In order to obtain a cost efficient system both in aspects of investment costs but also in aspects of heat economy of operating the process is most of the total charge of alkali charged as heated polysulfide liquor to an first atmospheric vessel, wherein the hot polysulfide liquor flashes off steam providing most if not all of the necessary steaming effect for the cellulose material. The polysulfide liquor is then allowed to impregnate the cellulose material at a temperature closer to cooking temperature but still so low that essentially no delignification occurs in impregnation vessel, as the H-factor in impregnation vessel is kept within 1-20.

First claim

The invention claimed is:

1. A method for the preparation of kraft pulp with increased pulping yield from lignin-containing cellulosic material using polysulfide cooking liquor, comprising:
feeding the lignin containing cellulosic material which has not been previously steamed to the top of a first vessel operating at an applied pressure in the top of the first vessel of at most 0.2 bar, and establishing an upper level of lignin containing cellulosic material in the first vessel;
determining a total charge of alkaline cooking liquor in the form of polysulfide liquor for the first vessel;
heating the polysulfide liquor to a temperature above its boiling point, allowing water to evaporate off from the polysulfide liquor;
charging at least 80% of the total charge of the alkaline cooking liquor, in the form of the polysulfide liquor, to the first vessel and establishing a lower level of liquor below said upper level, thus keeping steam and the lignin containing cellulosic material in a volume above the lower level of liquor;
keeping the suspended lignin containing cellulosic material in the first vessel for a sufficient time to reach an H-factor of at least 1;
feeding the suspended lignin containing material from the bottom of the first vessel to the top of a second vessel and cooking the lignin containing cellulosic material at full cooking temperature in the range of from 130 to 160° C. to a final kappa number below 40, while adding any of the remaining charge of the alkaline cooking liquor, preferably in form of polysulfide liquor, during feeding to or cooking in the second vessel.

2. The method according to claim 1 , including adding additional steam to the volume of the lignin containing cellulosic material kept above the lower level of liquor.

3. The method according to claim 1 , wherein the liquor in the first vessel has an alkali concentration above 60 g/l and a polysulfide concentration above 3 g/l, when charging the polysulfide cooking liquor, establishing a liquor-to-wood ratio in the range 2.0 to 3.2 in said first vessel.

4. The method according to claim 1 , including keeping the suspended liquor containing cellulosic material in the first vessel for a sufficient time to reach an H-factor between 1 and 20.

5. The method according to claim 1 , wherein the liquor in the first vessel has an alkali concentration above 60 g/l and a polysulfide concentration above 0.09 mol/l, when charging the polysulfide cooking liquor, establishing a liquor-to-wood ratio in the range 2.0 to 3.2 in said first vessel.

6. A method for the preparation of kraft pulp with increased pulping yield from lignin-containing cellulosic material using polysulfide cooking liquor, comprising:
feeding the lignin containing cellulosic material which has not been previously steamed to the top of a first vessel operating at an applied pressure in the top of the first vessel of at most 0.2 bar, and establishing an upper level of lignin containing cellulosic material in the first vessel;
determining a total charge of alkaline cooking liquor in the form of polysulfide liquor for the first vessel;
heating the polysulfide liquor to a temperature above its boiling point, allowing water to evaporate off from the polysulfide liquor;
charging at least 80% of the total charge of the alkaline cooking liquor, in the form of the polysulfide liquor, to the first vessel and establishing a lower level of liquor below said upper level, thus keeping steam and the lignin containing cellulosic material in a volume above the lower level of liquor;
adding additional steam to the volume of the lignin containing cellulosic material kept above the lower level of liquor;
keeping the suspended lignin containing cellulosic material in the first vessel for a sufficient time to reach an H-factor of at least 1;
feeding the suspended lignin containing material from the bottom of the first vessel to the top of a second vessel and cooking the lignin containing cellulosic material at full cooking temperature in the range of from 130 to 160° C. to a final kappa number below 40, while adding any of the remaining charge of the alkaline cooking liquor, preferably in form of polysulfide liquor, during feeding to or cooking in the second vessel; and
withdrawing a part of the liquor volume in the first vessel from the wall of the first vessel and circulating said part of the liquor volume back to the volume of the lignin containing cellulosic material in the first circulation.

7. The method according to claim 6 , including heating the first circulation from a heat source.

8. The method according to claim 7 , including adding the polysulfide liquor to the first circulation.

9. The method according to claim 6 , including heating the polysulfide liquor added to the first vessel from a heat source.

10. The method according to claim 9 , including adding the heated polysulfide liquor to the first circulation.

11. The method according to any of claim 7 , wherein the heat source is hot spent cooking liquor withdrawn from the second vessel.

12. The method according to any of claim 7 , wherein the heat source is steam.

13. The method according to claim 12 , wherein the steam is from the low pressure steam out of a pulp mill.

Assignees

• Valmet Oy

Inventors

• Antonsson Stefan
• Olsson Krister

Classifications

• D21C3/24

  Continuous processes · CPC title

• D21C3/022 Primary

  in presence of S-containing compounds · CPC title

• D21C3/26

  Multistage processes · CPC title

• D21C1/06 Primary

  with alkaline reacting compounds · CPC title

• D21C7/06

  Feeding devices · CPC title