Ionizing radiation resistant polycarbonate resin composition and article comprising the same

Patent metadata

Field	Value
Publication number	US-10150864-B2
Application number	US-201615195058-A
Country	US
Kind code	B2
Filing date	Jun 28, 2016
Priority date	Jun 30, 2015
Publication date	Dec 11, 2018
Grant date	Dec 11, 2018

Abstract

Disclosed herein is a polycarbonate resin composition. The polycarbonate resin composition includes: a polycarbonate resin; a polyalkylene glycol compound; and an anthraquinone colorant, wherein the polycarbonate resin composition has a yellow index (YI) of about −2 to about 2, as measured in accordance with ASTM D1925 after irradiating an about 3.2 mm thick specimen with γ-rays at about 25 kGy and leaving the specimen for 7 days and has an a* value of about −2 to about 2 and a b* value of −2 to about 2 as measured in accordance with ASTM D2244 after irradiating an about 3.2 mm thick specimen with γ-rays at about 25 kGy and leaving the specimen for 7 days. The polycarbonate resin composition can exhibit excellent properties in terms of color, transparency, and impact resistance after being irradiated with ionizing radiation.

First claim

What is claimed is:

1. A polycarbonate resin composition comprising:
a polycarbonate resin;
a polyalkylene glycol compound; and
an anthraquinone colorant comprising a red anthraquinone colorant and a violet anthraquinone colorant in a weight ratio of from 1:1.30 to 1:1.72,
wherein the polycarbonate resin composition has a yellow index (YI) of about −2 to about 2, as measured in accordance with ASTM D1925 after irradiating an about 3.2 mm thick specimen with γ-rays at about 25 kGy and leaving the specimen for 7 days and has an a* value of about −2 to about 2 and a b* value of −2 to about 2 as measured in accordance with ASTM D2244 after irradiating an about 3.2 mm thick specimen with γ-rays at about 25 kGy and leaving the specimen for 7 days.

2. The polycarbonate resin composition according to claim 1 , comprising the polyalkylene glycol compound in an amount of about 0.4 parts by weight to about 1 parts by weight based on about 100 parts by weight of the polycarbonate resin, and the anthraquinone colorant in an amount of about 0.0001 parts by weight to about 0.002 parts by weight based on about 100 parts by weight of the polycarbonate resin.

3. The polycarbonate resin composition according to claim 1 , further comprising: an epoxy ester compound represent by Formula 1:

wherein R 1 and R 3 are the same or different and are each independently a C 1 to C 10 hydrocarbon group; R 2 and R 4 are the same or different and are each independently a hydrogen atom or a C 1 to C 10 hydrocarbon group, wherein R 1 and R 2 are optionally connected to one another to form a ring and/or R 3 and R 4 are optionally connected to one another to form a ring; m and n are the same or different and are each independently 0 or 1; and m+n is 1 or 2.

4. The polycarbonate resin composition according to claim 3 , comprising the epoxy ester compound in an amount of about 0.001 parts by weight to about 3 parts by weight based on about 100 parts by weight of the polycarbonate resin.

5. The polycarbonate resin composition according to claim 1 , wherein the polycarbonate resin composition has a transmittance of about 80% or higher, as measured in accordance with ASTM D1003 after irradiating an about 3.2 mm thick specimen with γ-rays at about 25 kGy and leaving the specimen for about 7 days.

6. The polycarbonate resin composition according to claim 1 , wherein the polycarbonate resin composition has an Izod impact strength of about 90 kgf cm/cm or higher, as measured in accordance with ASTM D256 after irradiating an about 3.2 mm thick Izod specimen with γ-rays at about 25 kGy and leaving the specimen for about 7 days.

7. A molded article formed of the polycarbonate resin composition according to claim 1 .

8. The molded article according to claim 7 , wherein the molded article is an ionizing radiation resistant medical supply article.

Assignees

• Lotte Advanced Mat Co Ltd

Inventors

• Jang Hyun Hye
• Chei Woo Suk
• Hur Jong Chan
• Kwon O Sung
• Chi Jun Ho

Classifications

• C08K5/08

  Quinones · CPC title

• C08L71/02

  Polyalkylene oxides · CPC title

• C08K5/0041

  Optical brightening agents, organic pigments · CPC title

• C08L69/00 Primary

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title

• C08L2201/08

  Stabilised against heat, light or radiation or oxydation · CPC title