Grease compositions comprising estolide base oils

Patent metadata

Field	Value
Publication number	US-10150931-B2
Application number	US-201715449768-A
Country	US
Kind code	B2
Filing date	Mar 3, 2017
Priority date	Jun 17, 2011
Publication date	Dec 11, 2018
Grant date	Dec 11, 2018

Abstract

Provided herein are grease compositions comprising at least one estolide compound of formula:

in which n is an integer equal to or greater than 0; m is an integer equal to or greater than 2; R 1 , independently for each occurrence, is selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; R 2 is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R 3 and R 4 , independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Also provided are methods of making estolide-based grease products.

First claim

The invention claimed is:

1. A composition comprising:
at least 25% by weight of an estolide base oil; and
at least one thickener selected from a metal soap, a polyurea, a fluorocarbon resin, or a silica.

2. The composition according to claim 1 , wherein the estolide base oil comprises one or more compounds of Formula I:

wherein
x is, independently for each occurrence, an integer selected from 0 to 20;
y is, independently for each occurrence, an integer selected from 0 to 20;
n is equal to or greater than 0;
R 1 is selected from hydrogen and an optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and
R 2 is an optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched;
wherein each fatty acid chain residue of said at least one compound is independently optionally substituted.

3. The composition according to claim 2 , wherein
x is, independently for each occurrence, an integer selected from 0 to 14;
y is, independently for each occurrence, an integer selected from 0 to 14;
n is an integer selected from 0 to 20;
R 1 is an optionally substituted C 1 to C 22 alkyl that is saturated or unsaturated, and branched or unbranched; and
R 2 is an unsubstituted C 1 to C 22 alkyl that is saturated or unsaturated, and branched or unbranched,
wherein each fatty acid chain residue is unsubstituted.

4. The composition according to claim 3 , wherein R 1 is unsubstituted and unbranched.

5. The composition according to claim 4 , wherein R 1 is saturated.

6. The composition according to claim 3 , wherein R 2 is saturated.

7. The composition according to claim 3 , wherein x is, independently for each occurrence, an integer selected from 7 and 8.

8. The composition according to claim 7 , wherein y is, independently for each occurrence, an integer selected from 7 and 8.

9. The composition according to claim 3 , wherein x is 10 for each occurrence.

10. The composition according to claim 9 , wherein y is 5 for each occurrence.

11. The composition according to claim 3 , wherein said estolide base oil has an EN selected from an integer or fraction of an integer that is equal to or greater than 3, wherein EN is the average number of estolide linkages in compounds according to Formula I.

12. The composition according to claim 3 , wherein the at least one thickener comprises one or more of a simple lithium soap or a complex lithium soap.

13. The composition according to claim 12 , wherein the at least one thickener comprises one or more of lithium stearate, lithium 12-hydroxy stearate, lithium 16-hydroxystearate, or lithium ricinoleate.

14. The composition according to claim 3 , wherein the at least one thickener comprises a metal soap that is a reaction product of at least one metal-based material and at least one carboxylic acid or carboxylic acid ester.

15. The composition according to claim 14 , wherein the at least one metal-based material comprises one or more of a metal hydroxide, a metal carbonate, a metal bicarbonate, or a metal oxide.

16. The composition according to claim 14 , wherein the metal of the at least one metal-based material comprises one or more of an alkali metal or alkaline earth metal.

17. The composition according to claim 3 , wherein said composition further comprises at least one additive.

18. The composition according to claim 17 , wherein the at least one additive comprises one or more of a preservative, an antioxidant, a colorant, an anti-weld agent, an extreme pressure agent, a flame retardant, a rust inhibitor, a corrosion inhibitor, an oil bleed inhibitor, a metal deactivator, a viscosity modifier, a tackifier, or a pour point depressant.

19. The composition according to claim 3 , wherein the estolide base oil comprises 30% to 95% by weight of the composition.

20. The composition according to claim 3 , wherein the estolide base oil comprises 50% to 95% by weight of the composition.

21. The composition according to claim 3 , wherein the at least one thickener comprises one or more of a simple metal soap or a complex metal soap.

22. The composition according to claim 3 , further comprising at least one trimellitate.

23. The composition according to claim 3 , wherein the at least one thickener comprises a polyurea.

24. The composition of claim 23 , wherein the at least one thickener comprises a polyurea complex.

25. The composition of claim 3 , wherein the at least one thickener comprises a silica.

26. The composition of claim 25 , wherein the at least one thickener comprises a fumed silica.

Assignees

• Biosynthetic Technologies Llc

Inventors

• Bredsguard Jakob
• Forest Jeremy

Classifications

• C10N2030/64

  Environmental friendly compositions · CPC title

• C10M2207/026

  with tertiary alkyl groups · CPC title

• C10N2030/02

  Pour-point; Viscosity index · CPC title

• C10M2207/1285

  used as thickening agents · CPC title

• C10M2223/045

  Metal containing thio derivatives · CPC title