Enhanced polycarbonate extrusion grades

Patent metadata

Field	Value
Publication number	US-10150855-B2
Application number	US-201515111929-A
Country	US
Kind code	B2
Filing date	Mar 4, 2015
Priority date	Mar 6, 2014
Publication date	Dec 11, 2018
Grant date	Dec 11, 2018

Abstract

In an embodiment, a method for making a thermoplastic composition, comprising: melt polymerizing a polycarbonate, extruding and melt filtering the polycarbonate to form a melt filtered polycarbonate; forming the thermoplastic composition comprising the melt filtered polycarbonate, 0.03 to 0.05 wt % of a triacylglyceride release agent; and 0.10 to 0.14 wt % of a UV stabilizer; wherein the weight percentages are based on the total weight of the composition; and extruding the thermoplastic composition.

First claim

What is claimed is:

1. A method for making a thermoplastic composition, comprising:
melt polymerizing a polycarbonate,
extruding and melt filtering the polycarbonate to form a melt filtered polycarbonate;
forming the thermoplastic composition comprising
the melt filtered polycarbonate,
0.03 to 0.05 wt % of a triacylglyceride release agent; and
0.10 to 0.14 wt % of a UV stabilizer;
wherein the weight percentages are based on the total weight of the composition; and

extruding the thermoplastic composition.

2. The method of claim 1 , further comprising forming a multi-wall sheet from the thermoplastic composition.

3. The method of claim 1 , wherein the composition is free of stearyl stearate, glycerol monostearate, and pentaerythrityl tetrastearate.

4. The method of claim 1 , wherein the polycarbonate has a branching level of 1000 to 1200 ppm by weight and/or wherein the polycarbonate has an MVR of 5.5 to 7.5 g/10 min at 300° C./1.2 kg according to ASTM D1238-04.

5. The method of claim 1 , wherein the composition is free of a release agent other than the triacylglyceride.

6. The method of claim 1 , wherein the triacylglyceride release agent comprises glycerol tristearate.

7. The method of claim 1 , wherein the UV stabilizer comprises 2-(2H-benzotriazol-2-yl)-p-cresol.

8. The method of claim 1 , wherein the composition has a light transparency of greater than 90% as determined using 3.2 mm thick samples using ASTM D1003-00, Procedure B using CIE standard illuminant C, with unidirectional viewing.

9. The method of claim 1 , wherein the blend composition does not exhibit visually detectable surface vibration as waviness during extrusion.

10. The method of claim 1 , comprising only melt filtering the melt polycarbonate prior to adding any triacylglyceride.

11. The method of claim 1 , wherein the polycarbonate has an endcap ratio of 65 to 71%.

12. The method of claim 1 , wherein the melt polycarbonate has an endcap level of greater than 50%, or greater than 80%, or 80% to less than 100%, or 85% to 95%.

13. An article of manufacture formed from the composition made by the method of claim 1 .

14. The article of claim 13 , wherein the article is a multi-wall sheet.

15. The article of claim 14 , wherein the multi-wall sheet comprises greater than or equal to two transverse layers and a rib extending from one of the transverse layers to an adjacent transverse layer.

16. The article of claim 13 , wherein the article comprises an airplane part, electrical part, electronic application part, food service item part, medical device part, animal cage part, electrical connector part, enclosure for electrical equipment, electric motor part, power distribution equipment part, communication equipment part, computer part, or construction application part.

17. The method of claim 1 , wherein the polycarbonate has a branching level of 1,000 to 1,200 ppm by weight.

18. The method of claim 1 , wherein the polycarbonate has an MVR of 5.5 to 7.5 g/10 min at 300° C./1.2 kg according to ASTM D1238-04 or ISO 1133.

19. The method of claim 1 , wherein the polycarbonate has a number average molecular weight of 20,000 to 60,000 g/mol (polystyrene basis).

20. The method of claim 1 , wherein the polycarbonate has a weight average molecular weight of 40,000 to 80,000 g/mol (polystyrene basis).

Assignees

• Sabic Global Technologies Bv

Inventors

• Roncaglia Marco
• Fernandez Ignacio Vic
• Faber Rein Mollerus
• Maas Christianus Johannes Jacobus
• Rijken Cornelis Jan Maria

Classifications

• C08K5/3475 Primary

  condensed with carbocyclic rings · CPC title

• B29C47/06

  Operations & Transport · mapped topic

• B29C47/68

  Operations & Transport · mapped topic

• C08K5/11

  of acyclic polycarboxylic acids · CPC title

• C08L69/00 Primary

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title