High-strength titanium alloy member and production method for same

Patent metadata

Field	Value
Publication number	US-10151019-B2
Application number	US-201113817087-A
Country	US
Kind code	B2
Filing date	Aug 15, 2011
Priority date	Aug 20, 2010
Publication date	Dec 11, 2018
Grant date	Dec 11, 2018

Abstract

A production method for a titanium alloy member includes preparing a titanium alloy material for sintering as a raw material of a sintered body; nitriding the titanium alloy material for sintering, thereby forming a nitrogen compound layer and/or a nitrogen solid solution layer in a surface layer of the titanium alloy material for sintering and yielding a nitrogen-containing titanium alloy material for sintering; mixing the titanium alloy material for sintering and the nitrogen-containing titanium alloy material for sintering, thereby yielding a titanium alloy material for sintering mixed with nitrogen-containing titanium alloy material; sintering the titanium alloy material for sintering mixed with nitrogen-containing titanium alloy material, thereby bonding the material each other and dispersing nitrogen contained in the nitrogen-containing titanium alloy material for sintering in a condition in which nitrogen is uniformly dispersed into an entire inner portion of the sintered body by solid solution.

First claim

The invention claimed is:

1. A titanium alloy member comprising:
a fine acicular structure; and
0.054 to 0.093 mass % of nitrogen contained in solid solution,
wherein the fine acicular structure includes acicular crystals having a thickness of 5 μm or less,
the fine acicular structure consists of a β phase of which an area ratio is 0.1 to 1.0%, the balance being only α phase, and
the alloy member has a bending strength of 2286 to 2318 MPa in a three-point bending test.

2. The titanium alloy member according to claim 1 , wherein the alloy member is yielded from a titanium alloy selected from Ti-6Al-4V, Ti-3Al-2.5V, Ti-4Al-3Mo-1V, Ti-5Al-2Cr-1Fe, Ti-5Al-1.5Fe-1.5Cr-1.5Mo, Ti-6Al-Nb-1Ta-1Mo, Ti-8Al-1Mo-1V, Ti-8Al-4Co, Ti-6Al-2Xn-4Zr-2Mo, Ti-6Al-6V-2Sn, and Ti-6Al-2Sn-4Zr-6Mo.

3. The titanium alloy member according to claim 1 , containing no TiN phase.

4. A production method for a titanium alloy member according to claim 1 , the method comprising:
preparing a titanium alloy material;
separating a portion of the titanium alloy material and nitriding the portion, thereby forming at least a nitrogen solid solution layer in a surface layer of the portion, thereby yielding a nitrogen-containing titanium alloy material;
mixing the titanium alloy material and the nitrogen-containing titanium alloy material, thereby yielding a titanium alloy material mixed with nitrogen-containing titanium alloy material;
sintering the titanium alloy material mixed with nitrogen-containing titanium alloy material, thereby bonding the materials together and dispersing nitrogen contained in the nitrogen-containing titanium alloy material and forming a sintered body in a condition in which nitrogen is uniformly dispersed into an entire inner portion of the sintered body by solid solution, and
subjecting the sintered body to solution heat treatment and annealing treatment in this order, thereby obtaining a titanium alloy member having a fine acicular structure.

5. The production method for a titanium alloy member according to claim 4 , wherein the titanium alloy material for sintering is titanium alloy fiber obtained by a molten metal extraction method.

6. The production method for a titanium alloy member according to claim 4 , wherein the solution heat treatment is performed at a temperature within 100° C. from a β transus temperature, and the annealing treatment is performed in a temperature range of 450 to 750° C.

7. The production method for a titanium alloy member according to claim 4 , wherein the titanium alloy member after the solution heat treatment has a martensitic structure.

8. The production method for a titanium alloy member according to claim 4 , wherein the titanium alloy member after the solution heat treatment mainly has a structure of an α′ phase (hexagonal martensitic crystal) as a main structure.

9. The production method for a titanium alloy member according to claim 4 , wherein the sintering is performed by hot pressing.

10. The production method for a titanium alloy member according to claim 9 , wherein the hot pressing is performed in a temperature range of 900 to 1300° C.

Assignees

• Araoka Yuji
• Shiraishi Tohru
• Ono Yoshiki
• Nhk Spring Co Ltd

Inventors

• Araoka Yuji
• Shiraishi Tohru
• Ono Yoshiki

Classifications

• B22F1/14

  Treatment of metallic powder (mixing with lubricating or binding agents or with organic material B22F1/10) · CPC title

• B22F1/145

  Chemical treatment, e.g. passivation or decarburisation · CPC title

• B22F1/062

  Fibrous particles · CPC title

• C23C8/80

  After-treatment · CPC title

• B22F3/24

  After-treatment of workpieces or articles {(B22F3/1146 takes precedence)} · CPC title